Analysis of Challenges for Blockchain Adoption in Enterprise Distributed Applications

Decentralization, auditability, smart execution, and security are four ways that blockchain technology (BCT) differs from current cutting-edge technologies based on client-server architecture. Without the need of any middlemen, blockchain technology builds trust between untrustworthy parties. By employing its distinctive properties, blockchain technology is presently used to address the problems of enterprise distributed applications (EDAs) to some extent. As a result, businesses involved in a wide range of industries have shown interest in it. Despite being praised as tool for businesses to create secure applications, BCT is still not widely used. The objective of the current study is to use an extension of the technology acceptance model (TAM2), constituted by 15 hypotheses (H1–H15), to address the factors that influence professionals' desire to adopt the BCT in the EDAs. In order to achieve the research objective, the study consists of a quantitative non-experimental correlational method with the goal of creating an empirical model to evaluate the relationship between perceived usefulness, perceived ease of use, scalability, effort, performance, adaptability, maintainability, experience, and blockchain adoption in India with a focus on EDAs. Descriptive analysis, discriminant analysis, multiple linear regression, ANOVA, homoscedasticity, multicollinearity, reliability, linearity, survey question's normality, and independent errors are conducted to analyze survey data from a sample of 396 IT professionals from various firms in India. The findings show that IT professionals' desire to employ the BCT in EDAs are positively impacted by all the hypothesis except H3 and H8 that has no impact on IT professionals' desire to employ BCT

Quadrupole Electric Field for Erasing the Fine Structure Splitting of a Nanowire Quantum Dot Entangled Photon Source

Entanglement is an essential tool in quantum information processing (QIP), for example, to achieve a secure quantum communication network and quantum computing. Semiconductor quantum dots can generate on-demand entangled photon pairs via the biexciton-exciton cascade. These solid-state sources are currently limited in their applications due to two major challenges: first is the collection efficiency since only a fraction of a percent of the emitted photons from the quantum dot can be collected due to its isotropic emission profile; and second is the FSS that causes an energy splitting of the intermediate exciton state —it arises due to strain and structural asymmetry of the quantum dot and degrades its measured entanglement fidelity. Quantum dots have been integrated into photonic structures such as microcavities and nanowires to enhance their collection efficiency by coupling the emitted photons to the cavity or fundamental nanowire waveguide mode. However, the fine structure splitting still remains a major challenge, and although many post growth perturbation techniques have been implemented to tune and completely erase the FSS of a self-assembled Quantum Dot (QD), erasing the FSS of a QD in a photonic structure has not yet been achieved. In this thesis, we propose and then demonstrate for the first time the tuning of the FSS for a indium arsenic phosphide (InAsP) QD in a tapered indium phosphide (InP) nanowire by applying a quadrupole electric field. Out of all the post-growth perturbation based FSS erasing techniques, electric fields, and stress fields have been the most successful ones in erasing the FSS of a self-assembled quantum dot. However, implementing them on a nanowire quantum dot source is not a straightforward solution to its FSS problem. Stress field techniques are difficult to implement on a nanowire quantum dot source due to the thick nanowire shell around the quantum dot, where most of the applied external stress field relaxes and therefore doesn't reach the embedded quantum dot. The electric field on the other hand is known for reducing the electron-hole (e-h) overlap and therefore if implemented in its conventional form will reduce the QD brightness while erasing its FSS. Moreover, both stress and electric field techniques require multiple perturbation axes to erase the FSS of a quantum dot with any possible dipole orientation or macroscopic asymmetry. We overcame these problems by developing a novel approach of applying a quadrupole electric field along the plane of an embedded quantum dot inside the nanowire. We show theoretically that a quadrupole electric field corrects for the spatial asymmetry of the excitonic wave function for any quantum dot dipole orientation (θ = 0°, 10°, 20°) inside a nanowire and completely erases its fine structure splitting from 11 μeV to 0.05 μeV while maintaining a strong e-h overlap (β = 99%, 90, for a dot with θ = 0°, 20°) even after applying a correction quadrupole electric field. To experimentally demonstrate our theory we fabricated two prototypes of electrically gated InAsP/InP QD nanowire devices, with four metal gates precisely positioned around an individual InAsP quantum dot inside a vertically standing InP nanowire. The electrooptical characterization of an electrically gated nanowire quantum dot device shows the FSS tuning from 7 μeV to 4 μeV by application of a quadrupole electric field. Although we have achieved a FSS tuning in nanowire device, tuning and completely erasing the FSS of a nanowire device will require a significant improvement in the fabricated device design. This will require reducing the dimension of the metal gates and aligning it perfectly to touch the sidewalls of the vertical nanowires. We also observed the degradation in the QD emission while exposing it to 100 kV electron-beam (e-beam). Therefore, we propose a bottom-up approach of fabricating the device by first patterning the metal gates by e-beam lithography on a wafer and then selectively growing the nanowire QD source at its center by the conventional site-selected vapor-liquid-Solid (VLS) growth method. In principle, such an electrically gated device will erase the FSS of a nanowire quantum dot source and will bring it closer to becoming a deterministic source of entangled photons with near-unity fidelity and collection efficiency

Ab initio study of NaSrSb and NaBaSb as potential thermoelectric prospects

Zintl phases are excellent thermoelectric prospects to put the waste heat to good use. In the quest of the same, using first-principles methods combined with Boltzmann transport theory, we explored two recent phases NaSrSb and NaBaSb. We found low lattice thermal conductivity of 1.9 and 1.3 W m$^{-1}$ K$^{-1}$ at 300~K for NaSrSb and NaBaSb, respectively, which are of the same order as other potential Zintl phases such as Sr$_3$AlSb$_3$ and BaCuSb. We account for such low values to short phonon lifetimes, small phonon group velocities, and lattice anharmonicity in the crystal structure. The calculated electrical transport parameters based on acoustic deformation potential, ionized impurity, and polar optical phonon scattering mechanisms reveal large Seebeck coefficients for both materials. Further, we obtain a high figure of merit of ZT$\sim$2.0 at 900~K for \textit{n}-type NaSrSb. On the other hand, the figure of merit of \textit{n}-type NaBaSb surpasses the unity. We are optimistic about our findings and believe our work would set a basis for future experimental investigations.Comment: 10 figures, 1 tabl