Manufacturing and Characterization of Customizable Flexible Carbon Nanotube Fabrics for Smart Wearable Applications

The integration of carbon nanotube fabric into textiles is paving its way into smart materials and wearable applications. Potential novel applications of carbon nanotube hybrid (CNTH) materials and fabric composites span across a range of market levels from high-level PPE appropriate for military and industrial applications down to consumer products that can be used in everyday scenarios. The high-level performance properties of CNTH materials and their ability to be customized provide new possibilities for constructing fabrics with properties that are made to order. Furthermore, CNTH in combination with advanced textile compositing and construction methods allows the CNTH material to further leverage material customization aspects to meet specific requirements. The unique synthesis process for nanotube fabric allows for modification of the physical properties of the CNTH itself. The CNTH fabric combined with the customizability of standard textile composite materials and with the use of apparel design features allows for the design of materials with new combinations of physical properties. These unique properties offer high potential for developing families of smart wearable garments that can be scaled for industrial production. This article discusses the synthesis of carbon nanotube hybrid fabric, the process of hybrid fabric and textile integration, properties of the hybrid textile, and potential applications. The paper also provides an outlook towards large scale production of the hybrid textile material

Electrochemically Activated CNT Sheet as a Cathode for Zn-CO2 Batteries

High demand for electrochemical storage devices is increasing the need for high-performance batteries. A Zn-CO2 battery offers a promising solution for CO2 reduction as well as energy storage applications. For this study, a Zn-CO2 battery was fabricated using a Carbon Nanotube (CNT) sheet as a cathode and a Zn plate as an anode. The electrochemical activation technique was used to increase the surface area of the CNT electrode by roughly 4.5 times. Copper (Cu) as a catalyst was then deposited onto the activated CNT electrode using electrodeposition method and different Cu loadings were investigated to optimize CO2 reduction. The final assembled Zn-CO2 battery has a 1.6 V output voltage at a current density of 0.063 mA/cm2, which is higher than most devices reported in the literature. This study demonstrates the importance of activation process which enabled more catalyst loading on the cathode resulted in additional active sites for electroreduction process. This paper presents the activated CNT sheet as a promising cathode material for Zn-CO2 batteries

Flexible and Lightweight Carbon Nanotube Composite Filter for Particulate Matter Air Filtration

Particulate Matter (PM) has become an important source of air pollution. We proposed a flexible and lightweight carbon nanotube (CNT) composite air filter for PM removal. The developed CNT filtering layers were fabricated using a floating catalyst chemical vapor deposition (FC-CVD) synthesis process and then combined with conventional filter fabrics to make a composite air filter. Filtration performance for CNT filtering layer alone and composited with other conventional filter fabrics for particles size 0.3 μm to 2.5 μm was investigated in this study. The CNT composite filter is highly hydrophobic, making it suitable for humid environments. The CNT composite filter with two layers of tissue CNT performed best and achieved a filtration efficiency over 90% with a modest pressure drop of ~290 Pa for a particle size of 2.5 μm. This CNT composite filter was tested over multiple cycles to ensure its reusability. The developed filter is very light weight and flexible and can be incorporated into textiles for wearable applications or used as a room filter

Carbon Hybrid Materials—Design, Manufacturing, and Applications

Carbon nanotubes (CNTs) have extraordinary properties and are used for applications in various fields of engineering and research. Due to their unique combination of properties, such as good electrical and thermal conductivity and mechanical strength, there is an increasing demand to produce CNTs with enhanced and customized properties. CNTs are produced using different synthesis methods and have extraordinary properties individually at the nanotube scale. However, it is challenging to achieve these properties when CNTs are used to form macroscopic sheets, tapes, and yarns. To further improve the properties of macroscale forms of CNTs, various types of nanoparticles and microfibers can be integrated into the CNT materials. The nanoparticles and microfibers can be chosen to selectively enhance the properties of CNT materials at the macroscopic level. In this paper, we propose a technique to manufacture carbon hybrid materials (CHMs) by combining CNT non-woven fabric (in the form of sheets or tapes) with microfibers to form CNT-CF hybrid materials with new/improved properties. CHMs are formed by integrating or adding nanoparticles, microparticles, or fibers into the CNT sheet. The additive materials can be incorporated into the synthesis process from the inlet or the outlet of the reactor system. This paper focuses on CHMs produced using the gas phase pyrolysis method with microparticles/fibers integrated at the outlet of the reactor and continuous microfiber tapes integrated into the CNT sheet at the outlet using a tape feeding machine. After synthesis, characterizations such as microscopy and thermogravimetric analysis were used to study the morphology and composition of the CNTs, and examples for potential applications are discussed in this paper

Chlorosulfonic Acid Stretched Carbon Nanotube Sheet for Flexible and Low-Voltage Heating Applications

The carbon nanotube (CNT) is celebrated for its electrothermal property, which indicates the capability of a material to transform electrical energy into heat due to the Joule effect. The CNT nanostructure itself, as a one-dimensional material, limits the electron conduction path, thereby creating a unique heating phenomenon. In this work, we explore the possible correlation between CNT alignment in sheets and heating performance. The alignment of carbon nanotubes is induced by immersion and stretching in chlorosulfonic acid (CSA) solution. The developed CSA-stretched CNT sheet demonstrated excellent heating performance with a fast response rate of 6.5 °C/s and reached 180 °C in less than 30 s under a low voltage of 2.5 V. The heating profile of the stretched CNT sheet remained stable after bending and twisting movements, making it a suitable heating material for wearable devices, heatable smart windows, and in de-icing or defogging applications. The specific strength and specific conductance of the CSA-stretched CNT sheet also increased five- and two-fold, respectively, in comparison to the pristine CNT sheet