Pillared Clays as Superior Catalysts for Selective Catalytic Reduction of Nitric Oxide. Second Semiannual Report, 1996

During the first six months of the program, the work has progressed as planned. We have constructed a reactor system and assembled all laboratory essentials for conducting the three-year project. First, the catalytic activities of the Cu(2+) ion exchanged alumina-pillared clay for the selective catalytic reduction of NO by ethylene were measured. The temperature range was 250-500{degrees}C. The activities of this catalyst were substantially higher than the catalyst that has been extensively studied in the literature, Cu-ZSM-5. Fourier Transform Infrared Spectroscopy (FTIR) was used to study the acidity of the catalyst. The second part of the work was an in-depth FTIR study of the NO decomposition mechanism on the catalyst. This was planned as the first and the key step to obtain an understanding of the reaction mechanism. Key surface intermediates were identified from the FTIR spectra, and a redox type Eley-Rideal mechanism was proposed for the NO decomposition on this catalyst. This report will be divided into two parts. In Part One, we report results on the catalytic activities of the Cu-alumina-pillared clay and a direct comparison with other known catalysts. In Part two, we focus on the FTIR study and from the results, we propose a NO decomposition mechanism on this new catalyst. Plans for the next six months include tests of different pillared clays as well as the catalytic mechanism. The micro reactor will continue to be the key equipment for measuring the catalytic activities. FTIR will continue to be the major technique for identifying surface species and hence understanding the reaction mechanism