The Metallacyclopentane-Olefin Interchange Reaction

Tris(triphenylphosphine)tetramethylenenickel(II) and biscyclopentadienyltetramethylenetitanium, prepared from the reaction of a 1,4-dilithiobutane and the transition metal dihalides react with olefins to produce substituted metallacyclopentanes; the stereochemistry and substitution pattern of the metallocycles formed from propene, octa-1,7-diene, and norbornadiene has been determined

Mechanism of the fluxional behaviour in (1–5-η-cycloheptadienyl)-(1–5-η-cycloheptatrienyl)iron

Evidence for a 1.2-shift mechanism of the 1-5-η-cycloheptatrienyl moiety with respect to the central iron atom of the title compound is presented together with absolute assignments of the ^(13)C n.m.r. chemical shifts of the C_(7)H_(7) ring. A low-temperature rocking motion of both rings can be frozen out at -70 °C

Visualization of superposition of macroscopically distinct states

We propose a method of visualizing superpositions of macroscopically distinct states in many-body pure states. We introduce a visualization function, which is a coarse-grained quasi joint probability density for two or more hermitian additive operators. If a state contains superpositions of macroscopically distinct states, one can visualize them by plotting the visualization function for appropriately taken operators. We also explain how to efficiently find appropriate operators for a given state. As examples, we visualize four states containing superpositions of macroscopically distinct states: the ground state of the XY model, that of the Heisenberg antiferromagnet, a state in Shor's factoring algorithm, and a state in Grover's quantum search algorithm. Although the visualization function can take negative values, it becomes non-negative (hence becomes a coarse-grained joint probability density) if the characteristic width of the coarse-graining function used in the visualization function is sufficiently large.Comment: 12pages, 21figure

Emergence of swing-to-stance transition from interlocking mechanism in horse hindlimb

The bodies of quadrupeds have very complex muscle-tendon structure. In particular, it is known that in the horse hindlimb, multiple joints in the leg are remarkably interlocked due to the muscle-tendon structure. Although the function of these interlocking mechanisms during standing has been investigated in the field of anatomy, the function related to the emergence of limb trajectory during dynamic walking has not been revealed. To investigate the role of the interlocking mechanism, we developed a robot model imitating the muscle-tendon arrangement and the dynamics of a horse hindlimb. In the walking experiment, the robot autonomously generated a limb trajectory with a smooth transition between the swing phase and the stance phase by simply swinging the hip joint with sinusoidal input. Moreover, we compared the joint angles between successful and failed walking. The compared results indicate that the extension of the fetlock joint after hoof touchdown plays the crucial role in emergence of a function of supporting body.K. Miyashita, Y. Masuda, M. Gunji, A. Fukuhara, K. Tadakuma and M. Ishikawa, "Emergence of Swing-to-Stance Transition from Interlocking Mechanism in Horse Hindlimb," 2020 IEEE/RSJ International Conference on Intelligent Robots and Systems (IROS), Las Vegas, NV, USA, 2020, pp. 7860-7865, doi: 10.1109/IROS45743.2020.9341026

Energies and collapse times of symmetric and symmetry-breaking states of finite systems with a U(1) symmetry

We study quantum systems of volume V, which will exhibit the breaking of a U(1) symmetry in the limit of V \to \infty, when V is large but finite. We estimate the energy difference between the `symmetric ground state' (SGS), which is the lowest-energy state that does not breaks the symmetry, and a `pure phase vacuum' (PPV), which approaches a symmetry-breaking vacuum as V \to \infty. Under some natural postulates on the energy of the SGS, it is shown that PPVs always have a higher energy than the SGS, and we derive a lower bound of the excess energy. We argue that the lower bound is O(V^0), which becomes much larger than the excitation energies of low-lying excited states for a large V. We also discuss the collapse time of PPVs for interacting many bosons. It is shown that the wave function collapses in a microscopic time scale, because PPVs are not energy eigenstates. We show, however, that for PPVs the expectation value of any observable, which is a finite polynomial of boson operators and their derivatives, does not collapse for a macroscopic time scale. In this sense, the collapse time of PPVs is macroscopically long.Comment: In the revised manuscript, Eq. (22), Ref. [8], and Notes [13], [15] and [17] have been adde

Comprehensive Robot Model Based on Horse Anatomy : Towards Understanding the Passive Dynamics of Limbs

The 11th International Symposium on Adaptive Motion of Animals and Machines. Kobe University, Japan. 2023-06-06/09. Adaptive Motion of Animals and Machines Organizing Committee.Poster Session P1

Transcriptionally linked simultaneous overexpression of P450 genes for broad-spectrum herbicide resistance

雑草が獲得した最強の除草剤抵抗性メカニズムの解明 --解毒酵素の一斉活性化--. 京都大学プレスリリース. 2023-06-14.Broad-spectrum herbicide resistance (BSHR), often linked to weeds with metabolism-based herbicide resistance, poses a threat to food production. Past studies have revealed that overexpression of catalytically promiscuous enzymes explains BSHR in some weeds; however, the mechanism of BSHR expression remains poorly understood. Here, we investigated the molecular basis of high-level resistance to diclofop-methyl in BSHR late watergrass (Echinochloa phyllopogon) found in the United States, which cannot be solely explained by the overexpression of promiscuous cytochrome P450 monooxygenases CYP81A12/21. The BSHR late watergrass line rapidly produced 2 distinct hydroxylated diclofop acids, only 1 of which was the major metabolite produced by CYP81A12/21. RNA-seq and subsequent reverse transcription quantitative PCR (RT-qPCR)-based segregation screening identified the transcriptionally linked overexpression of a gene, CYP709C69, with CYP81A12/21 in the BSHR line. The gene conferred diclofop-methyl resistance in plants and produced another hydroxylated diclofop acid in yeast (Saccharomyces cerevisiae). Unlike CYP81A12/21, CYP709C69 showed no other herbicide-metabolizing function except for a presumed clomazone-activating function. The overexpression of the 3 herbicide-metabolizing genes was also identified in another BSHR late watergrass in Japan, suggesting a convergence of BSHR evolution at the molecular level. Synteny analysis of the P450 genes implied that they are located at mutually independent loci, which supports the idea that a single trans-element regulates the 3 genes. We propose that transcriptionally linked simultaneous overexpression of herbicide-metabolizing genes enhances and broadens the metabolic resistance in weeds. The convergence of the complex mechanism in BSHR late watergrass from 2 countries suggests that BSHR evolved through co-opting a conserved gene regulatory system in late watergrass

Sensitivity Improvement of Infrared Imaging Video Bolometer for Divertor Plasma Measurement

The sensitivity of an infrared imaging video bolometer (IRVB) was improved for the measurement of relatively low energy plasma radiation from the viewpoint of the metal foil absorber material. The photon energy of the radiation was considered up to 1 keV for the divertor plasma measurement. The thickness of the foil absorber was evaluated not only for conventional heavy elements, e.g., platinum, but also for light elements by the relation between the photon energy and attenuation length and by mechanical strength. A heat-transfer calculation using ANSYS suggested that light elements with practical foil thickness provide a higher temperature rise of the foil absorber compared with heavier elements with practical foil thickness. The maximum of the temperature rise was evaluated using He–Ne laser irradiation onto absorber samples. The material dependence of the temperature rise has a similar tendency between calculations and experiments. Experimentally, the sensitivity of the IRVB improved from 280 to 110 µW/cm2 using titanium with 1 µm thickness compared with conventional platinum with 2.5 µm thickness. Consequently, the signal-to-noise ratio of the IRVB could be improved from 2.8 to 9.1