Developments of Spent Nuclear Fuel Pyroprocessing Technology at Idaho National Laboratory

This paper summarizes research in used fuel pyroprocessing that has been published by Idaho National Laboratory over the last decade. It includes work done both on treatment of Experimental Breeder Reactor-II and development of advanced technology for potential scale-up and commercialization. Collaborations with universities and other laboratories is included in the cited work

Fecundity of Wild Northern Bobwhite Hens Under Hatchery Conditions

We describe egg production by 88 pairs of randomly selected, mature, wild-caught northern bobwhite (Colinus virginianus) hens housed under optimal conditions of food, water, climate, and a 17-hr photoperiod in a hatchery. We collected eggs daily using an 18-day period to differentiate between clutches. Hens continuously laid eggs until ceasing production. We evaluated number of eggs laid by each hen individually and hens collectively including total number, number/clutch, number/day, hatching success, and egg mass. Eighty-six hens produced 5,888 eggs. Number of eggs produced by individual hens ranged from 0 to 172 over ~ 200 days. Mean number of eggs laid/hen/day was 0.86. Clutch size ranged from 0 (n 1⁄4 2) to 12 (n 1⁄4 1). Mean number of eggs/clutch was 8.57. There was a strong correlation between clutch size and number of clutches. Some hens demonstrated continuous production of several large clutches. Hatching success of 5,793 eggs included for analysis was 61.6% (3,571 hatched, 2,222 failed to hatch). Hatched eggs had a greater mean mass compared to those that did not hatch

Strategic Minimization of High Level Waste from Pyroprocessing of Spent Nuclear Fuel

The pyroprocessing of spent nuclear fuel results in two high-level waste streams--ceramic and metal waste. Ceramic waste contains active metal fission product-loaded salt from the electrorefining, while the metal waste contains cladding hulls and undissolved noble metals. While pyroprocessing was successfully demonstrated for treatment of spent fuel from Experimental Breeder Reactor-II in 1999, it was done so without a specific objective to minimize high-level waste generation. The ceramic waste process uses “throw-away” technology that is not optimized with respect to volume of waste generated. In looking past treatment of EBR-II fuel, it is critical to minimize waste generation for technology developed under the Global Nuclear Energy Partnership (GNEP). While the metal waste cannot be readily reduced, there are viable routes towards minimizing the ceramic waste. Fission products that generate high amounts of heat, such as Cs and Sr, can be separated from other active metal fission products and placed into short-term, shallow disposal. The remaining active metal fission products can be concentrated into the ceramic waste form using an ion exchange process. It has been estimated that ion exchange can reduce ceramic high-level waste quantities by as much as a factor of 3 relative to throw-away technology

Modeling the Pyrochemical Reduction of Spent UO2 Fuel in a Pilot-Scale Reactor

A kinetic model has been derived for the reduction of oxide spent nuclear fuel in a radial flow reactor. In this reaction, lithium dissolved in molten LiCl reacts with UO2 and fission product oxides to form a porous, metallic product. As the reaction proceeds, the depth of the porous layer around the exterior of each fuel particle increases. The observed rate of reaction has been found to be only dependent upon the rate of diffusion of lithium across this layer, consistent with a classic shrinking core kinetic model. This shrinking core model has been extended to predict the behavior of a hypothetical, pilot-scale reactor for oxide reduction. The design of the pilot-scale reactor includes forced flow through baskets that contain the fuel particles. The results of the modeling indicate that this is an essential feature in order to minimize the time needed to achieve full conversion of the fuel

Propagation Effectiveness of the Surrogator for Northern Bobwhites in Southern Texas

Attempts to restore populations of northern bobwhites (Colinus virginianus) using pen-raised quail have been documented since the early 1900s. Low restoration success, based on low post-release survival rates and long distance dispersal from release sites, have proven the ineffectiveness of pen-raised quail in restoration of wild populations. The Surrogatort, a recent quail propagation tool using pen-raised quail, has been publicized as a method for increasing success rates in restoration of northern bobwhite populations by producing higher post-release survival and minimal dispersal. We tested the hypothesis that the Surrogatort is an effective means of supplementing populations of northern bobwhites in southern Texas. We raised 1,000 northern bobwhites in 2 Surrogators and conducted 2 trials in 2010 on a 990-ha ranch in Wilson County, Texas. Twenty northern bobwhites from each Surrogator were fitted with radio transmitters 12 hrs before release. We attempted to locate each bird daily for 3 weeks upon release from Surrogators followed by a reduced effort of 3 times per week until 100% mortality. Daily survival rates were low in Trial 1 (Surrogator A 1⁄4 0.87 and Surrogator B 1⁄4 0.96) and Trial 2 (Surrogator A 1⁄4 0.83 and Surrogator B 1⁄4 0.87). Mean distances traveled by post-released birds for Trial 1 were 401 and 1,416 m for Surrogators A and B, respectively. The Surrogator is not an effective means of restoring wild populations of northern bobwhites in southern Texas

Spitzer IRS Observations of the Galactic Center: Shocked Gas in the Radio Arc Bubble

We present Spitzer IRS spectra (R ~600, 10 - 38 micron) of 38 positions in the Galactic Center (GC), all at the same Galactic longitude and spanning plus/minus 0.3 degrees in latitude. Our positions include the Arches Cluster, the Arched Filaments, regions near the Quintuplet Cluster, the ``Bubble'' lying along the same line-of-sight as the molecular cloud G0.11-0.11, and the diffuse interstellar gas along the line-of-sight at higher Galactic latitudes. From measurements of the [O IV], [Ne II], [Ne III], [Si II], [S III], [S IV], [Fe II], [Fe III], and H_2 S(0), S(1), and S(2) lines we determine the gas excitation and ionic abundance ratios. The Ne/H and S/H abundance ratios are ~ 1.6 times that of the Orion Nebula. The main source of excitation is photoionization, with the Arches Cluster ionizing the Arched Filaments and the Quintuplet Cluster ionizing the gas nearby and at lower Galactic latitudes including the far side of the Bubble. In addition, strong shocks ionize gas to O^{+3} and destroy dust grains, releasing iron into the gas phase (Fe/H ~ 1.3 times 10^{-6} in the Arched Filaments and Fe/H ~ 8.8 times 10^{-6} in the Bubble). The shock effects are particularly noticeable in the center of the Bubble, but O$^{+3}$ is present in all positions. We suggest that the shocks are due to the winds from the Quintuplet Cluster Wolf-Rayet stars. On the other hand, the H_2 line ratios can be explained with multi-component models of warm molecular gas in photodissociation regions without the need for H_2 production in shocks.Comment: 51 pages, 17 figures To be published in the Astrophysical Journa

The closest extremely low-mass white dwarf to the Sun

We present the orbit and properties of 2MASS J050051.85-093054.9, establishing it as the closest (d ~ 71 pc) extremely low mass white dwarf to the Sun. We find that this star is hydrogen-rich with Teff ~ 10 500 K, log g ~ 5.9, and, following evolutionary models, has a mass of ~ 0.17 solar masses. Independent analysis of radial velocity and TESS photometric time series reveals an orbital period of ~ 9.5 h. Its high velocity amplitude (K ~ 144 km/s) produces a measurable Doppler beaming effect in the TESS light curve with an amplitude of 1 mmag. The unseen companion is most likely a faint white dwarf. J0500-0930 belongs to a class of post-common envelope systems that will most likely merge through unstable mass transfer and in specific circumstances lead to Type Ia supernova explosions