QR-CODE PROJECT : Towards better traceability of field sampling data

Ensuring traceability of field experimental data or laboratory sampling data to conduct reproducible research is a challenge at the present time. Between the time when geolocalized specimens (biotic or abiotic) are taken, and the time the resulting data ends up in analysis published with a study, many manual operations take place and may generate errors. The French LTSER have joined forces at the national level to propose a solution as generic as possible to this problem of monitoring of the samples and the data associated with them. Compared to existing solutions (such as Laboratory Information Management Systems), we target a robust labeling solution adapted to outdoor working conditions, with the management of stocks and movements of samples. We designed and realized a prototype tested from end to end, using an open source software, cheap Zebra printers (mobile or not) and raspberries as devices. This solution provides sufficient flexibility for the wide variety of existing protocols. In strength is the record of all contextual data associated with the samples, which constitute important parameters of the subsequent analyses. At last, not only traceability is guaranteed, but also a gain of time and a rationalization of the storage of samples that will induce a return on investment

Quantitative multimolecular marker approach to investigate the spatial variability of the transfer of pollution from the Fensch River to the Moselle River (France).

International audienc

Evolution of the source apportionment of the lipidic fraction from sediments along the Fensch River, France : a multimolecular approach.

International audienc

Physico-chimie des matières en suspension de la Moselle et de ses affluents

Afin de caractériser la physico-chimie des matières en suspension de la Moselle et de ses affluents, ce travail s est appuyé sur une approche géochimique et minéralogique. Notre étude s est concentrée sur l analyse des polluants dans les compartiments dissous et particulaire. Ces études ont notamment permis de déterminer (i) la composition des constituants inorganiques dans les particules et colloïdes du milieu aquatique de la Moselle et d un de ses affluents : la Fensch, (ii) l évolution des contributions inorganiques le long de la Moselle et de la Fensch ainsi que leur transfert à la confluence Fensch-Moselle, tout en déterminant les sources principales de contamination, (iii) les associations organo-minérales et l organisation des agrégats présents et (iv) d étudier la spéciation de certains éléments par des microanalyses. Ce travail a ainsi permis de mettre en évidence l importance des matières en suspension, souvent négligées par rapport aux autres compartiments Eau et SédimentsThis work uses geochemical and mineralogical approaches to characterize physical and chemical properties of suspended solids in the Moselle and its tributaries. The study focused on analyzing the pollutants in dissolved and particulate compartments. This allowed (i) the identification of inorganic components composition in particles and colloids in the aquatic environment of the Moselle and one of its tributaries: the Fensch, (ii) the determination of the evolution of inorganic contributions along Moselle and the Fensch and their transfer to the confluence Fensch-Moselle in addition to the determination of main contamination sources, (iii) the identification of organo-mineral associations and the determination of the organization of aggregates, (iv) the analysis of the speciation of some elements by microanalysis. This work highlighted the importance of studying suspended solids that are often neglected compared to water and sediments compartmentsNANCY-INPL-Bib. électronique (545479901) / SudocSudocFranceF

Impact of a highly contaminated river on a more important hydrologic system : changes in organic markers.

International audienc

Occurrence and distribution of polycyclic aromatic compounds in the river of a past industrial valley: from sediments to availability in water

International audienc

Do Hyperaccumulators develop Specific Chelates for Nickel Transport and Storage? The cases of Senecio coronatus and Berkheya coddii.

International audienceIn order to unravel nickel speciation within shoots of two hyperaccumulating plants Senecio coronatus and Berkheya coddii, spatially resolved X-ray absorption experiments were carried out at the Ni K-edge, using a micro-focused beam. Citrate and malate appeared as the main complexing ligands for nickel in the different investigated regions i.e.mesophyll, epidermis, conductive vessels (xylem and phloem)

Fate of nickel in seedlings of Berkheya coddii during germination.

Little is known about Ni storage in seeds of hyperaccumulating plants and its possible role in the first stages of plant development. The aim of this study was to determine Ni distribution in seeds and seedlings during germination and to test its role during germination with and without an external Ni supply. Field-harvested seeds from the South African Ni-hyperaccumulator Berkheya coddii Roessler were germinated either in Ni-free deionised water or in ultramafic soil. Sections of seeds and seedlings were analyzed using micro-proton induced X-ray emission (micro-PIXE) in order to localise Ni and other elements. Results show that high amounts of Ni were stored within the seeds. In germinating seeds, Ni was located in different parts: the lower epidermis, margins of cotyledons, and the pericarp in the micropylar area. The Ni and Ca were not mobilised during germination sensu stricto. Emergence of the first leaf seemed to trigger the translocation of Ni and Ca within the seedling. Besides, no effect of Ni supply from soil on its redistribution could be established for the germination stage

Pedogenesis and nickel biogeochemistry in a typical Albanian ultramafic toposequence

International audienceThis study aimed at relating the variability of Ni biogeochemistry along the ultramafic toposequence to pedogenesis and soil mineralogy. Hypereutric Cambisols dominate upslope; Cambic Vertisols and Fluvic Cambisols occur downslope. The soil mineralogy showed abundance of primary serpentine all over the sequence. It is predominant upslope but secondary smectites dominate in the Vertisols. Free Fe-oxides are abundant in all soils but slightly more abundant in the upslope soils. Whereas serpentines hold Ni in a similar and restricted range in every soil (approx. 0.3 %), Ni contents in smectites may vary a lot and Mg-rich and Al-poor smectites in the Vertisol could hold up to 4.9 % Ni. Ni was probably adsorbed onto amorphous Fe-oxides and was also exchangeable in secondary smectites. High availability of Ni in soils was confirmed by DTPA extractions. However, it varied significantly along the toposequence, being higher in upslope soils, where Ni-bearing amorphous Fe-oxides were abundant and total organic carbon higher and sensibly lower downslope on the Vertisols: Ni-DTPA varied from 285 mg kg(-1) in the surface of soil I (upslope) to 95.9 mg kg(-1) in the surface of Fluvic Cambisols. Concentration of Ni in Alyssum murale shoots varied from 0.7 % (Hypereutric Cambisols) to 1.4 % (Hypereutric Vertisol). Amazingly, Ni uptake by A. murale was not correlated to Ni-DTPA, suggesting the existence of specific edaphic conditions that affect the ecophysiology of A. murale upslope

Microscale investigations of the fate of heavy metals associated to iron-bearing particles in a highly polluted stream

International audienceAs it flows through a dense steelmaking area, the Fensch River does transport iron-rich particles and colloids, displaying high contents in metallic contaminants (Zn, Cr, Pb, Cu, Ni, and As). Chemical analysis using inductively coupled plasma mass spectrometry (ICP-MS) was carried out on three compartments-waters, suspended materials, and sediments-along the river linear. The variations of metallic trace element concentrations along the river were shown to be partially related to external inputs (industrial and domestic wastewaters and urban surfaces leaching). However, some discrepancies of element partitioning were evidenced. Pb, Cu, and Mn tend to concentrate in suspended particulate and in dissolved fraction, while Cr and As follow the trend of Fe and concentrate within sediments of the most downstream station, just before the junction with Moselle waters. Zn appears strongly associated to iron-rich particles, resulting in a decrease of its concentration in waters for the last station. Along the Fensch linear, the variation of metal partitioning between water and particulate phases is accompanied with strong modifications of the nature and mineralogy of iron-rich particles, as evidenced by microanalyses using electron and X-ray beams. The combination of bulk analyses using ICP-MS and microanalyses applied to the three compartments allowed us to propose a three-step process "settling-weathering-resuspension" to explain Zn partitioning