35 research outputs found
Characteristics of the polymer transport in ratchet systems
Molecules with complex internal structure in time-dependent periodic
potentials are studied by using short Rubinstein-Duke model polymers as an
example. We extend our earlier work on transport in stochastically varying
potentials to cover also deterministic potential switching mechanisms,
energetic efficiency and non-uniform charge distributions. We also use currents
in the non-equilibrium steady state to identify the dominating mechanisms that
lead to polymer transportation and analyze the evolution of the macroscopic
state (e.g., total and head-to-head lengths) of the polymers. Several numerical
methods are used to solve the master equations and nonlinear optimization
problems. The dominating transport mechanisms are found via graph optimization
methods. The results show that small changes in the molecule structure and the
environment variables can lead to large increases of the drift. The drift and
the coherence can be amplified by using deterministic flashing potentials and
customized polymer charge distributions. Identifying the dominating transport
mechanism by graph analysis tools is found to give insight in how the molecule
is transported by the ratchet effect.Comment: 35 pages, 17 figures, to appear in Phys. Rev.
Diffusion processes and growth on stepped metal surfaces
We study the dynamics of adatoms in a model of vicinal (11m) fcc metal
surfaces. We examine the role of different diffusion mechanisms and their
implications to surface growth. In particular, we study the effect of steps and
kinks on adatom dynamics. We show that the existence of kinks is crucially
important for adatom motion along and across steps. Our results are in
agreement with recent experiments on Cu(100) and Cu(1,1,19) surfaces. The
results also suggest that for some metals exotic diffusion mechanisms may be
important for mass transport across the steps.Comment: 3 pages, revtex, complete file available from
ftp://rock.helsinki.fi/pub/preprints/tft/ or at
http://www.physics.helsinki.fi/tft/tft_preprints.html (to appear in Phys.
Rev. B Rapid Comm.
Cluster size distributions in particle systems with asymmetric dynamics
We present exact and asymptotic results for clusters in the one-dimensional
totally asymmetric exclusion process (TASEP) with two different dynamics. The
expected length of the largest cluster is shown to diverge logarithmically with
increasing system size for ordinary TASEP dynamics and as a logarithm divided
by a double logarithm for generalized dynamics, where the hopping probability
of a particle depends on the size of the cluster it belongs to. The connection
with the asymptotic theory of extreme order statistics is discussed in detail.
We also consider a related model of interface growth, where the deposited
particles are allowed to relax to the local gravitational minimum.Comment: 12 pages, 3 figures, RevTe
Non-Arrhenius Behavior of Surface Diffusion Near a Phase Transition Boundary
We study the non-Arrhenius behavior of surface diffusion near the
second-order phase transition boundary of an adsorbate layer. In contrast to
expectations based on macroscopic thermodynamic effects, we show that this
behavior can be related to the average microscopic jump rate which in turn is
determined by the waiting-time distribution W(t) of single-particle jumps at
short times. At long times, W(t) yields a barrier that corresponds to the
rate-limiting step in diffusion. The microscopic information in W(t) should be
accessible by STM measurements.Comment: 4 pages, Latex with RevTeX macro
Physicians' views on patient participation in choice of oral anticoagulants in atrial fibrillation-a qualitative study
Direct oral anticoagulants provide an alternative to vitamin K antagonists for the anticoagulation therapy in atrial fibrillation (AF). The availability of several treatment options with different attributes makes shared decision-making appropriate for the choice of anticoagulation therapy. The aim of this study was to understand how physicians choose an oral anticoagulant (OAC) for patients with AF and how physicians view patients' participation in this decision. Semi-structured interviews with 17 Finnish physicians (eight general practitioners and nine specialists) working in the public sector were conducted. An interview guide on experience, prescribing and opinions about oral anticoagulants was developed based on previous literature. The data were thematically analysed using deductive and inductive approaches. Based on the interviews, patient's opinion was the most influential factor in decision-making when there were no clinical factors limiting the choice between OACs. Of patient's preferences, the most important was the attitude towards co-payments of OACs. Patients' opinions on monitoring of treatment, dosing and antidote availability were also mentioned by the interviewees. The choice of an OAC in AF was patient-centred as all interviewees expressed that patient's opinion affects the choice.</p
Effect of a columnar defect on the shape of slow-combustion fronts
We report experimental results for the behavior of slow-combustion fronts in
the presence of a columnar defect with excess or reduced driving, and compare
them with those of mean-field theory. We also compare them with simulation
results for an analogous problem of driven flow of particles with hard-core
repulsion (ASEP) and a single defect bond with a different hopping probability.
The difference in the shape of the front profiles for excess vs. reduced
driving in the defect, clearly demonstrates the existence of a KPZ-type of
nonlinear term in the effective evolution equation for the slow-combustion
fronts. We also find that slow-combustion fronts display a faceted form for
large enough excess driving, and that there is a corresponding increase then in
the average front speed. This increase in the average front speed disappears at
a non-zero excess driving in agreement with the simulated behavior of the ASEP
model.Comment: 7 pages, 7 figure
Competing mechanisms for step meandering in unstable growth
The meander instability of a vicinal surface growing under step flow
conditions is studied within a solid-on-solid model. In the absence of edge
diffusion the selected meander wavelength agrees quantitatively with the
continuum linear stability analysis of Bales and Zangwill [Phys. Rev. B {\bf
41}, 4400 (1990)]. In the presence of edge diffusion a local instability
mechanism related to kink rounding barriers dominates, and the meander
wavelength is set by one-dimensional nucleation. The long-time behavior of the
meander amplitude differs in the two cases, and disagrees with the predictions
of a nonlinear step evolution equation [O. Pierre-Louis et al., Phys. Rev.
Lett. {\bf 80}, 4221 (1998)]. The variation of the meander wavelength with the
deposition flux and with the activation barriers for step adatom detachment and
step crossing (the Ehrlich-Schwoebel barrier) is studied in detail. The
interpretation of recent experiments on surfaces vicinal to Cu(100) [T.
Maroutian et al., Phys. Rev. B {\bf 64}, 165401 (2001)] in the light of our
results yields an estimate for the kink barrier at the close packed steps.Comment: 8 pages, 7 .eps figures. Final version. Some errors in chapter V
correcte
Nonequilibrium Statistical Mechanics of the Zero-Range Process and Related Models
We review recent progress on the zero-range process, a model of interacting
particles which hop between the sites of a lattice with rates that depend on
the occupancy of the departure site. We discuss several applications which have
stimulated interest in the model such as shaken granular gases and network
dynamics, also we discuss how the model may be used as a coarse-grained
description of driven phase-separating systems. A useful property of the
zero-range process is that the steady state has a factorised form. We show how
this form enables one to analyse in detail condensation transitions, wherein a
finite fraction of particles accumulate at a single site. We review
condensation transitions in homogeneous and heterogeneous systems and also
summarise recent progress in understanding the dynamics of condensation. We
then turn to several generalisations which also, under certain specified
conditions, share the property of a factorised steady state. These include
several species of particles; hop rates which depend on both the departure and
the destination sites; continuous masses; parallel discrete-time updating;
non-conservation of particles and sites.Comment: 54 pages, 9 figures, review articl
Self-diffusion of adatoms, dimers, and vacancies on Cu(100)
We use ab initio static relaxation methods and semi-empirical
molecular-dynamics simulations to investigate the energetics and dynamics of
the diffusion of adatoms, dimers, and vacancies on Cu(100). It is found that
the dynamical energy barriers for diffusion are well approximated by the
static, 0 K barriers and that prefactors do not depend sensitively on the
species undergoing diffusion. The ab initio barriers are observed to be
significantly lower when calculated within the generalized-gradient
approximation (GGA) rather than in the local-density approximation (LDA). Our
calculations predict that surface diffusion should proceed primarily via the
diffusion of vacancies. Adatoms are found to migrate most easily via a jump
mechanism. This is the case, also, of dimers, even though the corresponding
barrier is slightly larger than it is for adatoms. We observe, further, that
dimers diffuse more readily than they can dissociate. Our results are discussed
in the context of recent submonolayer growth experiments of Cu(100).Comment: Submitted to the Physical Review B; 15 pages including postscript
figures; see also http://www.centrcn.umontreal.ca/~lewi