The potential response of the hydrate reservoir in the South Shetland Margin, Antarctic Peninsula, to ocean warming over the 21st century

In the South Shetland Margin (SSM), Antarctic Peninsula, a bottom-simulating reflector indicates the presence of hydrate between ca. 500 and 3000 m water depth (mwd). The cold seabed temperatures allow hydrate stability at shallower water depths. During the past five decades, the Antarctic Peninsula has been warming up faster than any other part of the Southern Hemisphere, and long-term ocean warming could affect the stability of the SSM hydrate reservoir at shallow waters. Here, we model the transient response of the SSM hydrate reservoir between 375 and 450 mwd to ocean warming for the period 1958–2100. For the period 1958–2010, seabed temperatures are given by oceanographic measurements in the area, and for 2010–2100 by two temperature scenarios represented by the observed trends for the periods 1960–2010 (0.0034°C y−1) and 1980–2010 (0.023°C y−1). Our results show no hydrate-sourced methane emissions for an ocean warming rate at the seabed of 0.0034 °C y−1. For a rate of 0.023°C y−1, emissions start in 2028 at 375 mwd and extend to 442 mwd at an average rate of about 0.91 mwd y−1, releasing ca. 1.13×103 mol y−1 of methane per metre along the margin by 2100. These emissions originate from dissociation at the top of the hydrate layer, a physical process that steady-state modelling cannot represent. Our results are speculative on account of the lack of direct evidence of a shallow water hydrate reservoir, but they illustrate that the SSM is a key area to observe the effects of ocean warming-induced hydrate dissociation in the coming decades

Gas Hydrates in Antarctica

Few potential distributing areas of gas hydrates have been recognized in literature in Antarctica: the South Shetland continental margin, the Weddell Sea, the Ross Sea continental margin and the Wilkes Land continental margin. The most studied part of Antarctica from gas hydrate point of view is the South Shetland margin, where an important gas hydrate reservoir was well studied with the main purpose to determine the relationship between hydrate stability and environment effects, including climate change. In fact, the climate signals are particularly amplified in transition zones such as the peri-Antarctic regions, suggesting that the monitoring of hydrate system is desirable in order to detect potential hydrate dissociation as predicted by recent modeling offshore Antarctic Peninsula. The main seismic indicator of the gas hydrate presence, the bottom simulating reflector, was recorded in few parts of Antarctica, but in some cases it was associated to opal A/CT transition. The other areas need further studies and measurements in order to confirm or refuse the gas hydrate presence

A quick-look method for initial evaluation of gas hydrate stability below subaqueous permafrost

Many studies demonstrated the coexistence of subaqueous permafrost and gas hydrate. Subaqueous permafrost could be a factor affecting the formation/dissociation of gas hydrate. Here, we propose a simple empirical approach that allows estimating the steady-state conditions for gas hydrate stability in the presence of subaqueous permafrost. This approach was derived for pressure, temperature, and salinity conditions typical of subaqueous permafrost in marine (brine) and lacustrine (freshwater) environments

Gas hydrate and free gas estimation from seismic analysis offshore Chiloé island (Chile)

In this study one seismic section offshore Chiloé Island was analyzed to better define the seismic character of the hydrate-bearing sediments. The velocity analysis was used to estimate the gas-phase concentration and relate it to the geological features. The velocity model allowed us to recognize two important layers that characterize hydrate- and free gas-bearing sediments above and below the BSR respectively: one located above the BSR, characterized by high velocity (1,800-2,200 m/s) and a second one, below the BSR, characterized by low velocity (1,600-1,700 m/s). A weak reflector at about 100 m below the BSR marks the base of the second layer. AVO analysis and offset stack sections confirming that the reflector interpreted as BGR is related to free gas presence in the pore space. The velocity field is affected by lateral variation, showing maximum (above the BSR) and minimum (below the BSR) values in the sector. Here, the highest gas hydrate and free gas concentrations were calculated, obtaining 9.5% and 0.5% of total volume respectively. A variable BSR depth (from 300 to 600 mbsf) can be justified supposing a variable geothermal gradient (from 25 to 45 °C/km)

A cold seep triggered by a hot ridge subduction

The Chile Triple Junction, where the hot active spreading centre of the Chile Rise system subducts beneath the South American plate, offers a unique opportunity to understand the influence of the anomalous thermal regime on an otherwise cold continental margin. Integrated analysis of various geophysical and geological datasets, such as bathymetry, heat flow measured directly by thermal probes and calculated from gas hydrate distribution limits, thermal conductivities, and piston cores, have improved the knowledge about the hydrogeological system. In addition, rock dredging has evidenced the volcanism associated with ridge subduction. Here, we argue that the localized high heat flow over the toe of the accretionary prism results from fluid advection promoted by pressure-driven discharge (i.e., dewatering/discharge caused by horizontal compression of accreted sediments) as reported previously. However, by computing the new heat flow values with legacy data in the study area, we raise the assumption that these anomalous heat flow values are also promoted by the eastern flank of the currently subducting Chile Rise. Part of the rift axis is located just below the toe of the wedge, where active deformation and vigorous fluid advection are most intense, enhanced by the proximity of the young volcanic chain. Our results provide valuable information to current and future studies related to hydrothermal circulation, seismicity, volcanism, gas hydrate stability, and fluid venting in this natural laboratory

Geophysical and Geological Views of Potential Water Resources in the North-Eastern Adriatic Sea

The increasing demand for freshwater requires the identification of additional and less-conventional water resources. Amongst these, offshore freshwater systems have been investigated in different parts of the world to provide new opportunities to face increasing water requests. Here we focus on the north-eastern Adriatic Sea, where offshore aquifers could be present as a continuation of onshore ones. Geophysical data, in particular offshore seismic data, and onshore and offshore well data, are interpreted and integrated to characterise the hydrogeological setting via the interpretation of seismo-stratigraphic sequences. We focus our attention on two areas located in the proximity of the Tagliamento and Isonzo deltas. Well and seismic data indicate that the Quaternary sediments, that extend from onshore to offshore areas, are the most promising from an offshore freshwater resources point of view, while the several kilometres thick pre-Quaternary carbonate and terrigenous sequences likely host mainly salty waters