Analysis of thermal degradation behavior for some hydraulic oils, using FTIR-TGA coupling

The transitions between the vibrational energetic states of atoms represent the infrared absorption spectra, which is a band spectrum over which the transitions between energetic rotational states overlap. One of the most important uses of infrared absorption spectrometry is the identification in quantitative terms of the structure of compounds from a substance, the analytes being either solid, liquid or vaporous. The FTIR-TGA Coupling is a technique that permanently controls the mass loss in a sample, as a function of temperature and time, as well as the identification and recording of various compounds occurring during the combustion process. Research on hydraulic oils has consisted of their analysis using the FTIR-TGA coupling in order to identify flammable substances that can generate explosive events

Analysis of thermal degradation behavior for some hydraulic oils, using FTIR-TGA coupling

The transitions between the vibrational energetic states of atoms represent the infrared absorption spectra, which is a band spectrum over which the transitions between energetic rotational states overlap. One of the most important uses of infrared absorption spectrometry is the identification in quantitative terms of the structure of compounds from a substance, the analytes being either solid, liquid or vaporous. The FTIR-TGA Coupling is a technique that permanently controls the mass loss in a sample, as a function of temperature and time, as well as the identification and recording of various compounds occurring during the combustion process. Research on hydraulic oils has consisted of their analysis using the FTIR-TGA coupling in order to identify flammable substances that can generate explosive events

Assessing the heavy metal pollution level in Jiu Valley by bio-monitoring inferior plants – moss

The analysis of the samples collected from residential areas and the proximity of the industrial areas of Jiu Valley was carried out by means of induced coupled plasma optical emission spectrometry (ICP-OES) after acid processing and mineralization of the samples. The pollution level has increased once with the industrial development and acceleration of urbanization processes in the human society. Of the pollutant-generating substances, heavy metals are of particular importance. The purpose of this paper is to highlight level of pollution by heavy metals using moss (inferior plants) in order to determine the degree of bioaccumulation. From the pollution point of view, zinc, cadmium and lead are of particular relevance, but the effects of other heavy metals have also been studied. The pollution effects last for a long time in waste dumps, areas polluted with heavy metals from fuel combustion processes, fossil fuels a.s.o. The analysis of the samples collected from residential areas and the proximity of the industrial areas of Jiu Valley was carried out by means of induced coupled plasma optical emission spectrometry (ICP-OES) after acid processing and mineralization of the samples

Determination of flammability parameters for organic waste resulting from the processing of sunflower seeds

Agricultural waste is found in abundance in the environment, whether it is the plant itself represented by the stem, leaf or seeds that have been peeled or other waste. By drying and crushing the residues from the plants, organic powders will be formed with a variable granulation and humidity. Through the processing of oilseeds such as sunflower seeds, significant amounts of waste from seeds result. Seed shells resulting from technological processes crumble, forming fine powders, whose granulations are different. A certain percentage will be 63μm or smaller and if those fine powders are mixed with air can form clouds with explosive properties. The purpose of this paper was to determine the minimum ignition layer and cloud temperatures. Experimental determination of flammability parameters is particularly important in order to take the proper safety measures so that accidents can be avoided

Assessing the heavy metal pollution level in Jiu Valley by bio-monitoring inferior plants – moss

The analysis of the samples collected from residential areas and the proximity of the industrial areas of Jiu Valley was carried out by means of induced coupled plasma optical emission spectrometry (ICP-OES) after acid processing and mineralization of the samples. The pollution level has increased once with the industrial development and acceleration of urbanization processes in the human society. Of the pollutant-generating substances, heavy metals are of particular importance. The purpose of this paper is to highlight level of pollution by heavy metals using moss (inferior plants) in order to determine the degree of bioaccumulation. From the pollution point of view, zinc, cadmium and lead are of particular relevance, but the effects of other heavy metals have also been studied. The pollution effects last for a long time in waste dumps, areas polluted with heavy metals from fuel combustion processes, fossil fuels a.s.o. The analysis of the samples collected from residential areas and the proximity of the industrial areas of Jiu Valley was carried out by means of induced coupled plasma optical emission spectrometry (ICP-OES) after acid processing and mineralization of the samples

Self-ignition temperature of the dust accumulations for sunflower and wood powders

Spontaneous combustion is a phenomenon that results from the heating of combustible organic powders by slow oxidation and which occurs through the air passage (created by an air depression) through the mass of dust. The oxidation phenomenon of combustible powders represents their reaction with atmospheric oxygen resulting in products of carbon dioxide, carbon oxide, water and other gases whose content depends on the temperature at which the oxidation takes place. The self-ignition of combustible dusts depends on their chemical composition, the properties of component substances, on the particle size and geometry of the material mass and, last but not least, on the temperature of the environment. Due to global worries of sustainability in construction engineering the trend is to use ecofriendly organic waste to various purposes as in construction materials. The challenge is that by using this kind of materials one should ensure the safety related to the process of such organic materials which are known to have combustible properties. The purpose of this work is to present the self-ignition behavior of combustible dusts such as sunflower and wood by means of drying tests under constant temperature conditions

Heavy metal pollution from dust deposits in urban and industrial areas in the Jiul Valley

The aim of this paper was to determine the concentration of heavy metals in dust samples by the method of analysis by inductively coupled plasma optical emission spectrometry (ICP-OES) and to assess the degree of pollution of the studied areas. The dust samples studied and subjected to analytical analyzes were collected from the vicinity of industrial areas and urban areas of localities in the Jiu Valley, a monoindustrial area. The main heavy metals determined were: Cu, Zn, Pb, Ni, Cr, Co etc. Dust particles depending on their origin can be inorganic or organic. The samples were collected from the urban areas and from the vicinity of the industrial areas