Detecting Life-bearing Extra-solar Planets with Space Telescopes

One of the promising methods to search for life on extra-solar planets (exoplanets) is to detect life's signatures in their atmospheres. Spectra of exoplanet atmospheres at the modest resolution needed to search for oxygen, carbon dioxide, water, and methane will demand large collecting areas and large diameters to capture and isolate the light from planets in the habitable zones around the stars. For telescopes using coronagraphs to isolate the light from the planet, each doubling of telescope diameter will increase the available sample of stars by an order of magnitude, indicating a high scientific return if the technical difficulties of constructing very large space telescopes can be overcome. For telescopes detecting atmospheric signatures of transiting planets, the sample size increases only linearly with diameter, and the available samples are probably too small to guarantee detection of life-bearing planets. Using samples of nearby stars suitable for exoplanet searches, this paper shows that the demands of searching for life with either technique will require large telescopes, with diameters of order 10m or larger in space.Comment: 15 pages, 6 figures, submitted to Ap.

Sputtering of Oxygen Ice by Low Energy Ions

Naturally occurring ices lie on both interstellar dust grains and on celestial objects, such as those in the outer solar system. These ices are continu- ously subjected to irradiation by ions from the solar wind and/or cosmic rays, which modify their surfaces. As a result, new molecular species may form which can be sputtered off into space or planetary atmospheres. We determined the experimental values of sputtering yields for irradiation of oxygen ice at 10 K by singly (He+, C+, N+, O+ and Ar+) and doubly (C2+, N2+ and O2+) charged ions with 4 keV kinetic energy. In these laboratory experiments, oxygen ice was deposited and irradiated by ions in an ultra high vacuum chamber at low temperature to simulate the environment of space. The number of molecules removed by sputtering was observed by measurement of the ice thickness using laser interferometry. Preliminary mass spectra were taken of sputtered species and of molecules formed in the ice by temperature programmed desorption (TPD). We find that the experimental sputtering yields increase approximately linearly with the projectile ion mass (or momentum squared) for all ions studied. No difference was found between the sputtering yield for singly and doubly charged ions of the same atom within the experimental uncertainty, as expected for a process dominated by momentum transfer. The experimental sputter yields are in good agreement with values calculated using a theoretical model except in the case of oxygen ions. Preliminary studies have shown molecular oxygen as the dominant species sputtered and TPD measurements indicate ozone formation.Comment: to be published in Surface Science (2015

An All-Permanent Magnet 10 GHz "Multi-Mode" ECR Ion Source for the Production of Metallic Ions

In order to measure cross sections for charge-changing processes in collisions between ions in our ion-ion [1] experiment one ion beam has to be produced on a high voltage terminal. Since there are restrictions concerning the available space and electrical power an all-permanent magnet 10 GHz electron cyclotron resonance ions source has been built earlier [2]. This ion source is in operation and produces multiply charged ions from gaseous elements with sufficient intensities. Now there is a growing interest in the use of ions from metallic elements. For this purpose a new fully permanent 10 GHz ECR ion source has been constructed and tested. The main feature of this ion source is a stepped plasma chamber (see fig. 1) which allows the propagation of higher microwave modes in the plasma and also results in a bigger plasma volume. The longitudinal magnetic field for the axial plasma confinement is produced by two ring magnets whereas the radial magnetic field is formed by a Halbach-type [3] hexapole magnet. The microwave is produced in a frequency-tunable magnetron (8.75-10.5 GHz, 250 Watt max.) and coupled to the plasma via a coaxial line. The applied microwave frequency turned out to be one of the most important parameters when optimizing the ion source on different charge states since a variation of the magnetic field is not possible with the present configuration

Dynamics of Quasi-ordered Structure in a Regio-regulated pi-Conjugated Polymer:Poly(4-methylthiazole-2,5-diyl)

Dynamics of regio-regulated Poly(4-methylthiazole-2,5-diyl) [HH-P4MeTz] was inves tigated by solid-state 1H, 2D, 13C NMR spectroscopies, and differential scanning calorimetry(DSC) measurements. DSC, 2D quadrupolar echo NMR, 13C cross-polarization and magic-angle spinning(CPMAS) NMR, and 2D spin-echo(2DSE) CPMAS NMR spectroscopy suggest existence of a quasi-ordered phase in which backbone twists take place with weakened pi-stackings. Two-dimensional exchange 2D NMR(2DEX) detected slow dynamics with a rate of an order of 10^2Hz for the CD_3 group in d_3-HH-P4MeTz at 288K. The frequency dependence of proton longitudinal relaxation rate at 288K shows a omega^-1/2 dependence, which is due to the one-dimensional diffusion-like motion of backbone conformational modulation waves. The diffusion rate was estimated as 3+/-2 GHz, which was approximately 10^7 times larger than that estimated by 2DEX NMR measurements. These results suggest that there exists anomalous dispersion of modulation waves in HH-P4MeTz. The one-dimensional group velocity of the wave packet is responsible for the behavior of proton longitudinal relaxation time. On the other hand, the 2DEX NMR is sensitive to phase velocity of the nutation of methyl groups that is associated with backbone twists. From proton T_1 and T_2 measurements, the activation energy was estimated as 2.9 and 3.4 kcal/mol, respectively. These were in agreement with 3.0 kcal/mol determined by Moller-Plesset(MP2) molecular orbital(MO) calculation. We also performed chemical shielding calculation of the methyl-carbon in order to understand chemical shift tensor behavior, leading to the fact that a quasi-ordered phase coexist with the crystalline phase.Comment: 14 pages, 11 figures, to appear in Phys.Rev.

Microwave Electronics

Contains reports on four research projects.Lincoln Laboratory (Purchase Order B-00306)United States Air Force (Contract AF19(604)-5200)United States NavyUnited States Arm