Quantum yield of the marine benthic microflora of near-shore coastal Penang, Malaysia

Benthic microalgal communities often contribute more than 30% of the primary production of shallow coastal and estuarine areas. At Muka Head Penang (Pulau Pinang) and the Songsong Islands (Pulau Songsong), Kedah, Malaysia, high concentrations of suspended solids and phytoplankton biomass (10.6 mg Chl a m-3) has reduced water clarity such that the euphotic zone of these areas is less than 2 m and 3 m deep respectively. The benthic microalgal communities, which were composed of the diatom genera Cocconeis, Fragilaria, Paralia and Pleurosigma, had a low biomass, had low maximum quantum yields (0.325 ± 0.129), were poorly adapted to their light environment and were constantly light limited. These characteristics suggest that the benthic microalgal communities were likely to have made only a minor contribution to the total primary production of the area

Interactions of phenyldithioesters with gold nanoparticles (AuNPs): Implications for AuNP functionalization and molecular barcoding of AuNP assemblies

The interactions of phenyldithioesters with gold nanoparticles (AuNPs) have been studied by monitoring changes in the surface plasmon resonance (SPR), depolarised light scattering, and surface enhanced Raman spectroscopy (SERS). Changes in the SPR indicated that an AuNP-phenyldithioester charge transfer complex forms in equilibrium with free AuNPs and phenyldithioester. Analysis of the Langmuir binding isotherms indicated that the equilibrium adsorption constant, Kads, was 2.3 ± 0.1 × 106 M−1, which corresponded to a free energy of adsorption of 36 ± 1 kJ mol−1. These values are comparable to those reported for interactions of aryl thiols with gold and are of a similar order of magnitude to moderate hydrogen bonding interactions. This has significant implications in the application of phenyldithioesters for the functionalization of AuNPs. The SERS results indicated that the phenyldithioesters interact with AuNPs through the C═S bond, and the molecules do not disassociate upon adsorption to the AuNPs. The SERS spectra are dominated by the portions of the molecule that dominate the charge transfer complex with the AuNPs. The significance of this in relation to the use of phenyldithioesters for molecular barcoding of nanoparticle assemblies is discussed