Projections for future radiocarbon content in dissolved inorganic carbon in hardwater lakes: a retrospective approach

Inland water bodies contain significant amounts of carbon in the form of dissolved inorganic carbon (DIC) derived from a mixture of modern atmospheric and pre-aged sources, which needs to be considered in radiocarbon-based dating and natural isotope tracer studies. While reservoir effects in hardwater lakes are generally considered to be constant through time, a comparison of recent and historical DI14C data from 2013 and 1969 for Lake Constance reveals that this is not a valid assumption. We hypothesize that changes in atmospheric carbon contributions to lake water DIC have taken place due to anthropogenically forced eutrophication in the 20th century. A return to more oligotrophic conditions in the lake led to reoxygenation and enhanced terrigenous organic matter remineralization, contributing to lake water DIC. Such comparisons using DI14C measurements from different points in time enable nonlinear changes in lake water DIC source and signature to be disentangled from concurrent anthropogenically induced changes in atmospheric 14C. In the future, coeval changes in lake dynamics due to climate change are expected to further perturb these balances. Depending on the scenario, Lake Constance DI14C is projected to decrease from the 2013 measured value of 0.856 Fm to 0.54–0.62 Fm by the end of the century

Effective Stress Liquefaction Analysis at the Wildlife Site

An incremental stress-strain model for granular soils based on fundamental soil mechanics principles is presented. The model captures the drained skeleton behavior observed in laboratory tests under cyclic loading. The undrained behavior is captured using the same skeleton stress-strain relation together with the volumetric constraint imposed by the pore water fluid. The model predicts cyclic simple shear response in close agreement with observed cyclic test data in terms of pore water pressure rise, cycles to trigger liquefaction, as well as the characteristic post-liquefaction response. Finally, the model is incorporated in a dynamic analyses procedure and applied to the field case history recorded at the Wildlife site. The recorded downhole time history was used as input and the predicted response compared with the field observation. In general, the agreement is good except for the pore water pressure response, which showed a more rapid rise than was observed

Two cardiac arrests, one medical team

Journal ArticleThe most painful of all medical care decisions concerns life-preserving measures which, because of limited resources, require certain individuals to be excluded in favor of others. How does one weigh the relative rights of individuals to such care? Whenever possible, decisions to withhold lifesaving therapy should be made in advance. but in the absence of a clear expression that lifesaving care should be withheld, the person in charge must assume that care was intended

A Laser System for the Spectroscopy of Highly-Charged Bismuth Ions

We present and characterize a laser system for the spectroscopy on highly-charged ^209Bi^82+ ions at a wavelength of 243.87 nm. For absolute frequency stabilization, the laser system is locked to a near-infra-red laser stabilized to a rubidium transition line using a transfer cavity based locking scheme. Tuning of the output frequency with high precision is achieved via a tunable rf offset lock. A sample-and-hold technique gives an extended tuning range of several THz in the UV. This scheme is universally applicable to the stabilization of laser systems at wavelengths not directly accessible to atomic or molecular resonances. We determine the frequency accuracy of the laser system using Doppler-free absorption spectroscopy of Te_2 vapour at 488 nm. Scaled to the target wavelength of 244 nm, we achieve a frequency uncertainty of \sigma_{244nm} = 6.14 MHz (one standard deviation) over six days of operation.Comment: Contribution to the special issue on "Trapped Ions" in "Applied Physics B

Polarized Neutron Laue Diffraction on a Crystal Containing Dynamically Polarized Proton Spins

We report on a polarized-neutron Laue diffraction experiment on a single crystal of neodynium doped lanthanum magnesium nitrate hydrate containing polarized proton spins. By using dynamic nuclear polarization to polarize the proton spins, we demonstrate that the intensities of the Bragg peaks can be enhanced or diminished significantly, whilst the incoherent background, due to proton spin disorder, is reduced. It follows that the method offers unique possibilities to tune continuously the contrast of the Bragg reflections and thereby represents a new tool for increasing substantially the signal-to-noise ratio in neutron diffraction patterns of hydrogenous matter.Comment: 5 pages, 3 figure

Cooperative Jahn-Teller Distortion in PrO2

We report neutron diffraction data on single crystal PrO2 which reveal a cooperative Jahn-Teller distortion at TD = 120 +/- 2 K. Below this temperature an internal distortion of the oxygen sublattice causes the unit cell of the crystallographic structure to become doubled along one crystal axis. We discuss several possible models for this structure. The antiferromagnetic structure below TN = 13.5 K is found to consist of two components, one of which shares the same doubled unit cell as the distorted crystallographic structure. We also present measurements of the magnetic susceptibility, the specific heat capacity and the electrical conductivity of PrO2. The susceptibility data show an anomaly at a temperature close to TD. From the specific heat capacity data we deduce that the ground state is doubly degenerate, consistent with a distortion of the cubic local symmetry. We discuss possible mechanisms for this. The conductivity shows an activated behaviour with an activation energy Ea = 0.262 +/- 0.003 eV.Comment: 12 pages, 14 figures, 2 tables. Additional suggested structure in v

Teaching in Rural Saskatchewan: First Year Teachers Identify Challenges and Make Recommendations

Despite the existing research on rural education, rural teaching, and pre-service rural practicum placements, there is little research on the experiences of beginning teachers in rural schools. The purpose of this study was to explore the experiences of Saskatchewan beginning teachers who obtain employment in rural or northern schools. Eight beginning teachers voluntarily participated in a telephone interview during their first year in the teaching profession. Their interviews highlighted shared themes related to the challenges of working in rural and northern communities, including: acceptance; understanding the community; isolation; overlap between personal and professional lives; and impact of rural context on workload. In addition, participants made recommendations for teachers considering employment in these environments, including: preparing to obtain a rural teaching position; seeking out mentorship relationships; and making connections within and outside of the community. These shared themes are discussed within the context of existing literature, and recommendations are made relating to future directions for research in this area

Sub-micron, Metal Gate, High-к Dielectric, Implant-free, Enhancement-mode III-V MOSFETs

The performance of 300nm, 500nm and 1μm metal gate, implant free, enhancement mode III-V MOSFETs are reported. Devices are realised using a 10nm MBE grown Ga2O3/(GaxGd1-x)2O3 high-κ (κ=20) dielectric stack grown upon a δ-doped AlGaAs/InGaAs/AlGaAs/GaAs heterostructure. Enhancement mode operation is maintained across the three reported gate lengths with a reduction in threshold voltage from 0.26 V to 0.08 V as the gate dimension is reduced from 1 μm to 300 nm. An increase in transconductance is also observed with reduced gate dimension. Maximum drain current of 420 μA/μm and extrinsic transconductance of 400 µS/µm are obtained from these devices. Gate leakage current of less than 100pA and subthreshold slope of 90 mV/decade were obtained for all gate lengths. These are believed to be the highest performance submicron enhancement mode III-V MOSFETs reported to date

Petrogenic organic carbon retention in terrestrial basins: a case study from perialpine Lake Constance

Inland waters play a major role in the global carbon cycle, with particulate organic carbon (POC) burial in terrestrial wetlands surpassing that in ocean sediments. Lake Constance, the second largest lake at the periphery of the European Alps, receives POC sourced from both aquatic and terrestrial productivity as well as petrogenic OC (OCpetro) from bedrock erosion. Distinguishing POC inputs to lake sediments is key to assessing carbon flux and fate as reworked OCpetro represents neither a net sink of atmospheric CO2 nor source of O2. New stable and radiocarbon isotopic data indicate that 11 (9–12) Gg/yr of OCpetro is buried in Lake Constance with underlying sediments on average containing 0.3 (0.25–0.33) wt% OCpetro. Extrapolation of these results suggests that 27 TgOCpetro/yr (12–54 TgOC/yr) could be subject to temporary geological storage in lakes globally, which is comparable to estimates of 43−25+61 TgOCpetro/yr delivered to the ocean by rivers (Galy et al., 2015). More studies are needed to quantify OCpetro burial in inland sedimentary reservoirs in order to accurately account for atmospheric carbon sequestration in terrestrial basins