Dimensionality-driven insulator–metal transition in A-site excess non-stoichiometric perovskites

Coaxing correlated materials to the proximity of the insulator–metal transition region, where electronic wavefunctions transform from localized to itinerant, is currently the subject of intensive research because of the hopes it raises for technological applications and also for its fundamental scientific significance. In general, this tuning is achieved by either chemical doping to introduce charge carriers, or external stimuli to lower the ratio of Coulomb repulsion to bandwidth. In this study, we combine experiment and theory to show that the transition from well-localized insulating states to metallicity in a Ruddlesden-Popper series, La0.5Srn+1−0.5TinO3n+1, is driven by intercalating an intrinsically insulating SrTiO3 unit, in structural terms, by dimensionality n. This unconventional strategy, which can be understood upon a complex interplay between electron–phonon coupling and electron correlations, opens up a new avenue to obtain metallicity or even superconductivity in oxide superlattices that are normally expected to be insulators

Non-destructive inspection technologies for repair assessment in materials and structures

Aging infrastructure globally faces degradation, posing risks and requiring substantial repair investment. Strategic maintenance practices are crucial for evaluating structural conditions and ensuring sustainability. The growing demands on modern materials and structures necessitate enhanced health monitoring approaches. Shifting from reactive to proactive maintenance methodologies is paramount, due to lower investment while keeping the structural performance at acceptable standards. However, quantitative assurance of repair/reinforcement/retrofit programs or self-healing effect in structures is similarly crucial for the operation of the infrastructure. Non-destructive testing (NDT) techniques, such as ultrasound, acoustic emission, and optical methods, play a vital role in assessing structural health. Through real-world case studies, the effectiveness of repair in addition to damage assessment are evaluated, encouraging a more systematic approach to monitoring structural repair efficacy. The paper intends to address the research gap in monitoring the repair effectiveness in civil structures and materials and provides valuable insights to enhance repair strategies in civil engineering.Concrete Structure