8,050 research outputs found
Derivative analysis of spectral absorption by photosynthetic pigments in the western Sargasso Sea
Concurrent measurements of the spectral absorption coefficient and photosynthetic pigmentation of natural particulates were performed to determine the principal pigments responsible for the absorption of spectral irradiance in seawater. The spectral absorption coefficient, Ap(Ξ»), was then analyzed by taking the second and fourth derivatives with respect to wavelength. The wavelength and magnitude of these derivative values provide useful information regarding the identification and quantification of phytoplankton pigments responsible for a given spectral signature. Linear relationships were examined and established between derivative values at selected wavelengths and concentrations of the major tetrapyrrole pigments, specifically chlorophylls a, b, and c. The correlation between derivative values near 526 nm and concentrations of photosynthetic carotenoids was poor and presumably caused by the broad absorption spectra of these pigments. A comparison of the measured particulate absorption coefficient with the absorption coefficient reconstructed for the phytoplankton component revealed that detritus can be a major source of light absorption. The method described here provides a rapid means of obtaining estimates of photosynthetic pigment concentrations in natural samples where absorption can be strongly influenced by detrital matter
Hyperfine frequency shift in two-dimensional atomic hydrogen
We propose the explanation of a surprisingly small hyperfine frequency shift
in the two-dimensional (2D) atomic hydrogen bound to the surface of superfluid
helium below 0.1 K. Owing to the symmetry considerations, the microwave-induced
triplet-singlet transitions of atomic pairs in the fully spin-polarized sample
are forbidden. The apparent nonzero shift is associated with the
density-dependent wall shift of the hyperfine constant and the pressure shift
due to the presence of H atoms in the hyperfine state not involved in the
observed transition. The interaction of adsorbed atoms with one
another effectively decreases the binding energy and, consequently, the wall
shift by the amount proportional to their density. The pressure shift of the
resonance comes from the fact that the impurity -state atoms
interact differently with the initial -state and final -state atoms and
is also linear in density. The net effect of the two contributions, both
specific for 2D hydrogen, is comparable with the experimental observation. To
our knowledge, this is the first mentioning of the density-dependent wall
shift. We also show that the difference between the triplet and singlet
scattering lengths of H atoms, pm, is exactly twice smaller
than the value reported by Ahokas {\it et al.}, Phys. Rev. Lett. {\bf101},
263003 (2008).Comment: 4 pages, no figure
Adsorption and two-body recombination of atomic hydrogen on He-He mixture films
We present the first systematic measurement of the binding energy of
hydrogen atoms to the surface of saturated He-He mixture films.
is found to decrease almost linearly from 1.14(1) K down to 0.39(1) K, when the
population of the ground surface state of He grows from zero to
cm, yielding the value K cm
for the mean-field parameter of H-He interaction in 2D. The experiments
were carried out with overall He concentrations ranging from 0.1 ppm to 5 %
as well as with commercial and isotopically purified He at temperatures
70...400 mK. Measuring by ESR the rate constants and for
second-order recombination of hydrogen atoms in hyperfine states and we
find the ratio to be independent of the He content and to
grow with temperature.Comment: 4 pages, 4 figures, all zipped in a sigle file. Submitted to Phys.
Rev. Let
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