416 research outputs found

    Crystal-field effects in the mixed-valence compounds Yb2M3Ga9 (M= Rh, Ir)

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    Magnetic susceptibility, heat capacity, and electrical resistivity measurements have been carried out on single crystals of the intermediate valence compounds Yb2Rh3Ga9 and Yb2Ir3Ga9. These measurements reveal a large anisotropy due apparently to an interplay between crystalline electric field (CEF) and Kondo effects. The temperature dependence of magnetic susceptibility can be modelled using the Anderson impurity model including CEF within an approach based on the Non-Crossing Approximation.Comment: Accepted to Phys. Rev.

    On the origin of heavy quasiparticles in LiV_2O_4

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    An explanation is provided for the heavy quasiparticle excitations in LiV_2O_4. It differs considerably from that of other known heavy-fermion systems. Main ingredients of our theory are the cubic spinel structure of the material and strong short-range correlations of the d electrons. The large gamma-coefficient is shown to result from excitations of Heisenberg spin 1/2 rings and chains. The required coupling constant is calculated from LDA+U calculations and is found to be of the right size. Also the calculated Sommerfeld-Wilson ratio is reasonably close to the observed one.Comment: REVTEX, 5 pages, 2 figure

    Participation in Transition(s):Reconceiving Public Engagements in Energy Transitions as Co-Produced, Emergent and Diverse

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    This paper brings the transitions literature into conversation with constructivist Science and Technology Studies (STS) perspectives on participation for the first time. In doing so we put forward a conception of public and civil society engagement in sustainability transitions as co-produced, relational, and emergent. Through paying close attention to the ways in which the subjects, objects, and procedural formats of public engagement are constructed through the performance of participatory collectives, our approach offers a framework to open up to and symmetrically compare diverse and interconnected forms of participation that make up wider socio-technical systems. We apply this framework in a comparative analysis of four diverse cases of civil society involvement in UK low carbon energy transitions. This highlights similarities and differences in how these distinct participatory collectives are orchestrated, mediated, and subject to exclusions, as well as their effects in producing particular visions of the issue at stake and implicit models of participation and ‘the public’. In conclusion we reflect on the value of this approach for opening up the politics of societal engagement in transitions, building systemic perspectives of interconnected ‘ecologies of participation’, and better accounting for the emergence, inherent uncertainties, and indeterminacies of all forms of participation in transitions

    Verdienmodellen voor natuurinclusieve landbouw:Wat ondernemers al doen, en wat de overheid kan doen om opschaling te bevorderen

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    De Rijksnatuurvisie 2014 breekt een lans voor natuurinclusieve landbouw waarbij veel nadruk ligt op de rol van markt en maatschappij. Zulke landbouw behelst wat de nota noemt ‘natuurcombinaties’ waarbij natuur en economische activiteiten met elkaar vervlochten zijn. Een natuurinclusieve landbouw heeft een wezenlijk andere oriëntatie dan gangbare landbouw. In dit essay gaan we in op de voorwaarden waaronder natuurinclusieve verdienmodellen op middellange termijn op grote schaal kunnen worden gerealiseerd. Dit wordt uiteengezet op basis van de ervaringen van koplopers, die al langer aan natuurinclusieve landbouw doen

    Compressibility of CeMIn5Ce M In_5 and Ce2MIn8Ce_2 M In_8 (M = Rh, Ir and Co) Compounds

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    The lattice parameters of the tetragonal compounds CeMMIn5_{5} and Ce2M_{2}MIn8_{8}(M=M=Rh, Ir and Co) have been studied as a function of pressure up to 15 GPa using a diamond anvil cell under both hydrostatic and quasihydrostatic conditions at room temperature. The addition of MMIn2_{2} layers to the parent CeIn3_{3} compound is found to stiffen the lattice as the 2-layer systems (average of bulk modulus values B0B_{0} is 70.4 GPa) have a larger B0B_{0} than CeIn3_{3} (67 GPa), while the 1-layer systems with the are even stiffer (average of B0B_{0} is 81.4 GPa). Estimating the hybridization using parameters from tight binding calculations shows that the dominant hybridization is fpfp in nature between the Ce and In atoms. The values of VpfV_{pf} at the pressure where the superconducting transition temperature TcT_{c} reaches a maximum is the same for all CeMMIn5_{5} compounds. By plotting the maximum values of the superconducting transition temperature TcT_{c} versus c/ac/a for the studied compounds and Pu-based superconductors, we find a universal TcT_{c} versus c/ac/a behavior when these quantities are normalized appropriately. These results are consistent with magnetically mediated superconductivity.Comment: Updated version resubmitted to Phys. Rev.
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