114 research outputs found
Interface effects in ferroelectric PbTiO ultrathin films on a paraelectric substrate
Interface effects on the ferroelectric behavior of PbTiO ultrathin films
deposited on SrTiO substrate are investigated using an interatomic
potential approach with parameters fitted to first-principles calculations. We
find that the correlation of atomic displacements across the film/substrate
interface is crucial for the stabilization of the ferroelectric state in films
a few unit-cells thick. We show that the minimum film thickness for the
appearance of a spontaneous polarized domain state is not an intrinsic property
of the ferroelectric film but depends on the polarizability of the paraelectric
substrate. We also observe that the substrate displays an induced polarization
with an unusual oscillatory behavior.Comment: 4 page
Surface reconstruction and ferroelectricity in PbTiO thin films
Surface and ferroelectric properties of PbTiO thin films are investigated
using an interatomic potential approach with parameters computed from
first-principles calculations. We show that a model developed for the bulk
describes properly the surface properties of PbTiO. In particular, the
antiferrodistortive surface reconstruction, recently observed from X-ray
scattering, is correctly reproduced as a result of the change in the balance of
long-range Coulombic and short-range interactions at the surface. The effects
of the surface reconstruction on the ferroelectric properties of ultrathin
films are investigated. Under the imposed open-circuit electrical boundary
conditions, the model gives a critical thickness for ferroelectricity of 4 unit
cells. The surface layer, which forms the antiferrodistortive reconstruction,
participates in the ferroelectricity. A decrease in the tetragonality of the
films leads to the stabilization of a phase with non-vanishing in-plane
polarization. A peculiar effect of the surface reconstruction on the in-plane
polarization profile is found.Comment: 6 pages, 5 figure
On the Stereochemistry of the Cations in the Doping Block of Superconducting Copper-Oxides
Metal-oxygen complexes containing Cu,- Tl-, Hg-, Bi- and Pb-cations are
electronically active in superconducting copper-oxides by stabilizing single
phases with enhanced , whereas other metal-oxygen complexes deteriorate
copper-oxide superconductivity. Cu, Tl, Hg, Bi, Pb in their actual oxidation
states are closed shell or inert pair ions. Their electronic
configurations have a strong tendency to polarize the oxygen environment. The
closed shell ions with low lying
excitations form linear complexes through hybridization polarizing
the apical oxygens. Comparatively low excitation energies
distinguish from other closed shell
ions deteriorating copper-oxide superconductivity, {\it e.g.} .Comment: 5 pages, uses REVTEX. To be published in: J. Superconductivity, Proc.
Int. Workshop on "Phase Separation, Electronic Inhomogenities and Related
Mechanisms for High T_c Superconductors", Erice (Sicily) 9-15 July 199
Developing Central Nervous System and Vulnerability to Platinum Compounds
Comparative studies on the effects of the platinum complexes in use or in clinical trials are carried out in order to discover differences in the neurotoxic potential and the reversibility of neurotoxicity. In this paper, we summarized the current literature on neurotoxicity and chemoresistance of cisplatin (cisPt) and discussed our recent efforts on the interference of cisPt and a new platinum compound [Pt(O,O′-acac)(γ-acac)(DMS)] (PtAcacDMS), with high specific reactivity with sulphur ligands instead of nucleobases as cisPt, on some crucial events of rat postnatal cerebellum development. The acute effects of drug treatments on cell proliferation and death in the external granular layer and granule cell migration and the late effects on the dendrite growth of Purkinje cells were evaluated. Together with the demonstrated antineoplastic effectiveness in vitro, compared with cisPt, data suggest a lower neurotoxicity of PtAcacDMS, in spite of its presence in the brain that involves considerations on the blood brain barrier permeability
Imaging of SNR IC443 and W44 with the Sardinia Radio Telescope at 1.5 GHz and 7 GHz
Observations of supernova remnants (SNRs) are a powerful tool for
investigating the later stages of stellar evolution, the properties of the
ambient interstellar medium, and the physics of particle acceleration and
shocks. For a fraction of SNRs, multi-wavelength coverage from radio to ultra
high-energies has been provided, constraining their contributions to the
production of Galactic cosmic rays. Although radio emission is the most common
identifier of SNRs and a prime probe for refining models, high-resolution
images at frequencies above 5 GHz are surprisingly lacking, even for bright and
well-known SNRs such as IC443 and W44. In the frameworks of the Astronomical
Validation and Early Science Program with the 64-m single-dish Sardinia Radio
Telescope, we provided, for the first time, single-dish deep imaging at 7 GHz
of the IC443 and W44 complexes coupled with spatially-resolved spectra in the
1.5-7 GHz frequency range. Our images were obtained through on-the-fly mapping
techniques, providing antenna beam oversampling and resulting in accurate
continuum flux density measurements. The integrated flux densities associated
with IC443 are S_1.5GHz = 134 +/- 4 Jy and S_7GHz = 67 +/- 3 Jy. For W44, we
measured total flux densities of S_1.5GHz = 214 +/- 6 Jy and S_7GHz = 94 +/- 4
Jy. Spectral index maps provide evidence of a wide physical parameter scatter
among different SNR regions: a flat spectrum is observed from the brightest SNR
regions at the shock, while steeper spectral indices (up to 0.7) are observed
in fainter cooling regions, disentangling in this way different populations and
spectra of radio/gamma-ray-emitting electrons in these SNRs.Comment: 13 pages, 9 figures, accepted for publication to MNRAS on 18 May 201
Sardinia Radio Telescope wide-band spectral-polarimetric observations of the galaxy cluster 3C 129
We present new observations of the galaxy cluster 3C 129 obtained with the
Sardinia Radio Telescope in the frequency range 6000-7200 MHz, with the aim to
image the large-angular-scale emission at high-frequency of the radio sources
located in this cluster of galaxies. The data were acquired using the
recently-commissioned ROACH2-based backend to produce full-Stokes image cubes
of an area of 1 deg x 1 deg centered on the radio source 3C 129. We modeled and
deconvolved the telescope beam pattern from the data. We also measured the
instrumental polarization beam patterns to correct the polarization images for
off-axis instrumental polarization. Total intensity images at an angular
resolution of 2.9 arcmin were obtained for the tailed radio galaxy 3C 129 and
for 13 more sources in the field, including 3C 129.1 at the galaxy cluster
center. These data were used, in combination with literature data at lower
frequencies, to derive the variation of the synchrotron spectrum of 3C 129
along the tail of the radio source. If the magnetic field is at the
equipartition value, we showed that the lifetimes of radiating electrons result
in a radiative age for 3C 129 of t_syn = 267 +/- 26 Myrs. Assuming a linear
projected length of 488 kpc for the tail, we deduced that 3C 129 is moving
supersonically with a Mach number of M=v_gal/c_s=1.47. Linearly polarized
emission was clearly detected for both 3C 129 and 3C 129.1. The linear
polarization measured for 3C 129 reaches levels as high as 70% in the faintest
region of the source where the magnetic field is aligned with the direction of
the tail.Comment: 19 pages, 17 figures, accepted for publication in MNRA
Peak positions and shapes in neutron pair correlation functions from powders of highly anisotropic crystals
The effect of the powder average on the peak shapes and positions in neutron
pair distribution functions of polycrystalline materials is examined. It is
shown that for highly anisotropic crystals, the powder average leads to shifts
in peak positions and to non-Gaussian peak shapes. The peak shifts can be as
large as several percent of the lattice spacing
LAPW frozen-phonon calculation, shell model lattice dynamics and specific-heat measurement of SnO
An ab-initio Linear Augmented Plane-Wave (LAPW) calculation of the
zone-centered phonon frequencies of SnO has been performed. E symmetry has
been ascribed to the mode observed at 113 cm in Raman measurements,
discarding a previous B assignement. The other phonon modes measured by
Raman spectroscopy are also well reproduced. A new shell-model has also been
developed, that gives good agreement of the zone-centered frequencies compared
to the measured data and the LAPW results. Specific heat measurements have been
performed between 5 K and 110 K. Computation of the specific heat and the
M\"{o}ssbauer recoilless fraction with the improved shell-model shows a good
agreement with the experimental data as a function of temperature.Comment: 11 pages, 1 figure. to appear in Phys. Rev. B (November 1999
Progress towards sustainable control of xylella fastidiosa subsp. Pauca in olive groves of salento (apulia, italy)
Xylella fastidiosa subsp. pauca is the causal agent of “olive quick decline syndrome” in Salento (Apulia, Italy). On April 2015, we started interdisciplinary studies to provide a sustainable control strategy for this pathogen that threatens the multi-millennial olive agroecosystem of Salento. Confocal laser scanning microscopy and fluorescence quantification showed that a zinc-copper-citric acid biocomplex—Dentamet® —reached the olive xylem tissue either after the spraying of the canopy or injection into the trunk, demonstrating its effective systemicity. The biocomplex showed in vitro bactericidal activity towards all X. fastidiosa subspecies. A mid-term evaluation of the control strategy performed in some olive groves of Salento indicated that this biocomplex significantly reduced both the symptoms and X. f. subsp. pauca cell concentration within the leaves of the local cultivars Ogliarola salentina and Cellina di Nardò. The treated trees started again to yield. A1 H-NMR metabolomic approach revealed, upon the treatments, a consistent increase in malic acid and γ-aminobutyrate for Ogliarola salentina and Cellina di Nardò trees, respectively. A novel endotherapy technique allowed injection of Dentamet® at low pressure directly into the vascular system of the tree and is currently under study for the promotion of resprouting in severely attacked trees. There are currently more than 700 ha of olive groves in Salento where this strategy is being applied to control X. f. subsp. pauca. These results collectively demonstrate an efficient, simple, low-cost, and environmentally sustainable strategy to control this pathogen in Salento
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