MAGSAT anomaly field inversion and interpretation for the US

Long wavelength anomalies in the total magnetic field measured by MAGSAT over the United States and adjacent areas are inverted to an equivalent layer crustal magnetization distribution. The model is based on an equal area dipole grid at the Earth's surface. Model resolution, defined as the closest dipole spacing giving a solution having physical significance, is about 220 km for MAGSAT data in the elevation range 300-500 km. The magnetization contours correlate well with large scale tectonic provinces. A higher resolution (200 km) model based on relatively noise free synthetic "pseudodata" is also presented. Magnetic anomaly component data measured by MAGSAT is compared with synthetic anomaly component fields arising from an equivalent source dipole array at the Earth's surface generated from total field anomaly data alone. An excellent inverse correlation between apparent magnetization and heat flow in the western U.S. is demonstrated. A regional heat flow map which is presented and compared with published maps, predicts high heat flow in Nebraska and the Dakotas, suggesting the presence of a "blind" geothermal area of regional extent

Equivalent source modeling of the main field using MAGSAT data

An iterative least squares estimation algorithm with the capability for including a priori statistical information was implemented to recover multiple magnetic dipole models of the Earth's main magnetic field. The dipoles are fixed to a specified radius at or below the core-mantle boundary and centered on equal area blocks. The algorithm can solve for dipole magnitudes only (fixed orientations), or allow full freedom of orientation and solve for vector components. External field parameters and observatory anomaly biases can also be estimated simultaneously. Time dependence is modeled using first time derivatives for dipole vector components. Single-epoch and time dependent dipole models are derived using MAGSAT and observatory annul means data. Equivalent spherical harmonic representation are computed in closed form from the dipole models and compared with truncated spherical harmonic models estimated in the standard way from the same data sets. In particular, a 21 deg spatial resolution model based on 93 dipoles was computed based on observatory annual means data and a selected MAGSAT data set and was compared with candidate IGRF 1975 models and their 1980 secular variation

An equivalent layer magnetization model for the United States derived from MAGSAT data

Long wavelength anomalies in the total magnetic field measured field measured by MAGSAT over the United States and adjacent areas are inverted to an equivalent layer crustal magnetization distribution. The model is based on an equal area dipole grid at the Earth's surface. Model resolution having physical significance, is about 220 km for MAGSAT data in the elevation range 300-500 km. The magnetization contours correlate well with large-scale tectonic provinces

Isomeric effects in the gas-phase reactions of dichloroethene, C2H2Cl2, with a series of cations

A study of the reactions of a series of gas-phase cations (NH$_4^+$, H$_3$O$^+$, SF$_3^+$, CF$_3^+$, CF$^+$, SF5$^+$, SF$_2^+$, SF$^+$, CF$_2^+$, SF$_4^+$, O$_2^+$, Xe$^+$, N$_2$O$^+$, CO$_2^+$, Kr$^+$, CO$^+$, N$^+$, N$_2^+$, Ar$^+$, F$^+$ and Ne$^+$) with the three structural isomers of dichloroethene, i.e. 1,1-C$_2$H$_2$Cl$_2$, cis-1,2-C$_2$H$_2$Cl$_2$ and trans-1,2-C$_2$H$_2$Cl$_2$ is reported. The recombination energy of these ions spans the range 4.7-21.6 eV. Reaction rate coefficients and product branching ratios have been measured at 298 K in a selected ion flow tube. Collisional rate coefficients are calculated by modified average dipole orientation theory and compared with experimental data. Thermochemistry and mass balance have been used to predict the most feasible neutral products. Threshold photoelectron-photoion coincidence spectra have also been obtained for the three isomers of C$_2$H$_2$Cl$_2$ with photon energies in the range 10-23 eV. The fragment ion branching ratios have been compared with those of the flow tube study to determine the importance of long-range charge transfer. A strong influence of the isomeric structure of dichloroethene on the products of ion-molecule reactions has been observed for H$_3$O$^+$, CF$_3^+$, and CF$^+$. For 1,1-C$_2$H$_2$Cl$_2$ the reaction with H$_3$O$^+$ proceeds at the collisional rate with the only ionic product being 1,1-C$_2$H$_2$Cl$_2$H$^+$. However, the same reaction yields two more ionic products in the case of cis-1,2- and trans-1,2-C$_2$H$_2$Cl$_2$, but only proceeds with 14 % and 18 % efficiency, respectively. The CF$_3^+$ reaction proceeds with 56-80 % efficiency, the only ionic product for 1,1-C$_2$H$_2$Cl$_2$ being C$_2$H$_2$Cl$^+$ formed via Cl- abstraction, whereas the only ionic product for both 1,2-isomers is CHCl$_2^+$ corresponding to a breaking of the C=C double bond. Less profound isomeric effects, but still resulting in different products for 1,1- and 1,2-C$_2$H$_2$Cl$_2$ isomers, have been found in the reactions of SF$^+$, CO$_2^+$, CO$^+$, N$_2^+$, and Ar$^+$. Although these five ions have recombination energies above the ionization energy of any of the C$_2$H$_2$Cl$_2$ isomers and hence the threshold for long-range charge transfer, the results suggest that the formation of a collision complex at short range between these ions and C$_2$H$_2$Cl$_2$ is responsible for the observed effects

Comparison of Magnetic Anomalies of Lithospheric Origin Measured by Satellite and Airborne Magnetometers over Western Canada

Crustal magnetic anomaly data from the OGO 2, 4 and 6 (Pogo) satellites are compared with upward-continued aeromagnetic data between 50 deg -85 deg N latitude and 220 deg - 260 deg E longitude. Agreement is good both in anomaly location and in amplitude, giving confidence that it is possible to proceed with the derivation and interpretation of satellite anomaly maps in all parts of the globe. The data contain a magnetic high over the Alpha ridge suggesting continental composition and a magnetic low over the southern Canada basin and northern Canadian Arctic islands (Sverdrup basin). The low in the Sverdrup basin corresponds to a region of high heat flow, suggesting a shallow Curie isotherm. A ridge of high field, with two distinct peaks in amplitude, is found over the northern portion of the platform deposits and a relative high is located in the central portion of the Churchill province. No features are present to indicate a magnetic boundary between Slave and Bear provinces, but a trend change is evident between Slave and Churchill provinces. South of 60 deg latitude a broad magnetic low is located over very thick (40-50 km) crust, interpreted to be a region of low magnetization

A Selected Ion Flow Tube Study of the Reactions of Several Cations with the Group 6B Hexafluorides SF6, SeF6, and TeF6

The first investigation of the ion chemistry of SeF$_6$ and TeF$_6$ is presented. Using a selected ion flow tube, the thermal rate coefficients and ion product distributions have been determined at 300 K for the reactions of fourteen atomic and molecular cations, namely H$_3$O$^+$, CF$_3^+$, CF$^+$, CF$_2^+$, H$_2$O$^+$, N$_2$O$^+$, O$^+$, CO$_2^+$, CO$^+$, N$^+$, N$_2^+$, Ar$^+$, F$^+$ and Ne$^+$ (in order of increasing recombination energy), with SeF$_6$ and TeF$_6$. The results are compared with those from the reactions of these ions with SF$_6$, for which the reactions with CF$^+$, CF$_2^+$, N$_2$O$^+$ and F$^+$ are reported for the first time. Several distinct processes are observed amongst the large number of reactions studied, including dissociative charge transfer, and F$^-$, F, F$_2^-$ and F$_2$ abstraction from the neutral reactant molecule to the reagent ion. The dissociative charge transfer channels are discussed in relation to vacuum ultraviolet photoelectron and threshold photoelectron-photoion coincidence spectra of XF$_6$ (X = S, Se, and Te). For reagent ions whose recombination energies lie between the first dissociative ionisation limit, XF$_6$ $\rightarrow$ XF$_5^+$ + F + e$^-$, and the onset of ionisation of the XF$_6$ molecule, the results suggest that if dissociative charge transfer occurs, it proceeds via an intimate encounter. For those reagent ions whose recombination energies are greater than the onset of ionisation, long-range electron transfer may occur depending on whether certain physical factors apply, for example non-zero Franck-Condon overlap. From the reaction kinetics, limits for the heats of formation of SeF$_4$, SeF$_5$, TeF$_4$ and TeF$_5$ at 298 K have been obtained; $\Delta_f$H$^o$(SeF$_4$) < -369 kJ mol$^{-1}$, $\Delta_f$H$^o$(SeF$_5$) < -621 kJ mol$^{-1}$, $\Delta_f$H$^o$(TeF$_4$) > -570 kJ mol$^{-1}$, and $\Delta_f$H$^o$(TeF$_5$) < -822 kJ mol$^{-1}$

Satellite and surface geophysical expression of anomalous crustal structure in Kentucky and Tennessee

An equivalent layer magnetization model is discussed. Inversion of long wavelength satellite magnetic anomaly data indicates a very magnetic source region centered in south central Kentucky. Refraction profiles suggest that the source of the gravity anomaly is a large mass of rock occupying much of the crustal thickness. The outline of the source delineated by gravity contours is also discernible in aeromagnetic anomaly patterns. The mafic plutonic complex, and several lines of evidence are consistent with a rift association. The body is, however, clearly related to the inferred position of the Grenville Front. It is bounded on the north by the fault zones of the 38th Parallel Lineament. It is suggested that such magnetization levels are achieved with magnetic mineralogies produced by normal oxidation and metamorphic processes and enhanced by viscous build-up, especially in mafic rocks of alkaline character

Threshold photoelectron photoion coincidence spectroscopy and selected ion flow tube reactions of CHF3: comparison of product branching ratios

The threshold photoelectron and threshold photoelectron photoion coincidence spectra of CHF$_3$ in the range 13.5 – 24.5 eV have been recorded. Ion yields and branching ratios have been determined for the three fragments CF$_3^+$, CHF2$^+$ and CF$^+$. The mean kinetic energy releases into fragment ions involving either C-H or C-F bond cleavage have been measured, and compared with statistical and impulsive models. CHF$_3^+$ behaves in a non-statistical manner characteristic of the small-molecule limit, with the ground electronic state and low-lying excited states of CHF$_3^+$ being largely repulsive along the C-H and C-F coordinates, respectively. The rate coefficients and product ion branching ratios have been measured at 298 K in a selected ion flow tube for the reactions of CHF$_3$ with a large number of gas-phase cations whose recombination energies span the range 6.3 through 21.6 eV. A comparison between the branching ratios from the two experiments, together with an analysis of the threshold photoelectron spectrum of CHF$_3$, shows that long-range charge transfer probably occurs for the Ar$^+$ and F$^+$ atomic ions whose recombination energies lie above ca. 15 eV. Below this energy, the mechanism involves a combination of short-range charge transfer and chemical reactions involving a transition state intermediate