Photophysics and photochemistry of octaglucosylated zinc phthalocyanine derivatives

The ground state electronic absorption spectra, photophysics and photochemistry of amphiphilic octaglucosylated zinc phthalocyanines containing oxygen or sulfur bridges are presented. Triplet quantum yield values for the two dyes (in DMF and DMSO) vary between 0.71 and 0.84, while singlet quantum yield values lie between 0.63 and 0.75. Fluorescence lifetimes were determined experimentally by time correlated single photon counting and semi-empirically by fluorescence quenching techniques; and values from both methods were within the same range. Kinetic data were obtained for the quenching of the triplet state of the phthalocyanines by ground state molecular oxygen; the bimolecular collisional quenching rate constant range between 2.35 × 108 and 1.13 × 109 M-1.s-1. These values suggest that triplet states of the dyes are effectively quenched by ground molecular oxygen

Spectral, photophysical and photochemical properties of tetra-and octaglycosylated zinc phthalocyanines

Photophysical and photochemical properties of a series of tetra- and octaglycosylated zinc phthalocyanines (ZnPcs) substituted with glucose and galactose moieties have been reported. Spectral properties of these phthalocyanines are compared in DMSO. Absorption spectra of the non-peripherally tetra-substituted ZnPcs 2 showed a significant red shift in their Q-band maxima as compared to the peripherally substituted analog 1. All the complexes gave high triplet quantum yields ranging from 0.68 to 0.88, whereas triplet lifetimes were in the range of 100–430 µs in argon-saturated solutions. The octagalactosylated ZnPc 3b showed the highest triplet quantum yield and singlet oxygen quantum yield of 0.88 and 0.69, respectively. The fluorescence quantum yields and lifetimes of all the compounds under investigation were within the range of zinc phthalocyanine complexes

Glycosylated Metal Phthalocyanines

In the first part; the syntheses of mono-; di-; and tetra-glycosylated phthalonitriles is described; which are the most used starting materials for the preparation of the corresponding glycosylated metal (mostly zinc) phthalocyanines. In the second section; the preparation of symmetric and unsymmetric mono-; tetra-; and octa- glycosylated zinc phthalocyanines are reviewed; in which the sugar is attached to the phthalocyanine macrocycle; either anomerically or via another one of its OH-groups

Glycosylated Metal Phthalocyanines

In the first part; the syntheses of mono-; di-; and tetra-glycosylated phthalonitriles is described; which are the most used starting materials for the preparation of the corresponding glycosylated metal (mostly zinc) phthalocyanines. In the second section; the preparation of symmetric and unsymmetric mono-; tetra-; and octa- glycosylated zinc phthalocyanines are reviewed; in which the sugar is attached to the phthalocyanine macrocycle; either anomerically or via another one of its OH-groups

Phthalocyanines as materials for advanced technologies: some examples

Metallophthalocyanine complexes and related compounds play an important role in many advanced applications and modem technologies mostly by virtue of their characteristic optical absorption and high chemical stability. As a class of materials made well-known by their vivid and fast colors, it is expected that metallophthalocyanines and analogues, e.g. naphthalocyanines, are going to keep their role with the increasing use of natural and artificial light in the technologies of the future. In the present review some relevant properties of phthalocyanines and related macrocycles for technological applications are analyzed. In particular the electrical conductivity and photoconductivity as well as some nonlinear optical properties (mostly optical limiting), of phthalocyanines and related compounds are discussed. Copyright (c) 2004 Society of Porphyrins & Phthalocyanines

Stacked polymeric phthalocyanines : synthesis and structure related properties

CHAPTER ORGANIZATION 1,2-Synthesis of stacked Pc polymers a) Nonbridged stacked poly-Pcs b) Bridged stacked poly-Pcs 3-Properties of bridged Pc

International Conference on Porphyrins and Phthalocyanines

Organizzazione del Simposio intitolato "Phthalocyanine based materials

Color chemistry, 3rd rev. ed.

Review of the book of Heinrich Zollinger "Color Chemistry", 3rd Ed., published by Wiley-VCH in 2003 (ISBN: 3-906390-23-3