Evaluating Structural, Chlorophyll-Based and Photochemical Indices to Detect Summer Maize Responses to Continuous Water Stress

his study evaluates the performance of structural, chlorophyll-based, and photochemical indices to detect maize water status and to assess production based on five years of field experiments (2013–2017) during the primary growth stages. We employed three categories of indicators, including water condition and productive and thermal indicators, to quantify the responses of summer maize under continuous water stress from drought to waterlogging conditions. Furthermore, we adopted several spectral indices to assess their sensitivity to three categories of metrics. The results showed the association is the best between the treatment level and Leaf Water Content (LWC). The waterlogging treatment influenced Leaf Water Potential (LWP) in moderate drought stress. Severe drought stress caused the strongest reduction in productivity from both Leaf Area Index (LAI) and chlorophyll content. In terms of sensitivity of various indices, red-edge-position (REP) was sensitive to maize water conditions LWP, LAI and chlorophyll content. Photochemical Reflectance Index (PRI) and Normalized Difference Vegetation Index (NDVI) were the most and second most sensitive indices to productive indicators, respectively. The results also showed that no indices were capable of capturing the information of Crop Water Stress Index (CWSI)

Experimental Verification of Solid-like and Fluid-like States in the Homogeneous Fluidization Regime of Geldart A Particles

The mechanisms underlying homogeneous fluidization of Geldart A particles have been debated for decades. Some ascribed the stability to interparticle forces, while others insisted a purely hydrodynamic explanation. Valverde et al. (2001) fluidized 8.53-μm (i.e., Geldart C) particles by the addition of fumed silica nanoparticles and found that even during homogeneous fluidization both solid-like and fluid-like behavior can be distinguished. However, it is still unclear whether both states exist for true Geldart A particles. In this paper, the particulate fluidization characteristics of three typical Geldart A powders were studied by camera recording, electrical capacitance tomography, and pressure fluctuation. For the first time, the existence of both a solid-like state dominated by interparticle forces and a fluid-like state dominated by fluid dynamics during homogeneous expansion of Geldart A particles was experimentally verified. Furthermore, the ability and performance of the used measurement techniques to identify different flow regimes were compared.</p

Reference Evapotranspiration Variation Analysis and Its Approaches Evaluation of 13 Empirical Models in Sub-Humid and Humid Regions: A Case Study of the Huai River Basin, Eastern China

Accurate and reliable estimations of reference evapotranspiration (ET0) are imperative in irrigation scheduling and water resource planning. This study aims to analyze the spatiotemporal trends of the monthly ET0 calculated by the Penman&ndash;Monteith FAO-56 (PMF-56) model in the Huai River Basin (HRB), eastern China. However, the use of the PMF-56 model is limited by the insufficiency of climatic input parameters in various sites, and the alternative is to employ simple empirical models. In this study, the performances of 13 empirical models were evaluated against the PMF-56 model by using three common statistical approaches: relative root-mean-square error (RRMSE), mean absolute error (MAE), and the Nash&ndash;Sutcliffe coefficient (NS). Additionally, a linear regression model was adopted to calibrate and validate the performances of the empirical models during the 1961&ndash;2000 and 2001&ndash;2014 time periods, respectively. The results showed that the ETPMF increased initially and then decreased on a monthly timescale. On a daily timescale, the Valiantzas3 (VA3) was the best alternative model for estimating the ET0, while the Penman (PEN), WMO, Trabert (TRA), and Jensen-Haise (JH) models showed poor results with large errors. Before calibration, the determination coefficients of the temperature-based, radiation-based, and combined models showed the opposite changing trends compared to the mass transfer-based models. After calibration, the performance of each empirical model in each month improved greatly except for the PEN model. If the comprehensive climatic datasets were available, the VA3 would be the recommended model because it had a simple computation procedure and was also very well correlated linearly to the PMF-56 model. Given the data availability, the temperature-based, radiation-based, Valiantzas1 (VA1) and Valiantzas2 (VA2) models were recommended during April&ndash;October in the HRB and other similar regions, and also, the mass transfer-based models were applicable in other months

Quantifying Climatic Impact on Reference Evapotranspiration Trends in the Huai River Basin of Eastern China

Reference evapotranspiration (ETref) is an important study object for hydrological cycle processes in the context of drought-flood risks of the Huai River Basin (HRB). In this study, the FAO-56 Penman–Monteith (PM) model was employed to calculate seasonal and annual ETref based on 137 meteorological station data points in HRB from 1961 to 2014. The Mann–Kendall (MK) trend analysis was adopted together with Theil–Sen’s estimator to detect tendencies of ETref and climate factors. Furthermore, a developed differential equation method based on the FAO-56 PM model was applied to quantify the sensitivities of ETref to meteorological factors and their contributions to ETref trends. The results showed that the ETref demonstrated a strong spatially heterogeneity in the whole HRB at each time scale. ETref showed a significant decreasing trend in the upper-middle HRB and Yi-Shu-Si River Basin, especially at the annual time scale, in growing season and summer, while a generally increasing trend in ETref was detected in the lower HRB, and the significance only showed in spring. These phenomena could be reasonably explained by a significantly increasing mean temperature (TA), a significantly decreasing wind speed (WS), solar radiation (SR), and a slightly decreasing relative humidity (RH). The most sensitive factor to ETref was RH in most sub-regions and most time scales, except in the growing season and summer. Based on the developed differential equation method, the dominant factor of the decreasing ETref was WS in the annual time scale, spring, autumn, and winter in most sub-regions, except the lower HRB, which then shifted to SR in the growing season and summer. However, in the lower HRB, the significantly decreasing RH was the most dominant factor, especially in the annual time scale, growing season, and spring, which might be responsible for the slightly increasing ETref there

Attribution Analysis of Long-Term Trends of Aridity Index in the Huai River Basin, Eastern China

This paper aims to combinedly investigate the spatiotemporal trends of precipitation (Pre), reference evapotranspiration (ET0), and aridity index (AI) by employing nonparametric methods based on daily datasets from 137 meteorological stations during 1961&ndash;2014 in the Huai River Basin (HRB). The dominant factors influencing ET0 and AI trends were also explored using the detrended and differential equation methods. Results show that (1) Pre, ET0, and AI were much larger in summer than in other seasons, and AI had a nonsignificant increasing trend in annual time scale, while Pre and ET0 exhibited decreasing trends, but AI showed a downward trend in spring and autumn (becoming drier) and an upward trend during summer and winter due to increased Pre (becoming wetter); (2) lower AI values were identified in north and higher in south, and lower ET0 was identified in south and higher in north in annual time scale, growing season and spring, while ET0 decreased from west to east in summer and winter, the spatial distribution of Pre was similar to that of AI; (3) for ET0 trends, in general, wind speed at two-meter height (u2) was the dominant factor in spring, autumn, winter, and annual time scale, while in other seasons, solar radiation (Rs) played a dominant role; (4) for AI trends, AI was mostly contributed by Pre in spring, autumn, and winter, the Rs contributed the most to AI trend in growing season and summer, then in annual time scale, u2 was the dominant factor; (5) overall, the contribution of Pre to AI trends was much larger than that of ET0 in spring, autumn, and winter, while AI was mostly contributed by ET0 in annual time scale, growing season and summer. The outcomes of the study may improve our scientific understanding of recent climate change effects on dry&ndash;wet variations in the HRB; moreover, this information may be utilized in other climatic regions for comparison analyses

Study of Mn incorporation into SAPO framework: synthesis, characterization and catalysis in chloromethane conversion to light olefins

MnAPSO-34 molecular sieve has been synthesized with triethylamine as the template, characterized with XRD, XRF, P-31, Al-27 and Si-21 NMR and FT-IR techniques and compared with SAPO-34. The template decomposition and removal have been investigated with TG-DTG-DSC coupled with mass spectrometer. Mn incorporation generates a negligible difference On the chemical shift in P-31 and Al-27 MAS NMR, while an effect on the intensity of resonance peaks is revealed. Si-29 MAS NMR study has demonstrated that Mn incorporation favors the Si island formation, which may give rise to the stronger acidic sites. The thermal analysis (TG-DSC) on template removal in a diluted oxygen atmosphere, leading to the formation Of CO2, NO and H2O, showed, besides a low temperature endothermic weight loss due to the desorption of water, two weight losses (200-400 and 400-600 degrees C) for SAPO-34 and MnAPSO-34, suggesting two different chemical location environments of template molecules in these two molecular sieves. The quantity of template removed at higher temperature range is much higher in MnAPSO-34, indicating stronger template-framework interaction and stronger acidity after calcination. The acid difference caused by Mn incorporation has also been evidenced by ammonia adsorption evaluated by FT-IR. Chloromethane transformation was carried out over MnAPSO-34 and SAPO-34 and the catalytic performance showed that both molecular sieves are very active and selective catalyst for light olefins production. MnAPSO-34 demonstrated higher activity and light olefins selectivity. (c) 2005 Elsevier Inc. All rights reserved

How Has the Recent Climate Change Affected the Spatiotemporal Variation of Reference Evapotranspiration in a Climate Transitional Zone of Eastern China?

Reference evapotranspiration (ET0) is essential for agricultural production and crop water management. The recent climate change affecting the spatiotemporal variation of ET0 in eastern China continues to still be less understood. For this purpose, the latest observed data from 77 meteorological stations in Anhui province were utilized to determine the spatiotemporal variations of ET0 by the use of the Penman–Monteith FAO 56 (PMF-56) model. Furthermore, the Theil–Sen estimator and the Mann–Kendall (M–K) test were adopted to analyze the trends of ET0 and meteorological factors. Moreover, the differential method was employed to explore the sensitivity of ET0 to meteorological factors and the contributions of meteorological factors to ET0 trends. Results show that the ET0 decreased significantly before 1990, and then increased slowly. The ET0 is commonly higher in the north and lower in the south. ET0 is most sensitive to relative humidity (RH), except in summer. However, in summer, net radiation (Rn) is the most sensitive factor. During 1961–1990, Rn was the leading factor annually, during the growing season and summer, while wind speed (u2) played a leading role in others. All meteorological factors provide negative contributions to ET0 trends, which ultimately lead to decreasing ET0 trends. During 1991–2019, the leading factor of ET0 trends changed to the mean temperature (Ta) annually, during the growing season, spring and summer, and then to Rn in others. Overall, the negative contributions from u2 and Rn cannot offset the positive contributions from Ta and RH, which ultimately lead to slow upward ET0 trends. The dramatic drop in the amount of u2 that contributes to the changes in ET0 in Region III is also worth noting

How Has the Recent Climate Change Affected the Spatiotemporal Variation of Reference Evapotranspiration in a Climate Transitional Zone of Eastern China?

Reference evapotranspiration (ET0) is essential for agricultural production and crop water management. The recent climate change affecting the spatiotemporal variation of ET0 in eastern China continues to still be less understood. For this purpose, the latest observed data from 77 meteorological stations in Anhui province were utilized to determine the spatiotemporal variations of ET0 by the use of the Penman&ndash;Monteith FAO 56 (PMF-56) model. Furthermore, the Theil&ndash;Sen estimator and the Mann&ndash;Kendall (M&ndash;K) test were adopted to analyze the trends of ET0 and meteorological factors. Moreover, the differential method was employed to explore the sensitivity of ET0 to meteorological factors and the contributions of meteorological factors to ET0 trends. Results show that the ET0 decreased significantly before 1990, and then increased slowly. The ET0 is commonly higher in the north and lower in the south. ET0 is most sensitive to relative humidity (RH), except in summer. However, in summer, net radiation (Rn) is the most sensitive factor. During 1961&ndash;1990, Rn was the leading factor annually, during the growing season and summer, while wind speed (u2) played a leading role in others. All meteorological factors provide negative contributions to ET0 trends, which ultimately lead to decreasing ET0 trends. During 1991&ndash;2019, the leading factor of ET0 trends changed to the mean temperature (Ta) annually, during the growing season, spring and summer, and then to Rn in others. Overall, the negative contributions from u2 and Rn cannot offset the positive contributions from Ta and RH, which ultimately lead to slow upward ET0 trends. The dramatic drop in the amount of u2 that contributes to the changes in ET0 in Region III is also worth noting