5-(2-Hydroxybenzoyl)-1-methyl-3-nitropyridin-2(1H)-one

In the title compound, C13H10N2O5, the dihedral angle between the pyridine and phenyl ring is 50.47 (2)°. The hydroxyl H and ketone O atoms form an intramolecular O—H...O hydrogen bond with the hydroxyl group almost coplanar with the phenyl ring. In the crystal, molecules are linked by two C—H...O hydrogen bonds, forming dimers. The dimers are linked by further C—H...O hydrogen bonds, forming a three-dimensional architecture

Crystal structures of methyl (E)-3-(2-chlorophenyl)-2-({2-[(E)-2-nitrovinyl]phenoxy}methyl)acrylate and methyl (E)-2-({4-chloro-2-[(E)-2-nitrovinyl]phenoxy}methyl)-3-(2-chlorophenyl)acrylate

The title compounds, C19H16ClNO5, (I), and C19H15Cl2NO5, (II), both crystallize in the monoclinic space group P21/n. They differ essentially in the orientation of the methyl acetate group, with the C=O bond directed towards the NO2 group in (I) but away from it in (II). In compound (I), the mean plane of the methyl acrylate unit is planar, with a maximum deviation of 0.0044 (2) Å for the methyl C atom, while in (II) this deviation is 0.0147 Å. The interplanar angles between the two aromatic rings are 74.87 (9) and 75.65 (2)° for compounds (I) and (II), respectively. In both compounds, the methyl acrylate and nitrovinyl groups each adopt an E conformation about the C=C bond. In the crystal of (I), molecules are linked by C—H...O hydrogen bonds forming chains along the b axis. The chains are linked via C—H...Cl hydrogen bonds, forming sheets parallel to the ab plane. The sheets are linked via C—H...π interactions, forming a three-dimensional structure. In the crystal of (II), molecules are linked by pairs of C—H...O hydrogen bonds, forming inversion dimers with an R22(30) ring motif. The dimers are linked via C—H...O hydrogen bonds, forming sheets parallel to the ac plane and enclosing R44(28) ring motifs. The sheets are linked via parallel slipped π–π interactions (intercentroid distances are both ca 3.86 Å), forming a three-dimensional structure

1-Cyclohexyl-5-(2-hydroxybenzoyl)-3-nitropyridin-2(1H)-one

In the title compound, C18H18N2O5, the cyclohexane ring adopts a chair conformation, and its mean plane is almost normal to the central pyridin-2-one ring with a dihedral angle of 87.94 (8)°. The latter ring is inclined to the 2-hydroxybenzoyl ring by 50.92 (8)°. There is an intramolecular O—H...O hydrogen bond in this unit forming an S(6) ring motif. The NO2 group is disordered over two orientations of equal occupancy. In the crystal, molecules are linked via C—H...O hydrogen bonds, forming chains propagating along [001]. Inversion-related chains are linked by C—H...π interactions, forming columns along the c-axis direction