Synthesis and characterization of silver-chitosan nanoparticles on textile

Metal nanoparticles these times have gathered huge popularity in the fields of health industry. This study focuses on synthesis of silver and chitosan nanoparticles and study their antibacterial effects and cytotoxicity when they are coated on a fabric. The prepared fabric was subjected to characterization techniques such as XPS, XRD, EDX and SEM. These tests confirmed the presence of silver nanoparticles on the surface of the fabric. Antibacterial and cytotoxicity tests were conducted, and the results exhibited that silver nanoparticles have showed good antibacterial effect on both gram positive and gram-negative bacteria and showed no cytotoxicity. The antibacterial effect was effective after 10 cycles of washing.t PLASMAMED - PTDC/CTM-TEX/28295/2017 fnanced by FCT, FEDER and POCI in the frame of the Portugal 2020 program, the project UID/CTM/00264/2019 of 2C2T under the COMPETE and FCT/MCTES (PIDDAC) co-fnanced by FEDER through the PT2020 progra

Gold nanoparticles synthesis and antimicrobial effect on fibrous materials

Depositing nanoparticles in textiles have been a promising strategy to achieve multifunc- tional materials. Particularly, antimicrobial properties are highly valuable due to the emergence of new pathogens and the spread of existing ones. Several methods have been used to functionalize textile materials with gold nanoparticles (AuNPs). Therefore, this review highlighted the most used methods for AuNPs preparation and the current studies on the topic in order to obtain AuNPs with suitable properties for antimicrobial applications and minimize the environmental concerns in their production. Reporting the detailed information on the functionalization of fabrics, yarns, and fibers with AuNPs by different methods to improve the antimicrobial properties was the central objective. The studies combining AuNPs and textile materials have opened valuable opportunities to develop antimicrobial materials for health and hygiene products, as infection control and barrier material, with improved properties. Future studies are needed to amplify the antimicrobial effect of AuNPs onto textiles and minimize the concerns related to the synthesis.FEDER funds through the Operational Competitiveness Program—COMPETE and by National Funds through Fundação para a Ciência e Tecnologia (FCT)—under the project POCI-01-0145-FEDER-007136 and UID/CTM/00264/2019. I.R. (SFRH/BD/137668/2018) acknowledges FCT, Portugal, for its doctoral grant financial support. A.Z. also acknowledges financial support of the FCT project PTDC/CTM-TEX/28295/2017 financed by FCT, FEDER, and POC

Development of antimicrobial polyester fabric by a green in situ synthesis of copper nanoparticles mediated from chitosan and ascorbic acid

The antimicrobial functionalization of polyester fabrics (PES) is useful to provide protection from pathogens and reducing odors. Copper nanoparticles (CuNPs) have been widely applied due to their antimicrobial properties and higher biocompatibility compared with other metal nanoparticles. However, the inherent instability of CuNPs under atmospheric conditions and the use of harmful chemicals during their synthesis limit their use. Thus, the development of efficient and safe methods for the CuNPs synthesis and their stabilization onto surfaces present high interest. In this work, PES was functionalized with CuNPs via in situ synthesis using cost-effective and safe chemicals in the presence and absence of chitosan. In sample without chitosan, the CuNPs showed a suitable stabilization onto PES due to the doubled stabilization of ascorbic acid (AA) and cetyl trimethyl ammonium bromide (CTAB). In sample with chitosan, less CuNPs were retained by the PES but also less CuNPs agglomeration was observed. Both samples presented excellent antibacterial effect against Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli) as well as laundering durability.(undefined

Development of a plasma activated multifunctional polyester fabric using zinc oxide nanoparticles and citronella oil microcapsules

Apresentação efetuada na 21th World Textile Conference - AUTEX 2022, em Lodz, Poland, 2022This work was funded by ERDF through the COP and FCT projects: UID/CTM/00264/2021, PLASMAMED PTDC/CTM TEX/28295/2017, ARCHKNIT POCI-01-0247-FEDER-039733, FATORST+ POCI-01-0247-ERDF-047124, MEDCOR PTDC/CTM-TEX/1213/2020, 4NoPressure POCI-01-0247-FEDER-039869 financed by FEDER through POCI under the “Portugal 2020” programme, and the Ph.D. scholarship SFRH/BD/137668/2018

Antibacterial properties of bacterial nanocellulose functionalized with metal nanoparticles via in situ synthesis

[Excerpt] Wound infections are generally caused by pathogens and multidrug-resistant (MDR) strains that render the administration of antibiotics ineffective. An alternative is to treat infected wounds at the initial stage using a fibrous bionanopolymer, bacterial nanocellulose (BNC), functionalized with antimicrobial metal nanoparticles (MNPs). BNC is a highly promising wound dressing due to its very high-water retention capacity (> 99 %) and high porosity. Such properties enable the absorbance of exudates, whilst maintaining the environment moist allowing the exchange of air. However, BNC is absent of antibacterial properties, thus gold (Au), copper (Cu), and copper oxide (Cu2O) NPs were incorporated within the nanofibrous structure of the biopolymer via in situ synthesis

Development of a plasma activated multifunctional polyester fabric using zinc oxide nanoparticles and citronella oil microcapsules

There is a high demand for the development of textiles possessing multifunctional properties for outdoor, protective and health care applications. The coating of polyester (PES) textiles with metal nanoparticles and essential oils may act in a synergistic mode to obtain materials with improved antimicrobial and UV-protection properties. However, the lack of functional groups onto PES structure makes the adhesion of particles a difficult task. In this work, PES fabric was activated by dielectric barrier discharge (DBD) plasma treatment, and functionalized with zinc oxide nanoparticles (ZnO NPs) and poly (methyl methacrylate) (PMMA)-citronella microcapsules by dip-coating

Sustainable and multifunctional natural fiber-based electric wire sheaths for smart textiles

Envisioning the development of sustainable products for improvement of daily life quality, a cable-like composite using natural fibers was developed to be potentially used in smart textiles. Natural fibers such as jute and hemp were used along with Bekinox®VN yarn. Bekinox®VN is a stainless steel conductive yarn often used in intelligent textiles within a wide range of applications such as antistatic, power and signal transfer, thermal conductivity or even as a heat resistant sewing yarn. Furthermore, applying a chitosan coating on the surface of the sheath will confer antibacterial properties, thus preventing the colonization and proliferation of bacteria, as well as natural fiber degradation. The chitosan coating was applied by a pad dry method. Tests were performed to evaluate the mechanical, electrical and antimicrobial properties. The results displayed that the best tensile strength was obtained for hemp fabric followed by cable composite. The antimicrobial properties were improved with the coating of chitosan and demonstrating excellent results against Gram-positive and Gram-negative bacteria. Although chitosan reduces the mechanical strength of the sheath, it confers antibacterial activity, which not only will preserve the fiber in the structure but will also protect human skin against possible cross-contaminations.This work was funded by ERDF through the COP and FCT projects: UID/CTM/00264/2021, PLASMAMED PTDC/CTM TEX/28295/2017, ARCHKNIT POCI-01-0247-FEDER-039733, FATORST+ POCI-01-0247-ERDF-047124, MEDCOR PTDC/CTM-TEX/1213/2020, 4NoPressure POCI-01-0247-FEDER-039869 financed by FEDER through POCI under the “Portugal 2020” programme. RDVF and AIR also acknowledge Ph.D. scholarships SFRH/BD/145269/2019 and SFRH/BD/137668/2018, respectively

Sustainable and multifunctional natural fiber-based electric wire sheaths for smart textiles

Envisioning the development of sustainable products for improvement of daily life quality, a cable-like composite using natural fibers was developed to be potentially used in smart textiles. Natural fibers such as jute and hemp were used along with Bekinox®VN yarn. Bekinox®VN is a stainless steel conductive yarn often used in intelligent textiles within a wide range of applications such as antistatic, power and signal transfer, thermal conductivity or even as a heat resistant sewing yarn. Furthermore, applying a chitosan coating on the surface of the sheath will confer antibacterial properties, thus preventing the colonization and proliferation of bacteria, as well as natural fiber degradation. The chitosan coating was applied by a pad dry method. Tests were performed to evaluate the mechanical, electrical and antimicrobial properties. The results displayed that the best tensile strength was obtained for hemp fabric followed by cable composite. The antimicrobial properties were improved with the coating of chitosan and demonstrating excellent results against Gram-positive and Gram-negative bacteria. Although chitosan reduces the mechanical strength of the sheath, it confers antibacterial activity, which not only will preserve the fiber in the structure but will also protect human skin against possible cross-contaminations.This work was funded by ERDF through the COP and FCT projects: UID/CTM/00264/2021, PLASMAMED PTDC/CTM TEX/28295/2017, ARCHKNIT POCI-01-0247-FEDER-039733, FATORST+ POCI-01-0247-ERDF-047124, MEDCOR PTDC/CTM-TEX/1213/2020, 4NoPressure POCI-01-0247-FEDER-039869 financed by FEDER through POCI under the “Portugal 2020” programme. RDVF and AIR also acknowledge Ph.D. scholarships SFRH/BD/145269/2019 and SFRH/BD/137668/2018, respectively

Enhancing the antimicrobial efficacy of polyester fabric impregnated with silver nanoparticles using DBD plasma treatment

The functionalization of polyester fabric (PES) with antimicrobial agents presents huge number of potential applications in advanced products. However, the lack of functional groups and the high PES hydrophobicity make the functionalization processes costly, prolonged and requires the use of polluting chemical compounds. In this work, dielectric barrier discharge (DBD) plasma treatment, an affordable and environmental-friendly method, was used to introduce new chemical groups, increase the surface energy and roughness of PES in order to improve the adhesion of silver nanoparticles (AgNPs) in its surface. The PES functionalization was evaluated by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and antimicrobial efficacy against Staphylococcus aureus and Escherichia coli. Despite some additional oxidation, the DBD plasma- treated PES showed superior adhesion of AgNPs and excellent antimicrobial efficacy even after 10 washing cycles (WC)

The assessment of bacterial nanocellulose functionalized with metal nanoparticles

[Excerpt] Introduction Biocompatibility is one of the mandatory requirements of indwelling medical devices to avoid foreign body reactions and consequential surgical removal.This research was funded by FEDER funds through the Operational Competitiveness Program–COMPETE, under the project POCI-01-0247-FEDER-068924 and by National Funds through Fundação para a Ciência e Tecnologia (FCT), under the project UID/CTM/00264/2020. Cátia Alves, Liliana Melro, Behnaz Mehravani, and Ana Isabel Ribeiro acknowledge FCT, MCTES, FSE, and UE PhD grants 2022.10454.BD, 2020.04919.BD, 2022.13094.BD, and SFRH/BD/137668/2018