CP-odd WWZ couplings induced by vector-like quarks

A minimal extension of the standard model includes extra quarks with charges 2/3 and/or -1/3, whose left-handed and right-handed components are both SU(2) singlets. This model predicts new interactions of flavor-changing neutral current at the tree level, which also violate CP invariance. We study CP-odd anomalous couplings for the gauge bosons W, W, and Z induced by the new interactions at the one-loop level. These couplings become nonnegligible only if both an up-type and a down-type extra quarks are incorporated. Their form factors are estimated to be maximally of order $10^{-5}$. Such magnitudes are larger than those predicted in the standard model, though smaller than those in certain other models.Comment: 13 pages, 3 Postscript figures, figure sizes change

Stereoselective synthesis of cis and trans-fused 3a-aryloctahydroindoles using cyclization of N-vinylic α-(methylthio)acetamides: synthesis of (-)-mesembrane

金沢大学大学院自然科学研究科生理活性物質科学金沢大学薬学部Treatment of N-(2-arylcyclohex-1-en-1-yl)-α-(methylthio)acetamides with N-chlorosuccinimide (NCS) gave 3a-aryl-2,3,3a,4,5,6-hexahydro-3-(methylthio)indol-2-ones. Desulfurization of the cyclization products followed by a catalytic hydrogenation of the resulting hexahydroindol-2-ones gave predominantly or exclusively trans-fused octahydroindol-2-ones. On the other hand, reduction of the desulfurization products with Et3SiH in CF3CO2H exclusively provided cis-fused octahydroindol-2-ones. A chiral induction of N-[2-(3,4-dimethoxy)phenylcyclohex-1-en-1-yl]-α-(methylthio)acetamide having an (R)-1-(1-naphthyl)ethyl group on the nitrogen atom led to the synthesis of (-)-mesembrane and (-)-trans-mesembrane. © 2007 Elsevier Ltd. All rights reserved