Synthesis and properties of Co-doped titanate nanotubes and their optical sensitization with methylene blue

Here we report on a novel chemical route to synthesize homogenous cobalt doped titanate nanotubes (CoTNT), using an amorphous Co-doped precursor. The influence of the synthesis temperature, autoclave dwell time and metal doping on the structural and microstructural as well as on the optical properties of the synthesized titanate nanotubes is studied and discussed. The optical band gaps of the CoTNT samples are red shifted in comparison with the values determined for the undoped samples, such red shifts bringing the absorption edge of the CoTNT samples into the visible region. CoTNT materials also demonstrate particular high adsorption ability for methylene blue, the amount of the adsorbed dye being higher than the one predictable for a monolayer formation. This suggests the possibility of intercalation of the dye molecule between the TiO6 layers of the TNT structure. It is also shown that the methylene blue sensitized Co-doped nanostructures are highly stable under UV radiation and present a strong and broad absorption in the visible region.Comment: 31 pages, 3 tables, 7 figure

Mechanisms of direct reactions with halo nuclei

Halo nuclei are exotic nuclei which exhibit a strongly clusterised structure: they can be seen as one or two valence nucleons loosely bound to a core. Being observed at the ridge of the valley of stability, halo nuclei are studied mostly through reactions. In this contribution the reaction models most commonly used to analyse experimental data are reviewed and compared to one another. A reaction observable built on the ratio of two angular distributions is then presented. This ratio enables removing most of the sensitivity to the reaction mechanism, which emphasises the effects of nuclear structure on the reaction.Comment: Invited talk given by Pierre Capel at the "10th International Conference on Clustering Aspects of Nuclear Structure and Dynamics" (Cluster12), Debrecen, Hungary, 24-28 September 2012. To appear in the Cluster12 Proceedings in the Open Access Journal of Physics: Conference Series (JPCS). (5 pages, 3 figures