Exploring the Synergistic Effects of Dual‐Layer Electrodes for High Power Li‐Ion Batteries

Abstract Invited for this issue's Front Cover are the group of Prof. Janine Mauzeroll and Prof. Steen B. Schougaard. The front cover picture shows Li‐metal cells which contain two active materials (red and blue). The cell on the left has both materials intermixed (blended electrode), while the cell on the right has them segregated (dual‐layer electrode). The brightness emitted by the bulbs, the position on the scale, and the distribution of Li+ in the liquid phase (green orbs) reflects the high‐power capabilities of the dual‐layer architecture. Cover design by Jeremy I. G. Dawkins, Janine Mauzeroll and Steen B. Schougaard. Read the full text of the Research Article at 10.1002/celc.202300279

Exploring the Synergistic Effects of Dual‐Layer Electrodes for High Power Li‐Ion Batteries

Abstract The electrification of the transport sector has created an increasing demand for lithium‐ion batteries that can provide high power intermittently while maintaining a high energy density. Given the difficulty in designing a single redox material with both high power and energy density, electrodes based on composites of several electroactive materials optimized for power or capacity are being studied extensively. Among others, fast‐charging LiFePO4 and high energy Li(NixMnyCoz)O2 are commonly employed in industrial cell manufacturing. This study focuses on comparing different approaches to combining these two active materials into a single electrode. These arrangements were compared using standard electrochemical (dis)charge procedures and using synchrotron X‐ray fluorescence to identify variations in solution concentration gradient formation. The electrochemical performance of the layered electrodes with the high‐power material on top is found to be enhanced relative to its blended electrode counterpart when (dis)charged at the same specific currents. These findings highlight dual‐layer lithium‐ion batteries as an inexpensive way of increasing energy and power density of lithium‐ion batteries as well as a model system to study and exploit the synergistic effects of blended electrodes