8 research outputs found
Molybdenum Complexes as Catalysts for the Oxidation of Cycloalkanes with Molecular Oxygen
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Synthesis and catalytic epoxidation potentiality of oxodiperoxo molybdenum(VI) complexes with pyridine-2-carboxaldoxime and pyridine-2-carboxylate: the crystal structure of PMePh3[MoO(O-2)(2)(PyCO)]
No full text[MoO(O-2)(2)(PyCOXH)(H2O)] and PMePh3[MoO(O-2)(2)(PyCO)] (PyCOXH = Pyridine-2-carboxaldoxime and PyCOH = Pyridine-2-carboxylic acid) have been synthesized. Both complexes have been characterized by physico-chemical and spectroscopic methods; in addition, the carboxylate complex has been structurally characterized by X-ray crystallography. The carboxylate complex is a more efficient catalyst than the oxime complex for epoxidation of olefins and shows excellent catalytic activity for the substrates: cyclooctene, cinnamyl alcohol, allyl alcohol and 1-hexene
Partial Catalytic Oxidation of Alcohols: Catalysts Based on Metals and Metal Coordination Compounds (a Review)
No full textComputational mechanistic studies of acceptorless dehydrogenation reactions catalyzed by transition metal complexes
No full textSynthesis and Catalytic Epoxidation Activity with TBHP and H2O2 of Dioxo-, Oxoperoxo-, and Oxodiperoxo Molybdenum(VI) and Tungsten(VI) Compounds Containing Monodentate or Bidentate Phosphine Oxide Ligands: Crystal Structures of W(O)2(Cl)2(OPMePh2)2, W(O)(O)2(Cl)2(OPMePh2)2, Mo(O)2(Cl)2dppmO2C4H10O, W(O)2(Cl)2dppmO2, Mo(O)(O2)2dppmO2, and W(O)(O2)2dppmO2
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