Effect of morphology and hydrophobization of MoS2 microparticles on the stability of poly-α-olefins lubricants

International audienceThe use of MoS ⁠ 2 nanoparticles as additive to lubricating oils is restricted by their low stability in oily media, which limits their use despite the enormous benefits associated with their intrinsic properties in terms of reduction of friction and wear coefficients. In this context, we investigated the effect of morphologies (platelets vs spheres) and surface functionalization of nanoparticles on the stability of their suspensions in poly-α-olefins (PAO) with various viscosities, which are base oils used in wind turbines. The particles were characterized by XRD, FTIR, scanning electron microscopy, atomic force microscopy and dynamic light scattering, and the stability of the resultant formulations was followed by optical (non-contact) measurements. It was found that the dispersions had similar stability despite the larger size of platelet-like particles compared to spherical ones (1-5 μm vs 600-800 nm). The dispersibility could be increased through grafting of alkylsilane on the surface defects (the longer the alkyl chain, the more stable the formulation) and with the increase of the oil kinematic viscosity (from 34 to 1705 cps at 25 °C)

Preparation and use of maize tassels’ activated carbon for the adsorption of phenolic compounds in environmental waste water samples

The determination and remediation of three phenolic compounds bisphenol A (BPA), ortho-nitrophenol (o-NTP), parachlorophenol (PCP) in wastewater is reported. The analysis of these molecules in wastewater was done using gas chromatography (GC) × GC time-of-flight mass spectrometry while activated carbon derived from maize tassel was used as an adsorbent. During the experimental procedures, the effect of various parameters such as initial concentration, pH of sample solution, eluent volume, and sample volume on the removal efficiency with respect to the three phenolic compounds was studied. The results showed that maize tassel produced activated carbon (MTAC) cartridge packed solid-phase extraction (SPE) system was able to remove the phenolic compounds effectively (90.84–98.49 %, 80.75–97.11 %, and 78.27–97.08 % for BPA, o-NTP, and PCP, respectively) . The MTAC cartridge packed SPE sorbent performance was compared to commercially produced C18 SPE cartridges and found to be comparable. All the parameters investigated were found to have a notable influence on the adsorption efficiency of the phenolic compounds from wastewaters at different magnitudes

Numerical modeling transient flow in plastic pipes

We present a numerical code for calculating transient flow in plastic pipes, especially in the polyethylene pipe, to analysis effect of material viscoelasticity on water hammer phenomena. The set partial differential equations to be solved is obtained using conservation laws and behavior for the fluid and the pipe wall, associated with constitutive equations of the two media, and relationships compatibility of interfaces on velocities and stresses. A global digital processing is achieved using the method of characteristics. The results obtained are in good agreement with those found in the literature

Beurling’S Theorem and Lp− Lqmorgan’S Theorem for the Generalized Bessel-Struve Transform

The generalized Bessel-Struve transform satisfies some uncertainty principles similar to the Euclidean Fourier transform. A generalization of Beurling’s theorem and Lp− LqMorgan’s theorem obtained for the generalized Bessel-Struve transform