Synthesis and styrene copolymerization of novel dimethyl and dimethoxy ring-substituted octyl phenylcyanoacrylates

Novel dimethyl and dimethoxy ring-substituted octyl phenylcyanoacrylates, RPhCH=C(CN)CO2CH2(CH2)6CH3 (where R is 2,3-dimethyl, 2,4-dimethyl, 2,5-dimethyl, 2,6-dimethyl, 3,4-dimethyl, 3,5-dimethyl, 2,3-dimethoxy, 2,4-dimethoxy, 2,5-dimethoxy, 2,6-dimethoxy, 3,4-dimethoxy, 3,5-dimethoxy) were prepared and copolymerized with styrene. The acrylates were synthesized by the piperidine catalyzed Knoevenagel condensation of ring-disubstituted benzaldehydes and octyl cyanoacetate, and characterized by CHN analysis, IR, 1H and 13C NMR. All the acrylates were copolymerized with styrene in solution with radical initiation (ABCN) at 70C. The compositions of the copolymers were calculated from nitrogen analysis

r-FrMS: a relation-driven fractal organisation for distributed manufacturing systems

Up-to-date market dynamics and decentralisation have brought about the need of flexible and robust organisational structures for manufacturing resources. To meet the need of such an environment, the manufacturing system should be equipped with an open, reconfigurable and scalable organisational structure. This paper proposes a novel organisational model, referred to as a relation-driven fractal organisation, to meet the requirements. The proposed model applies the concept of a fractal to its organisational structure and adopts a relational pattern between composing entities as a basic building block for organising. In this paper, the existing fractal-like systems involved in manufacturing systems are investigated, and the fractal organisation is derived as their super-ordinate concept. Then, r-FrMS, a relation-driven fractal organisation applied into distributed manufacturing systems, is proposed along with its organising mechanism which adopts employment relations between manufacturing resources as its organising principle.close5