43 research outputs found
The thermodynamic stability and hydration enthalpy of strontium cerate doped by yttrium
The standard molar enthalpy of formation of SrY0.05Ce0.95O2.975 has been
derived by combining the enthalpy of solution of this compound in 1 M HCl + 0.1
KI obtained by us and auxiliary literature data. The following value has been
derived: DfH (SrY0.05Ce0.95O2.975, s, 298.15 K) = -1720.4 (3.4) kJ/mol. The
obtained value has been used to obtain the formation enthalpy of
SrY0.05Ce0.95O2.975 from the mixture of binary oxides (DoxH (298.15 K) = -45.9
(3.4) kJ/mol) and formation enthalpy of reaction of SrY0.05Ce0.95O2.975 with
water forming Sr(OH)2, CeO2, Y2O3 (DrH (298.15 K) = -85.5 (3.4) kJ/mol). Data
obtained by solution calorimetry and additional information on the entropies of
different substances have shown that SrY0.05Ce0.95O2.975 is thermodynamically
stable with respect to a mixture of SrO, Y2O3, CeO2 and that the reaction of
SrY0.05Ce0.95O2.975 with water is thermodynamically favourable.Comment: 7 pages, 12 reference
Magnetic properties of bismuth-cobalt oxides doped by erbium
We synthesized bismuth - cobalt oxide doped by erbium with general formula
Bi3-xErxCoO3-y. Compound has structure of delta-form bismuth oxide. Magnetic
properties of the compound were measured by Faraday's method using quartz
scales in the temperature range of 80-500 K. The magnetic susceptibility and
effective magnetic moment were calculated.Comment: 5 pages, 2 figure
Formation enthalpy of BaCe0.7Nd0.2In0.1O2.85
In this paper for the first time we synthesized the compound
BaCe0.7Nd0.2In0.1O2.85 by solid-state reaction. The phase has orthorhombic
structure (space group Pmcn). We also measured the standard formation
enthalpies of BaCe0.7Nd0.2In0.1O2.85 by solution calorimetry in 1 M HCl with
0.1 M KI. We determined the stability of Nd(In)-doped barium cerate with
respect to mixtures of binary oxides. On the basis of these data we established
that above-mentioned mixed oxide is thermodynamically stable with respect to
their decomposition into binary oxides at room temperatures. We also
established that BaCe0.7Nd0.2In0.1O2.85 oxide is thermodynamically favoured
than BaCe0.8Nd0.2O2.9.Comment: 9 page
New phases in the Ba-Ce(M)-O systems (M = Ga, In)
A new and known barium cerates doped by In and Ga were synthesized in air at
1700 K. The synthesis was performed by solid state reactions from BaCO3, CeO2,
In2O3 or Ga2O3. X-ray diffraction profiles of the powdered samples were
obtained with DRON-UM-1 and STADI-P diffractometers using monochromatized CuKa
radiation. The following compositions of new phases were obtained:
BaCe1-xGaxO3-d (x = 0.05; 0.1) and BaCe1-xInxO3-d (x = 0.25, 0.5). They
crystallize in the orthorhombic space group Pnma. The lattice parameters were
calculated by full profile Rietveld method. Based on analysis of literature
data it was possible to assume that increasing of tolerance factors from BaCeO3
up to BaCe1-xGaxO3-d (BaCe1-xInxO3-d) led to the increasing of stability and
transport properties of Ga and In doped barium cerates.Comment: 8 pages, 2 figures, 3 table
Study of the SmBaCuO solid solutions decomposition and its possible role for changing critical current
We studied thermochemical characteristics of the Sm1+xBa2-xCu3Oy single
crystals by solution calorimetry. Dependences of formation enthalpies from
samarium content were constructed. It was established that solid solutions on
the bases of Sm123 could be decomposed both in inert and in oxygen atmosphere
into different mixtures. We supposed that solid solutions decomposition could
lead to increasing critical current density. We assumed from thermochemical
data that Jc could be greater for samples prepared in oxygen than for samples
synthesized in inert atmosphere. We confirmed these assumptions by comparison
of obtained thermochemical data with transport properties measured in
literature. We also investigated temperature dependences of resistance in the
temperature range of 300-550 K during slow heating. As it was shown there was
anomaly of resistance near 500 K. The origin of this anomaly was discussed.Comment: 8 pages, 2 figure
Solution calorimetry investigations of new phase BaCe0.6Y0.3In0.1O2.8
The preparation of BaCeO3 doped by yttrium and indium oxides
(BaCe0.6Y0.3In0.1O2.8) has been performed by solid-state reaction from BaCO3,
CeO2, Y2O3, In2O3. The compound BaCe0.6Y0.3In0.1O2.8 has been synthesized for
the first time. The X-ray measurements have showed that BaCe0.6Y0.3In0.1O2.8
has an orthorhombic structure (space group Pmcn). The standard formation
enthalpies of BaCe0.6Y0.3In0.1O2.8 have been determined by solution calorimetry
combining the solution enthalpies of BaCe0.6Y0.3In0.1O2.8 and BaCl2 + 0.6CeCl3
+ 0.3YCl3 + 0.1InCl3 mixtures in 1 M HCl with 0.1 M KI at 298.15 K and
literature data. It has been obtained that above-mentioned mixed oxide is
thermodynamically stable with respect to their decomposition into binary oxides
at room temperatures. It has been also shown that BaCe0.6Y0.3In0.1O2.8 has been
more thermodynamically favored than BaCe0.9In0.1O2.95.Comment: 9 pages, 1 figure, 1 table, 24 references. arXiv admin note: text
overlap with arXiv:1212.034
Thermodynamic stability of new phase Bi12.5Sm1.5ReO24.5
The Bi12.5Sm1.5ReO24.5 phase has been synthesized for the first time. The
preparation of Bi12.5Sm1.5ReO24.5 has been performed by solid-state reaction
from Bi2O3, Gd2O3, Re2O7. The X-ray measurements have showed that
Bi12.5Sm1.5ReO24.5 was cubic structure (space group Fm3m). The standard molar
enthalpy of formation of Bi12.5Sm1.5ReO24.5 has been determined by solution
calorimetry combining the enthalpies of dissolution of Bi12.5Sm1.5ReO24.5 and
6.25Bi2O3 + 0.75Sm2O3 + 0.5Re2O7 mixture in 2 M HCl and literature data. It has
been obtained that above-mentioned phase is thermodynamically stable with
respect to their decomposition into binary oxides at room temperatures.Comment: 9 pages, 1 figure, 2 tables, 15 reference
Decomposition of solid solutions in the Nd-Ba-Cu-O system and its influence on changing transport characteristics
Thermochemical characteristics of Nd1+xBa2-xCu3Oy solid solutions were
studied by solution calorimetry. Dependences of formation enthalpies from Nd
content were constructed. It was established that decomposition of solid
solution on the basis of Nd123 phase took place both in inert and in oxygen
atmosphere. As a result of decomposition the different mixtures such as solid
solutions with increasing and decreasing Nd content and BaCuO2 were formed.
Obtained thermochemical data were compared with results of measurements of
transport characteristics. It was established that treatment of samples at
550-600 C led to increasing critical current and decreasing Tc.Comment: 7 pages, 1 figure Keywords: Nd-Ba-Cu-O system; Calorimetry;
Decompositio
Preparation and ionic conductivity of new Bi12.5Lu1.5ReO24.5 phase
The substitution of Re into Bi2O3 allows stabilization of the d- Bi2O3
structure by additional substitution of lutetium ion to give phase of
composition Bi12.5Lu1.5ReO24.5. The phase was synthesized for the first time.
Structural analysis performed by neutron diffraction showed that space group
was Fm3m with lattice parameter a = 5.5591(2) {\AA}. The phase has been found
to show high ion conductivity at moderate temperature. The conductivity was
measured in the temperature range of 600-800 K. The conductivity of
Bi12.5Lu1.5ReO24.5 at 800 K is the same as the conductivity of BiCuVOx,
Bi12.5Ln1.5ReO24.5 (Ln = Eu, La, Nd) phases. In this connection the
Bi12.5Lu1.5ReO24.5 phase offers excellent potential for moderate temperature
application
Thermodynamic properties of yttrium cuprate
The standard formation enthalpy and enthalpy from binary oxide of yttrium
cuprate have been determined by solution calorimetry combining the solution
enthalpies of Y2Cu2O5 and Y2O3 + 2CuO mixture in 6 M HCl at 323.15 K and
literature data. The heat capacity of Y2Cu2O5 has been measured by adiabatic
calorimetry from 8 up to 303 K. Smoothed values of heat capacities, entropies
and enthalpies were calculated on the basis of experimental data. The
thermodynamic functions (heat capacity, entropy and enthalpy) at 298.15 K have
been calculated. On the basis of obtained data it has been obtained that
above-mentioned complex oxide is thermodynamically unstable with respect to
their decomposition into binary oxides at room temperatures.Comment: 10 pages; 2 Table