106 research outputs found

    Theoretical Treatment of Electronic Distribution of Phynelene and Thiophene Systems

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    Present work deals with density functional theory to investigate the electronic distribution of phynelene and thiophene compounds and their adducts, the position of interaction between the two structures changes to include six systems. The  electronic properties were studied in two ways, the vertical energy method and vertical orbital method include the chemical potential, chemical molecular hardness, chemical softness, electrophilic index and polarizability. The geometry optimization was calculated at b3LYP level of theory. The results showed that the new structures are more reactive,  they have low chemical hardness with large electrophilicity.

    System for Visually Disabled through Wearables Utilizing Arduino and Ultrasound

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    Blindness and other vision impairment is on the rise with more than 2.2 billion people worldwide are affected including children, elder persons, pregnant women, chronically ill and disabled persons who experience difficulties in mobility and being independent. Some of the conventional assistances like usage of white cane or a guide dog lacks the ability to cater all the needs of the blind people. The present research outlines a wearable system with Arduino and ultrasound equipment to improve the walking ability of the persons with vision impairment. From the use of the proposed system, there is the potentiality of detecting obstacles in real time and also determine the location hence minimizing the dependence on other help. The system consists of two wearable components: a glove and a belt which contain ultrasonic sensors, GPS module and GSM module and a vibration motor. The glove senses the objects that are in front of the user while the belt detects stairs or any other raised ground. The method used here was the development and calibration of these components separately then brought together to form a coherent entire system where all the component was precise and reliable. The findings show that the proposed system is successful to identify obstacles on its path before the user comes close to them and gives out alerts through sound and touch. GPS and GSM modules provide an extra layer of security to the kids by allowing a tracking of their location in real time

    Effects of Some Essential Oils on Aspergillus flavus Growth and Aflatoxin Production

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    The present study aimed at investigating the effects of some essential oils on inhibiting fungal growth of A. flavus and aflatoxin production. Clove oil was found as the best among the six different oils tested against the radial growth at the concentration of 0.05. mL/100ml. However the other oils were also significantly better than the control except the Pumpkin oil. Different concentrations (0.00, 0.01, 0.03 and 0.05 ml/100ml) of only three of the oils were tested against the radial growth of A. flavus. Clove and Cumin oils were significantly effective than the control at all these concentrations. Although Pumpkin oil was slightly more effective than the control at its higher concentration (0.05) ml/100ml), it was not effective at its lower concentrations (0.01 and 0.03 ml/100ml). Clove oil was also the best in suppressing mycelial growth at the concentration of 0.05 ml/100ml. However, the other oils were also significantly better than the control, while, Pumpkin oil was non-effective. Spore germination was also affected by the oils tested. Clove oil gave complete inhibition at its higher concentration followed by Cumin, Rehan, Garlic and Desert date, while Pumpkin oil was the least one. Aflatoxin production was highly affected by the essential oils tested. Clove and Cumin exhibited a complete inhibition, followed by Rehan; Garlic and Desert date while Pumpkin oil was non-effective

    Evaluation of Antimicrobial Activity of Moringa Oleifera Leaf Extracts Against Pathogenic Bacteria Isolated From Urinary Tract Infected Patients

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    Antibiotic resistance has increased substantially in recent years and is posing an ever-increasing therapeutic problem. One of the methods to reduce the resistance to antibiotics is by using antibiotic resistance inhibitors from plants. The aim of this study is to evaluate the antibacterial properties of aqueous, petroleum ether and methanolic leaf extracts of Moringa oleifera plant against pathogenic bacteria isolated from urinary tract infected patients and five standard strains of American type culture collection. The antibacterial activity of Moringa oleifera leaf extracts was determined in vitro, using Cup plate method, and compared with sensitivity testing of some antibiotic agents using disc diffusion method. The results obtained showed that all concentration of methanolic extracts of Moringa oleifera had high inhibitory effects on S. aureus ATCC25923, K. pneumoniae ATCC35637 standard strains and the S. aureus, S. saprophyticus and E.coli isolated from UTI. The three concentration of water extract had inhibitory effects only on Proteus vulgaris NCTC8196 strain. The petroleum ether extracts showed no inhibitory activity on any organism. These results were compared with standard antibiotics Amikacin, Ciprofloxacin, and Norfloxacin which showed moderate sensitivity against S. aureus and Amikacin was completely resistant to K. pneumoniae isolated from UTI. These results provide valuable information that Moringa oleifera hold great promise as highly effective antibacterial agents

    Dark Iron-Catalyzed Reactions in Acidic and Viscous Aerosol Systems Efficiently Form Secondary Brown Carbon

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    Iron-driven secondary brown carbon formation reactions from water-soluble organics in cloud droplets and aerosols create insoluble and soluble products of emerging atmospheric importance. This work shows, for the first time, results on dark iron-catalyzed polymerization of catechol forming insoluble black polycatechol particles and colored water-soluble oligomers under conditions characteristic of viscous multicomponent aerosol systems with relatively high ionic strength (I = 1–12 m) and acidic pH (∼2). These systems contain ammonium sulfate (AS)/nitrate (AN) and C3–C5 dicarboxylic acids, namely, malonic, malic, succinic, and glutaric acids. Using dynamic light scattering (DLS) and ultra high pressure liquid chromatography-mass spectrometry (UHPLC-MS), we show results on the rate of particle growth/agglomeration and identity of soluble oligomeric reaction products. We found that increasing I above 1 m and adding diacids with oxygen-to-carbon molar ratio (O:C \u3e 1) significantly reduced the rate of polycatechol formation/aggregation by a factor of 1.3 ± 0.4 in AS solution in the first 60 min of reaction time. Using AN, rates were too slow to be quantified using DLS, but particles formed after 24 h reaction time. These results were explained by the relative concentration and affinity of ligands to Fe(III). We also report detectable amounts of soluble and colored oligomers in reactions with a slow rate of polycatechol formation, including organonitrogen compounds. These results highlight that brown carbon formation from iron chemistry is efficient under a wide range of aerosol physical states and chemical composition

    Utilization of adjusted body weight for dosing unfractionated heparin in obese patients with venous thromboembolism: A retrospective matched cohort study

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    Purpose: To evaluate the effectiveness of adjusted body weight (AjBW)-based dosing of unfractionated heparin (UFH) in obese patients vis a vis actual body weight (ABW)-based dosing in non-obese patients with venous thromboembolism (VTE).Methods: A retrospective chart review was conducted for obese and non-obese patients initiated on UFH for treating VTE from September 2013 to December 2014. Patients were excluded from the study if they were under 18 years old, developed heparin-induced thrombocytopenia during treatment, received thrombolytic therapy prior to UFH, or received UFH at a dose that did not follow the institution’s protocol. The primary objective was to assess the efficacy of dosing UFH based on AjBW in achieving a therapeutic activated partial thromboplastin time (aPTT) within the first 24 h in obese patients, in comparison to the standard ABW-dosing for non-obese.Results: Of the 57 patients included in the study, 27 patients (47.4 %) were obese, and 30 patients (52.6 %) were non-obese; 16 (59.25 %) of the obese patients achieved a therapeutic aPTT within the first 24 h of AjBW-based dosed UFH, while 18 (60 %) of the non-obese patients achieved a therapeutic aPTT within the first 24 h of ABW-based dosed UFH (p = 0.45).Conclusion: AjBW-based dosing of UFH in obese patients demonstrates comparable efficacy to ABWbased dosing in non-obese patients. Keywords: Obesity, Unfractionated heparin, Venous thromboembolism, Adjusted body weight, Ideal body weigh

    Novel Classes of Bipolar Soft Generalized Topological Structures: Compactness and Homeomorphisms

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    The purpose of this paper is to define bipolar soft generalized compact sets and bipolar soft generalized compact spaces. The structures of g~~-centralized bipolar soft generalized closed sets collection in a bipolar soft generalized compact space are given. Moreover, some main properties of bipolar soft generalized compactness are discussed and their relationships are studied. The concept of a bipolar soft generalized compactness is introduced and it investigates under what condition a bipolar soft generalized topological space forms a bipolar soft generalized compact space. The relation between bipolar soft generalized compact space and soft generalized compact space is proposed. Furthermore, some further properties of bipolar soft mappings, such as bipolar soft composite mappings, are presented and some of their characteristics are explained. Additionally, novel classes of bipolar soft mapping such as bipolar soft generalized continuous, bipolar soft generalized open, and bipolar soft generalized closed mappings are defined. Finally, some results and counterexamples are obtained

    Reactivity of aminophenols in forming nitrogen-containing brown carbon from iron-catalyzed reactions

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    Nitrogen-containing organic carbon (NOC) in atmospheric particles is an important class of brown carbon (BrC). Redox active NOC like aminophenols received little attention in their ability to form BrC. Here we show that iron can catalyze dark oxidative oligomerization of o- and p-aminophenols under simulated aerosol and cloud conditions (pH 1–7, and ionic strength 0.01–1 M). Homogeneous aqueous phase reactions were conducted using soluble Fe(III), where particle growth/agglomeration were monitored using dynamic light scattering. Mass yield experiments of insoluble soot-like dark brown to black particles were as high as 40%. Hygroscopicity growth factors (κ) of these insoluble products under sub- and super-saturated conditions ranged from 0.4–0.6, higher than that of levoglucosan, a prominent proxy for biomass burning organic aerosol (BBOA). Soluble products analyzed using chromatography and mass spectrometry revealed the formation of ring coupling products of o- and p-aminophenols and their primary oxidation products. Heterogeneous reactions of aminophenol were also conducted using Arizona Test Dust (AZTD) under simulated aging conditions, and showed clear changes to optical properties, morphology, mixing state, and chemical composition. These results highlight the important role of iron redox chemistry in BrC formation under atmospherically relevant conditions

    Synthesis and characterization of sodium alginate/polyvinyl alcohol/zinc oxide/iron oxide nanocomposites for electrochemical applications

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    Polymer nanocomposites films, based on sodium alginate (NaAlg) and polyvinyl alcohol (PVA) complexed with zinc oxide nanoparticles (ZnO NPs) and iron oxide nanorods (Fe3O4 NRs) as nanofiller, were prepared by solution casting technique. Different techniques were used to describe the prepared films. XRD and FTIR were used to pinpoint the complexation of the nanofiller with the polymer mixture. The XRD investigation verified the existence of the crystalline peaks of ZnO/Fe3O4 NPs in the polymeric matrices. The average particle size of nanocomposite was 23 nm. TEM image of the ZnO nanopowder confirming the spherical form of nanoparticles with average size 30 nm. The TEM image of Fe3O4 NRs reveals the free nanorods are around 9–23 nm in diameter and 130–350 nm in length. Peak positions and intensity variations in the FTIR absorption spectra are observed when the concentration increases from 2 to 8 wt% of ZnO NPs/Fe3O4 NRs. AC conductivity showed that the NaAlg/PVA-(8 wt%) ZnO/Fe3O4 NPs nanocomposites have higher electrical conductivity than NaAlg/PVA blend. For samples of 8% ZnO/Fe3O4, the (Formula presented.) of nanocomposites reached 3.66 × 10−8 S cm−1. ZnO/Fe3O4 nanoparticles considerably improved the nanocomposites' ability to conduct electricity. For the development of functional composite materials for the manufacture of electrical devices, sensors, and high-energy storage capacitors, the enhanced characteristics of synthesized NaAlg/PVA-ZnO/Fe3O4 nanocomposites can be helpful

    Perception of consanguineous marriage among the qatari population

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    BackgroundHereditary blood diseases are widespread among the Arab population due to the high rates of consanguineous marriages; research regarding the perception of consanguineous marriage in some countries, such as Qatar, is extremely scarce. Therefore, this study aimed to investigate the prevalence of consanguineous marriage and assess the perception of consanguineous marriage among the Qatari population.MethodsA cross-sectional study used a self-administered questionnaire among 395 Qatari adults aged 18–35 who attended primary healthcare institutions in Qatar. A convenience sampling technique was used to select the study participants. An independent t-test was used to compare the significance of the mean between the two groups with positive and negative perceptions of consanguineous marriage. Categorical data were analyzed for association using the chi-square or Fisher's exact test. Finally, a multiple logistic regression analysis was conducted to determine the significant predictors of the positive perception of consanguineous marriage. A significant level was set at p < 0.05.ResultsApproximately 45% of the participants had a positive perception toward consanguineous marriage, and the most common reason stated by those participants was “habit and traditions.” The prevalence of consanguineous marriage among married couples was 62.6%, and among those with consanguineous marriage, most were married to first cousins (81.7%). Moreover, compared to the participants with negative perceptions of consanguineous marriage, those with positive ones were significantly older, married, with lower educational levels and higher monthly income levels, did not hear about glucose-6-phosphate dehydrogenase (G6PD) deficiency, did not know what kinds of diseases are being screened in the premarital test, and were married to a relative.ConclusionThe prevalence of consanguineous marriage is high among the Qatari population, and this requires an immediate need for community-based campaigns to raise public awareness about the problem and its potential impact
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