Cobalt availability in the soil plant and animal food chain: a study under a peri-urban environment

Abstract Cobalt metal is considered as an essential trace element for the animals. Present investigation was undertaken in the peri-urban area to analyze the cobalt availability in animal food chain by using different indices. Cow, buffalo and sheep samples along with forage and soil samples were collected from the three different sites of District Jhang and analyzed through atomic absorption spectrophotometer. Cobalt values differed in soil samples as 0.315-0.535 mg/kg, forages as 0.127-0.333 mg/kg and animal samples as 0.364-0.504 mg/kg. Analyzed cobalt concentration in soil, forage and animal samples was found to be deficient in concentration with respect to standard limits. Soil showed the minimum cobalt level in Z. mays while maximum concentration was examined in the forage C. decidua samples. All indices examined in this study has values lesser than 1, representing the safer limits of the cobalt concentration in these samples. Enrichment factor (0.071-0.161 mg/kg) showed the highly deficient amount of cobalt enrichment in this area. Bio-concentration factor (0.392-0.883) and pollution load index (0.035-0.059 mg/kg) values were also lesser than 1 explains that plant and soil samples are not contaminated with cobalt metal. The daily intake and health risk index ranged from 0.00019-0.00064 mg/kg/day and 0.0044-0.0150 mg/kg/day respectively. Among the animals, cobalt availability was maximum (0.0150 mg/kg/day) in the buffaloes that grazed on the C. decidua fodder. Results of this study concluded that cobalt containing fertilizers must be applied on the soil and forages. Animal feed derived from the cobalt containing supplements are supplied to the animals, to fulfill the nutritional requirements of livestock

Evaluation of Cu, Zn, Fe, and Mn Concentrations in Water, Soil, and Fruit Samples in Sargodha District, Pakistan

This study aimed to assess the concentrations of copper (Cu), zinc (Zn), iron (Fe), and manganese (Mn) in the edible parts of grapefruit and kinnow fruit irrigated with sewage water (SW), tube-well water (TW), and canal water (CW). Preparation of the samples used in the study for metal analysis was carried out via the wet acid digestion method. Atomic absorption spectrometry (AAS) was used for metal determination. According to the results, Cu concentration ranged from 0.152 to 0.754 mg/L in water, 5.254 to 41.659 mg/kg in soil, and 0.128 to 0.864 mg/kg in fruit samples. Zn concentration varied from 0.574 to 2.723 mg/L in water, 17.812 to 112.954 mg/kg in soil, and 2.658 to 42.642 mg/kg in fruit samples. Fe concentration ranged from 0.254 to 1.245 mg/L in water, 10.635 to 48.638 mg/kg in soil, and 1.062 to 7.584 mg/kg in fruit samples. Mn concentration ranged from 0.154 to 0.638 mg/L in water, 51.283 to 183.865 mg/kg in soil, and 0.136 to 1.464 mg/kg in fruit samples. The Pollution Load Index (PLI) indicated that Cu and Mn exceeded a PLI value of one, and Zn had a PLI > 1 only in sewage water-irrigated sites. Bioconcentration Factor (BCF), Enrichment Factor (EF), Daily Intake of Metal (DIM), and Health Risk Index (HRI) values for all metals were within permissible limits, indicating no immediate health risks associated with consuming these fruits