12 research outputs found
Two molecular-type complexes of the octahedral rhenium(III) cyanocluster anion [Re6Se8(CN)6]4- with M2+ (Mn2+, Ni2+)
No full textTwo novel octahedral rhenium(III) selenocyanide cluster
complexes [(nBu)(4)N](2)Ni(H2O)(5)[Re6Se8(CN)(6)].2H(2)O (1)
and [(nBU)(4)N](2)Mn(H2O)(4)[Re6Se8(CN)(6)].2H(2)O (2) have
been prepared by the reaction of K-4[Re6Se8(CN)(6)].3.5H(2)O,
(nBu)(4)NBr kand Ni(OAC)(2) (or MnSO4) in aqueous solution. The
complexes have been structurally solved in the orthorhombic
unit cell Pbca with parameters: a = 19.393(2), b = 17.292(2), c
= 37.255(4) Angstrom for 1, and a = 19.518(41), b = 17.488(3),
c = 37.997(5) Angstrom for 2. The cluster anions and M2+ form
ionic pairs (M(H2O)(n)[Re6Se8(CN)(6)])(2-) that are packed in
the solid state with n-tetrabutylammonium cations. Coordinated
and solvate water molecules as well as the nitrogen atoms of
the anions form a network of hydrogen bonds in the structures.
These compounds are isomorphous, although the coordination
environments of the metal cations differ
An X-ray spectral study of the influence on the electronic structure of highT c superconductors of the parameters determining the superconducting transition temperature
No full textPolarization dependence of EXAFS and XANES spectra of superconducting films on the basis of Y-Ba-Cu-O
No full text
Phase transitions of intercalation inclusion compounds C2F0.92Br0.0·yCH3CN in the temperature range 20–260°C
No full textIron(II) closo-borate complexes with 1,2,4-triazole derivatives: Spin crossover in the iron(II) closo-borate complexes with tris(pyrazol-1-yl)methane
No full textSynthesis, Structure, Magnetic Behavior, and Mössbauer Spectroscopy of Two New Iron(II) Spin-Transition Compounds with the Ligand 4-Isopropyl-1,2,4-triazole. X-ray Structure of [Fe 3
No full text
