Optimizing Thermoelectric Efficiency in La_(3−x)Te_4 via Yb Substitution

A low temperature, solid state synthesis technique has enabled the production of homogeneous samples of La_(3−x−y)Yb_yTe_4. This allows the substitution of divalent Yb to be utilized to optimize the thermoelectric performance in lanthanum telluride. The addition of Yb^(2+) changes the electrical transport properties in a manner that can be well understood using valence counting rules and a corresponding change in the Fermi energy. The substitution of Yb^(2+) for La^(3+) results in a threefold finer control over the carrier density n, thus allowing the optimum n ~ 0.3 × 10^(21) cm^(−3) to be both predicted and prepared. The net result is an improvement in thermoelectric efficiency, with zT reaching ~ 1.2 at 1273 K

Particular Solutions in Bimetric Theory and Their Implications

Ghost-free bimetric theory can describe gravity in the presence of an extra spin-2 field. We study certain aspects of dynamics in this theory: (1) It is shown that if either of the metrics is an Einstein solution then the other is always forced to be Einstein, too. For a class of bimetric models this constraint is stronger and as soon as one metric is Einstein, the other metric is forced to be proportional to it. As a consequence, the models in this class avoid a branch of pathological solutions that exhibit determinant singularities or nonlinear ghosts. These constraints persists in a generalized form when sources are included, but are destroyed in the massive gravity limit of the theory. (2) For another class of bimetric models, we show the existence of solutions that do not admit a massive gravity limit. A bimetric model that could exhibit a nonlinear version of "partially massless" symmetry belongs to both these classes. It is argued that if such a model exits, its symmetry will not survive in the massive gravity limit.Comment: Latex, 18 pages. Published versio

Zintl Chemistry for Designing High Efficiency Thermoelectric Materials

Zintl phases and related compounds are promising thermoelectric materials; for instance, high zT has been found in Yb_(14)MnSb_(11), clathrates, and the filled skutterudites. The rich solid-state chemistry of Zintl phases enables numerous possibilities for chemical substitutions and structural modifications that allow the fundamental transport parameters (carrier concentration, mobility, effective mass, and lattice thermal conductivity) to be modified for improved thermoelectric performance. For example, free carrier concentration is determined by the valence imbalance using Zintl chemistry, thereby enabling the rational optimization of zT. The low thermal conductivity values obtained in Zintl thermoelectrics arise from a diverse range of sources, including point defect scattering and the low velocity of optical phonon modes. Despite their complex structures and chemistry, the transport properties of many modern thermoelectrics can be understood using traditional models for heavily doped semiconductors