Analytical fuel property effects--small combustors

The consequences of using broad-property fuels in both conventional and advanced state-of-the-art small gas turbine combustors are assessed. Eight combustor concepts were selected for initial screening, of these, four final combustor concepts were chosen for further detailed analysis. These included the dual orifice injector baseline combustor (a current production 250-C30 engine combustor) two baseline airblast injected modifications, short and piloted prechamber combustors, and an advanced airblast injected, variable geometry air staged combustor. Final predictions employed the use of the STAC-I computer code. This quasi 2-D model includes real fuel properties, effects of injector type on atomization, detailed droplet dynamics, and multistep chemical kinetics. In general, fuel property effects on various combustor concepts can be classified as chemical or physical in nature. Predictions indicate that fuel chemistry has a significant effect on flame radiation, liner wall temperature, and smoke emission. Fuel physical properties that govern atomization quality and evaporation rates are predicted to affect ignition and lean-blowout limits, combustion efficiency, unburned hydrocarbon, and carbon monoxide emissions

Investigation of measures to reduce dog attacks and promote responsible ownership amongst dog owners with dog control issues in the UK

The overall aim of the project is to identify methods to reduce dog attacks and dog control issues as well as provide evidence-based recommendations to promote responsible dog ownership amongst owners with dog control issues. The project examined contemporary enforcement practice and also explored risk factors related to dog attacks

The Prototypical Young L/T-Transition Dwarf HD 203030B Likely Has Planetary Mass

Upon its discovery in 2006, the young L7.5 companion to the solar analog HD 203030 was found to be unusual in being $\approx$200 K cooler than older late-L dwarfs. HD 203030B offered the first clear indication that the effective temperature at the L-to-T spectral type transition depends on surface gravity: now a well-known characteristic of low-gravity ultra-cool dwarfs. An initial age analysis of the G8V primary star indicated that the system was 130--400 Myr old, and so the companion between 12--31 $M_{\rm Jup}$. Using moderate resolution near-infrared spectra of HD 203030B, we now find features of very low gravity comparable to those of 10--150 Myr-old L7--L8 dwarfs. We also obtained more accurate near infrared and {\sl Spitzer}/IRAC photometry, and find a $(J-K)_{\rm MKO}$ color of $2.56\pm0.13$ mag---comparable to those observed in other young planetary-mass objects---and a luminosity of log($L_{\rm bol}/L_{\odot}$)$\,=\,-4.75\pm0.04$ dex. We further reassess the evidence for the young age of the host star, HD 203030, with a more comprehensive analysis of the photometry and updated stellar activity measurements and age calibrations. Summarizing the age diagnostics for both components of the binary, we adopt an age of 100 Myr for HD 203030B and an age range of 30--150 Myr. Using cloudy evolutionary models, the new companion age range and luminosity result in a mass of 11 $M_{\rm Jup}$ with a range of 8--15 $M_{\rm Jup}$, and an effective temperature of $1040\pm50$ K.Comment: 12 pages, 7 figures, accepted for publication in A

Total syntheses of conformationally-locked difluorinated pentopyranose analogues and a pentopyranosyl phosphate mimetic

Trifluoroethanol has been elaborated, via a telescoped sequence involving a metalated difluoroenol, a difluoroallylic alcohol, [2,3]-Wittig rearrangement, and ultimately an RCM reaction and requiring minimal intermediate purification, to a number of cyclooctenone intermediates. Epoxidation of these intermediates followed by transannular ring opening or dihydroxylation, then transannular hemiacetalization delivers novel bicyclic analogues of pentopyranoses, which were elaborated (in one case) to an analogue of a glycosyl phosphate

Opinion diversity and the resilience of cooperation in dynamical networks

Across various scenarios, individuals cooperate with others to contribute towards a shared goal and ensure self-preservation. In game theory, the act of cooperation is considered as an individual producing some form of benefit to be utilised by others, under the expectation others will return the favour. In several scenarios, individuals make use of their own information to aid with their decision about who to connect and cooperate with. However, the choice of cooperation can be taken advantage of by opportunistic defectors, which can lead to significant disruption. This paper investigates how the diversity of opinion can contribute to the structure and mechanics of a dynamical network model and to the resilience of cooperation, by utilising a computational model where individuals make use of both public and private information to implement their decision. Our results show that increasing diversity leads to more stable, less connected and less prosperous networks coupled to more frequent, but shallower information cascades. Our work generally shows that the outcome of the conflict between cooperators and cheaters strongly depends on the interplay between population structure, individual decision making and individual opinions

Cooperation dynamics in dynamical networks with history-based decisions

In many aspects of life on earth, individuals may engage in cooperation with others to contribute towards a goal they may share, which can also ensure self-preservation. In evolutionary game theory, the act of cooperation can be considered as an altruistic act of an individual producing some form of benefit or commodity that can be utilised by others they are associated with, which comes at some personal cost. Under certain conditions, individuals make use of information that they are able to perceive within a group in order to aid with their choices for who they should associate themselves within these cooperative scenarios. However, cooperative individuals can be taken advantage of by opportunistic defectors, which can cause significant disruption to the population. We study a model where the decision to establish interactions with potential partners is based on the opportune integration of the individual’s private ability to perceive the intentions of others (private information) and the observation of the population, information that is available to every individual (public information). When public information is restricted to a potential partners current connection count, the population becomes highly cooperative but rather unstable with frequent invasions of cheaters and recoveries of cooperation. However, when public information considers the previous decisions of the individuals (accepted / rejected connections) the population is slightly less cooperative but more stable. Generally, we find that allowing the observation of previous decisions, as part of the available public information, can often lead to more stable but fragmented and less prosperous networks. Our results highlight that the ability to observe previous individual decisions, balanced by individuals personal information, represents an important aspect of the interplay between individual decision-making and the resilience of cooperation in structured populations

Evaluation of irrigation pumping plant efficiencies and costs in the high plains of eastern Colorado

CER68-69RLL-DLM43.Includes bibliographical references (page 18).December 1968

Leishmania donovani populations in Eastern Sudan: temporal structuring and a link between human and canine transmission.

BACKGROUND: Visceral leishmaniasis (VL), caused by the members of the Leishmania donovani complex, has been responsible for devastating VL epidemics in the Sudan. Multilocus microsatellite and sequence typing studies can provide valuable insights into the molecular epidemiology of leishmaniasis, when applied at local scales. Here we present population genetic data for a large panel of strains and clones collected in endemic Sudan between 1993 and 2001. METHODS: Genetic diversity was evaluated at fourteen microsatellite markers and eleven nuclear sequence loci across 124 strains and clones. RESULTS: Microsatellite data defined six genetic subpopulations with which the nuclear sequence data were broadly congruent. Pairwise estimates of FST (microsatellite) and KST (sequence) indicated small but significant shifts among the allelic repertoires of circulating strains year on year. Furthermore, we noted the co-occurrence of human and canine L. donovani strains in three of the six clusters defined. Finally, we identified widespread deficit in heterozygosity in all four years tested but strong deviation from inter-locus linkage equilibrium in two years. CONCLUSIONS: Significant genetic diversity is present among L. donovani in Sudan, and minor population structuring between years is characteristic of entrenched, endemic disease transmission. Seasonality in vector abundance and transmission may, to an extent, explain the shallow temporal clines in allelic frequency that we observed. Genetically similar canine and human strains highlight the role of dogs as important local reservoirs of visceral leishmaniasis

Migrant workers’ exercise of agency during the COVID-19 pandemic in the UK: resilience, reworking and resistance

Drawing on qualitative data, we apply Katz’s conceptual framework of agency as resilience, reworking and resistance practices to theorise UK migrant workers’ responses to worsened employment conditions, stress of unemployment and reduced incomes during the pandemic. We draw attention to the range of micro practices they adopted to survive and rework existing conditions to their advantage - actions which rarely feature in academic writing, yet which recognise those who do not ‘resist’ as conscious agents who exercise power. Meanwhile, although outright oppositional responses to deteriorating employment conditions are rare, we demonstrate the nature of workplace union representation as a central factor in resisting managerial control. We extend Katz’s framework by considering the ‘how’ and ‘why’ behind migrant workers’ responses, to understand better their dynamic choices of resilience, reworking and resistance practices in the chaotic circumstances of the pandemic