Crystal structure of 2-{[(2-chlorophenyl)imino]methyl}phenol

In the title compound, C13H10ClNO, the dihedral angle between the planes of the aromatic rings is 51.42 (9)° and an intramolecular O—H...N hydrogen bond closes an S(6) ring. The Cl atom and the N atom are syn. No directional interactions beyond van der Waals contacts are observed in the crystal

Crystal structure of 3-acetoxy-2-methylbenzoic acid

In the title molecule, C10H10O4, the carboxylic acid group is twisted by 11.37 (15)° from the plane of the benzene ring and the acetoxy group is twisted from this plane by 86.60 (17)°. In the crystal, molecules are linked by pairs of O—H...O hydrogen bonds, forming inversion dimers with the expected R22(8) graph-set motif