Low-Cost Goethite Nanorods for As (III) and Se (VI) Removal from Water

Arsenite (As(III)) and Selenate (Se(VI)) are universally touted as extremely toxic oxyanions in natural and industrial water systems. Thus, the production of low-cost adsorbents that are scalable and toxic-free is of great importance today. In this work, a large-scale goethite nanorods (α-FeOOH NRs) is synthesized using a modified rapid hydrolysis method. The obtained powder is characterized using different multidisciplinary techniques. Accordingly, the results showed uniform and straight nanorods (length ~400 nm and diameter ~40 nm) resembling cigar-like morphology while the structure is confirmed to be of orthorhombic α-FeOOH phase. The potential application of this material to adsorb As (III) and Se (VI) ions in water is explored. In particular, for initial adsorbate concentrations (~500 µg/L), the removal efficiencies are found exceptional with α-FeOOH doses of 0.33 g/L and ~0.5 g/L for As (III) and Se (VI), respectively. Attractively, the adsorption capacities were estimated using trusted isotherms and then experimentally verified at ultimately high concentrations. Besides, a pH-controlled adsorption study showed that a pH of 5–8 is a favored range for higher ionic uptake, which meets the World Health Organization (WHO) benchmarks of drinking water. To conclude, the α-FeOOH NRs are potential adsorbent for the sustainable removal of toxin ions in water systems

Mechanical performance and feasibility analysis of green concrete prepared with local natural zeolite and waste PET plastic fibers as cement replacements

Green concrete is a sustainable composite material having natural and waste materials replacing carbon dioxide gas-producing cement, and aggregates in the concrete. Thus, it significantly contributes in reducing greenhouse gas emissions and improves the economic viability of a country as well. Literature suggests that research on the development of green concrete is evolving with widely-available natural and waste materials. Considering the need for the development of green concrete, the current research is conducted. It was hypothesized that the mechanical performance of green concrete prepared by substituting cement with Natural Zeolite (NZ) and waste Polyethylene Terephthalate (PET) fibers will yield stronger, cost-effective, and environmentally green concrete for the construction industry. The microstructure, morphology, and surface properties of the locally extracted NZ were characterized using X-ray Diffraction, SEM and BET, respectively. The influence of quantity, shape, orientations, and surface of NZ and PET fibers along with varying curing times, i.e., 28, 90, and 180 days were considered for experimentation. The main findings of this study are that two optimum proportions for the concrete mixtures are obtained: the first one was 10 % NZ while the other one was 2.5 % PET, and 15 % NZ, and 1.0 % PET. These optimum mixing ratios were found to enhance the compressive strength of concrete, reduce the production cost, and reuse waste PET bottles effectively, which are key points of this study. Furthermore, the workability of the fresh concrete was improved with higher proportions of PET rather than NZ. Finally, the findings of the current research highlight a pragmatic remedial solution for saving energy, turning non-decomposable waste into useful materials for green concrete, and simultaneously contributing to a cleaner environment

Productive and Sustainable H₂ Production from Waste Aluminum Using Copper Oxides-Based Graphene Nanocatalysts: A Techno-Economic Analysis

Hydrogen has universally been considered a reliable source of future clean energy. Its energy conversion, processing, transportation, and storage are techno-economically promising for sustainable energy. This study attempts to maximize the production of H2 energy using nanocatalysts from waste aluminum chips, an abundant metal that is considered a potential storage tank of H2 energy with high energy density. The present study indicates that the use of waste aluminum chips in the production of H2 gas will be free of cost since the reaction by-product, Al2O3, is denser and can be sold at a higher price than the raw materials, which makes the production cost more efficient and feasible. The current framework investigates seven different copper oxide-based graphene nanocomposites that are synthesized by utilizing green methods and that are well-characterized in terms of their structural, morphological, and surface properties. Reduced graphene oxide (rGO) and multi-layer graphene (MLG) are used as graphene substrates for CuO and Cu2O NPs, respectively. These graphene materials exhibited extraordinary catalytic activity, while their copper oxide composites exhibited a complete reaction with feasible techno-economic production. The results revealed that the H2 production yield and rates increased twofold with the use of these nanocatalysts. The present study recommends the optimum reactor design considerations and reaction parameters that minimize water vaporization in the reaction and suggests practical solutions to quantify and separate it. Furthermore, the present study affords an economic feasibility approach to producing H2 gas that is competitive and efficient. The cost of producing 1 kg of H2 gas from waste aluminum chips is USD 6.70, which is both economically feasible and technically applicable. The unit cost of H2 gas can be steeply reduced by building large-scale plants offering mass production. Finally, the predicted approach is applicable in large, medium, and small cities that can collect industrial waste aluminum in bulk to generate large-scale energy units

Productive and Sustainable H2 Production from Waste Aluminum Using Copper Oxides-Based Graphene Nanocatalysts: A Techno-Economic Analysis

Hydrogen has universally been considered a reliable source of future clean energy. Its energy conversion, processing, transportation, and storage are techno-economically promising for sustainable energy. This study attempts to maximize the production of H2 energy using nanocatalysts from waste aluminum chips, an abundant metal that is considered a potential storage tank of H2 energy with high energy density. The present study indicates that the use of waste aluminum chips in the production of H2 gas will be free of cost since the reaction by-product, Al2O3, is denser and can be sold at a higher price than the raw materials, which makes the production cost more efficient and feasible. The current framework investigates seven different copper oxide-based graphene nanocomposites that are synthesized by utilizing green methods and that are well-characterized in terms of their structural, morphological, and surface properties. Reduced graphene oxide (rGO) and multi-layer graphene (MLG) are used as graphene substrates for CuO and Cu2O NPs, respectively. These graphene materials exhibited extraordinary catalytic activity, while their copper oxide composites exhibited a complete reaction with feasible techno-economic production. The results revealed that the H2 production yield and rates increased twofold with the use of these nanocatalysts. The present study recommends the optimum reactor design considerations and reaction parameters that minimize water vaporization in the reaction and suggests practical solutions to quantify and separate it. Furthermore, the present study affords an economic feasibility approach to producing H2 gas that is competitive and efficient. The cost of producing 1 kg of H2 gas from waste aluminum chips is USD 6.70, which is both economically feasible and technically applicable. The unit cost of H2 gas can be steeply reduced by building large-scale plants offering mass production. Finally, the predicted approach is applicable in large, medium, and small cities that can collect industrial waste aluminum in bulk to generate large-scale energy units