2-(4-Methyl­sulfanylphen­yl)-1H-benzimidazol-3-ium bromide

In the cation of the title compound, C14H13N2S+·Br−, the essentially planar benzimidazole system (r.m.s. deviation = 0.0082 Å) is substituted with a 4-methyl­sulfanylphenyl ring. The dihedral angle between the benzimidazole system and the 4-methyl­sulfanylphenyl ring is 2.133 (2)°. The crystal structure is characterized by strong and highly directional inter­molecular N—H⋯Br hydrogen bonds involving the bromide ion. Moreover, C—H⋯S inter­actions result in chains of mol­ecules along the c axis. The supra­molecular assembly is further stabilized by π–π stacking inter­actions between the benzimidazole system and 4-methyl­sulfanylphenyl rings [centroid–centroid distance = 3.477 (4) Å]

Bis{2-[4-(methyl­sulfan­yl)phen­yl]-1H-benzimidazol-3-ium} tetra­bromido­cuprate(II) dihydrate

The asymmetric unit of the title compound, (C14H13N2S)2[CuBr4]·2H2O, contains two cations, one anion and two solvent water mol­ecules that are connected via O—H⋯Br, N—H⋯Br and N—H⋯O hydrogen bonds into a two-dimensional polymeric structure. The cations are arranged in a head-to-tail fashion and form stacks along [100]. The central CuII atom of the anion is in a distorted tetra­hedral environment

Bis{2-[4-(methyl­sulfan­yl)phen­yl]-1H-benzimidazol-3-ium} tetra­bromido­cadmate(II) ethanol monosolvate

In the anion of the title compound, (C14H13N2S)2[CdBr4]·C2H5OH, the CdII atom is in a distorted tetra­hedral environment and one of the Br atoms is disordered over three sites with site-occupancy factors of 0.828 (5), 0.106 (3) and 0.068 (4). In the crystal, inter­molecular N—H⋯O, C—H⋯O and N—H⋯Br inter­actions result in a two-dimensional polymeric network extending parallel to (010)

Complexes of the Schiff base derived from 4-aminophenyl benzimidazole and 2, 2'- dehydropyrollidene-N-aldehyde with Zn (II), Cd (II) and Hg (II) halides

2421-2425A new Schiff base, dhpyr4apbi, has been synthesized from 4-aminophenyl benzimidazole and 2, 2'- dehydropyrollidene-N-aldehyde and its complexes with Zn (II), Cd (II) and Hg (II) halides have been prepared. Physicochemical properties of these metal complexes have been investigated using elemental analysis, molar conductance, proton NMR and IR measurements. The complexes are non-electrolytes and are dimeric in nature with the empirical formula M2L2X4 (M = Zn, Cd, Hg; X = Cl, Br.). The minimum energy configurati on has been obtained for these complexes using the molecular model Pro Plus. All the compl exes have been screened for their biological activities. The Cd(II) and Hg(II) complexes show moderate antibacterial activity against Pseudomonas fluorescens.</i

Some π-Cyclooctenyl Complexes of Palladium(II)

1194-119

Cationic complexes of palladium(II) containing phosphorus, arsenic, antimony and nitrogen donor ligands

1001-1003Palladium perchlorate reacts with several monodentate tertiary phosphines or arsines in acetonitrile to produce three-coordinate complexes of the type [PdL3[ClO4]2 (L= Ph3P, Ph2EtP, Ph3As, Ph2MeAs, Nap2MeAs, Cy3As, Ph3Sb), while the reaction in tetrahydrofuran leads to four-coordinate complexes of the formula [PdL4][ClO4]2 (L= Ph3P, Ph3As, Ph3Sb). With chelating bidentate ligands, palladium perchlorate yields [Pd(L-L)2][ClO4]2 (L-L= diphos, ɑ-pybzl) complexes