1 research outputs found
Charge transfer mechanism and Tc(x) dependence in Y0.8(Ca)0.2Ba2Cu3O6+x
We propose a model for charge transfer mechanism in Y0.8(Ca)0.2Ba2Cu3O6+x to
count hole doping of CuO2 planes and x dependence of critical transition
temperature T_c. It is assumed the total number of doped holes in the planes is
sum of holes that are introduced through two separate channels: substitution of
Y3+ by Ca2+ and from CuO chains that are longer than a minimal (critical)
length l_min needed for charge transfer to take place. The T_c(x) dependence is
obtained by combining calculated x dependence of doping, p(x), and universal
T_c versus p relation. Although calculated T_c(x) dependences for l_min=3 and
l_min=4 both remarkably correlate to the experimental T_c(x), we argue that the
value l_min=4 gives a reasonable overall agreement.Comment: Four pages of text, 2 figures, corrected typing error in abstract:
Y2+ and Ca3+ replaced by Y3+ and Ca2+. Thw word "each" added in page 3, line
4. Accepted in Superconductor Science and Technology, on 07.Apr.2008, after
having been considerably revise