Effect of maleated compatibiliser (PBS-g-MA) addition on the flexural properties and water absorption of poly(butylene succinate)/kenaf bast fibre composites

Poly(butylene succinate) (PBS) composites with 30 wt.% loading of kenaf bast fibre (KBF) were compatibilised with 5 wt.% maleated PBS (PBS-g-MA). The maleic anhydride (MA) concentration in the compatibiliser was either 3, 5, 7 or 10 phr. In general, the compatibilised composites showed better flexural properties than the un-compatibilised composite. The highest increment in the flexural strength and modulus of 12.7 and 8.9%, respectively, were obtained with the addition of PBS-g-MA with MA concentration of 5 phr. Compatibilised and un-compatibilised PBS/KBF composites were immersed in distilled water for 90 days. The absorption of water by all the composites was observed to follow Fick’s law. The equilibrium moisture content, Mm, of the composites with PBS-g-MA at 3, 5 and 7 phr of MA concentrations was lower than that of the un-compatibilised composite due to improved fiber-matrix interfacial adhesion and reduction of voids content. Both un-compatibilised and compatibilised composites showed dimensional instability after the water absorption. This was probably due to the degradation of the fibre-matrix interfacial adhesion and fibre integrity. The flexural properties of these composites decreased after the water absorption. After re-drying only some of the flexural properties were recovered from plasticizing effect of water

Mechanical, thermal and morphological properties of epoxy resin toughened with epoxidized soybean oil

Biobased toughened thermosetting polymer blend was prepared by incorporating epoxidized soybean oil (ESO) into a petroleum-based epoxy (DGEBA) in different composition ratios. The mechanical properties (tensile and flexural tests) of the ESO/DGEBA thermoset blends were determined. Thermal properties of the blends were characterized using thermogravimetric analysis. The result showed that, the tensile and flexural properties decreased with increasing of ESO content. However, a slight increase in the strength properties was observed at 10% of ESO content. A significant enhancement in impact strength proves the role of ESO acting as a plasticizer in the blends as well as improve the toughness properties of ESO/DGEBA thermoset blend. As the ESO content increase, the thermal stability of ESO/DGEBA thermoset blend has decreased might be due to reduced cross-linking density of the epoxy network. Further investigations on morphological properties were also done to correlate the mechanical properties of ESO/DGEBA thermoset blend