Process Optimization Potassium Nanofertilizer Production via Ionotropic Pre-gelation using Alginate-Chitosan Carrier

Potassium nanofertilizer synthesis by incorporating potassium in alginate-chitosan carrier via ionotropic pre-gelation was optimized to maximize potassium content and develop controlled release fertilizer. Utilizing two-level factorial design, potassium to alginate ratio, calcium chloride to alginate ratio, and pre-gelation time were determined significant. Central Composite Design for optimization was utilized to generate a Response Surface model relating the factors to the response for numerical optimization. Optimum process conditions for maximum potassium content were (1) 1.5:1 (w/w) potassium to alginate ratio, (2) 6.5:117.5 (v/v) calcium chloride to alginate ratio, and (3) 40 minutes pre-gelation time. The potassium content of the fertilizer formulated at optimum condition was successfully verified to contain 29.75 %K(w/w). Characterization showed that potassium was successfully incorporated in the alginatechitosan carrier as shown by the SEM surface images. DLS result showed two peaks at particle sizes near 594.1 nm and 102.8 nm indicating that potassium nanofertilizer was successfully synthesized. Potassium nanofertilizer may be a controlled release fertilizer since only 14.6 %K was released after 24 hours in Britton-Robinson buffer solution. Preliminary costing shows higher cost of production based on raw materials, but it may be offset in the long run by longer availability of nutrient and low fertilizer application rate

Process Optimization for the Production of Potassium-Carrageenan Nanofertilizer by Ionic Crosslinking

The effects of nutrient loading, mixing temperature, time and type of drying method (freeze and oven drying) on the total K content of the potassium-carrageenan fertilizer formulated through ionic crosslinking was evaluated. Direct effect on the total K was observed at varying nutrient loading at nutrient-to-carrier mass ratios 1:2 and 2:1 with no significant effect at varying mixing conditions and drying. Instead, variations are observed on the qualitative properties of potassium-carrageenan such as viscosity due to the thermoreversible properties of kappa-carrageenan. A linear model based on the significant factor was generated to predict the potassium content at the range of nutrient ratio adjusted to 1:2 to 1.5:1 to obtain a center ratio 1:1, with a maximum predicted value of 26.64% w/w. Potassium and carrageenan crosslinking yield an organized helix structure based on SEM micrograph with crystalline structure. Freeze dried fertilizers yield smaller particle sizes about 300nm due to its easily size reducible physical appearance than in oven-drying where film like particles are observed. Further, a decrease in absorbance is observed at increased potassium concentration. Evaluation of release pattern using buffer system shows slower release of nutrient using carrageenan carrier compared to conventional fertilizer at pH sensitive environment

Parametric and Optimization Studies on the entrapment of Potassium Fertilizer into Chitosan-Poly(methacrylic acid) Carrier via Ionic Gelation

Nanofertilizer is an emerging technology for exhibiting slow release mechanism of fertilizer application. This slow release mechanism allows increase in nutrient uptake of plants while minimizing environmental pollution; specifically, reducing eutrophication in bodies of water. This study includes parametric and optimization studies for ionic gelation process in the formulation of potassium fertilizer in chitosan polymethacrylic acid (CS-PMAA) carrier, and subsequent characterization of the formulated K fertilizer. A 2k factorial experimnental design was initially implemented to determine significant factors. Results show that polymerization time inversely affects the K content concentration of the K-CS-PMAA fertilizer due to the swelling behavior of chitosan, while K:CS-PMAA ratio directly affects the K content concentration. Upon numerical optimization, the conditions found to maximize K content of the formulated fertilizer are 3000 ppm K+ corresponding to 1.5:1 ratio of the K loading concentration to CS-PMAA carrier for 30 mins polymerization time. The optimum K content of K-CS-PMAA fertilizer is about 34.98% w/w – less than the 44.27% w/w K content of the fertilizer grade, muriate of potash (MOP). The Dynamic Light Scattering (DLS) and Scanning Electron Microscope (SEM) results of 368.1 nm and 75.4 nm, respectively, indicated that K-CS-PMAA is nanosized. The Fourier Transform Infrared Spectroscopy (FT-IR) results proved the presence of CS-PMAA with deviations at 1483.01 and 1405.07 caused by the vibration in the --COO-anion groups of PMAA indicating the attachment of potassium in the nanoparticle. Furthermore, the fertilizer formulated was proved to exhibit slow release behavior with the value of 83.70% K+ release after 48 hours compared to the 99.43% release of MOP

Process Optimization Potassium Nanofertilizer Production via Ionotropic Pre-gelation using Alginate-Chitosan Carrier

Potassium nanofertilizer synthesis by incorporating potassium in alginate-chitosan carrier via ionotropic pre-gelation was optimized to maximize potassium content and develop controlled release fertilizer. Utilizing two-level factorial design, potassium to alginate ratio, calcium chloride to alginate ratio, and pre-gelation time were determined significant. Central Composite Design for optimization was utilized to generate a Response Surface model relating the factors to the response for numerical optimization. Optimum process conditions for maximum potassium content were (1) 1.5:1 (w/w) potassium to alginate ratio, (2) 6.5:117.5 (v/v) calcium chloride to alginate ratio, and (3) 40 minutes pre-gelation time. The potassium content of the fertilizer formulated at optimum condition was successfully verified to contain 29.75 %K(w/w). Characterization showed that potassium was successfully incorporated in the alginatechitosan carrier as shown by the SEM surface images. DLS result showed two peaks at particle sizes near 594.1 nm and 102.8 nm indicating that potassium nanofertilizer was successfully synthesized. Potassium nanofertilizer may be a controlled release fertilizer since only 14.6 %K was released after 24 hours in Britton-Robinson buffer solution. Preliminary costing shows higher cost of production based on raw materials, but it may be offset in the long run by longer availability of nutrient and low fertilizer application rate

Parametric and Optimization Studies on the entrapment of Potassium Fertilizer into Chitosan-Poly(methacrylic acid) Carrier via Ionic Gelation

Nanofertilizer is an emerging technology for exhibiting slow release mechanism of fertilizer application. This slow release mechanism allows increase in nutrient uptake of plants while minimizing environmental pollution; specifically, reducing eutrophication in bodies of water. This study includes parametric and optimization studies for ionic gelation process in the formulation of potassium fertilizer in chitosan polymethacrylic acid (CS-PMAA) carrier, and subsequent characterization of the formulated K fertilizer. A 2k factorial experimnental design was initially implemented to determine significant factors. Results show that polymerization time inversely affects the K content concentration of the K-CS-PMAA fertilizer due to the swelling behavior of chitosan, while K:CS-PMAA ratio directly affects the K content concentration. Upon numerical optimization, the conditions found to maximize K content of the formulated fertilizer are 3000 ppm K+ corresponding to 1.5:1 ratio of the K loading concentration to CS-PMAA carrier for 30 mins polymerization time. The optimum K content of K-CS-PMAA fertilizer is about 34.98% w/w – less than the 44.27% w/w K content of the fertilizer grade, muriate of potash (MOP). The Dynamic Light Scattering (DLS) and Scanning Electron Microscope (SEM) results of 368.1 nm and 75.4 nm, respectively, indicated that K-CS-PMAA is nanosized. The Fourier Transform Infrared Spectroscopy (FT-IR) results proved the presence of CS-PMAA with deviations at 1483.01 and 1405.07 caused by the vibration in the --COO-anion groups of PMAA indicating the attachment of potassium in the nanoparticle. Furthermore, the fertilizer formulated was proved to exhibit slow release behavior with the value of 83.70% K+ release after 48 hours compared to the 99.43% release of MOP

Oil Adsorption Kinetics of Calcium Stearate-Coated Kapok Fibers

This study used a simple and efficient dipping method to prepare oleophilic calcium stearate-coated kapok fibers (CaSt2-KF) with improved hydrophobicity. Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and scanning electron microscopy (SEM) confirmed the deposition of calcium stearate particles on the surface of the kapok fibers. This led to higher surface roughness and improved static water contact angle of 137.4°. The calcium stearate-coated kapok fibers exhibited comparable sorption capacities for kerosene, diesel, and palm oil. However, the highest sorption capacity of 59.69 g/g was observed for motor oil at static conditions. For motor oil in water, the coated fibers exhibited fast initial sorption and a 65% removal efficiency after 30 s. At equilibrium, CaSt2-KF attained a sorption capacity of 33.9 g/g and 92.5% removal efficiency for motor oil in water. The sorption kinetics of pure motor oil and motor oil in water follows the pseudo-second-order kinetic model, and the Elovich model further described chemisorption. Intraparticle diffusion and liquid film diffusion were both present, with the latter being the predominant diffusion mechanism during motor oil sorption