14,276 research outputs found

    New Requirements of Creditor Notice in Probate Proceedings

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    Crystallographic investigation into the self-assembly, guest binding, and flexibility of urea functionalised metal-organic frameworks

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    Introduction of hydrogen bond functionality into metal-organic frameworks can enhance guest binding and activation, but a combination of linker flexibility and interligand hydrogen bonding often results in the generation of unwanted structures where the functionality is masked. Herein, we describe the self-assembly of three materials, where Cd2+, Ca2+, and Zn2+ are linked by N,NÊč-bis(4-carboxyphenyl)urea, and examine the effect of the urea units on structure formation, the generation of unusual secondary building units, structural flexibility, and guest binding. The flexibility of the Zn MOF is probed through single-crystal to single-crystal transformations upon exchange of DMF guests for CS2, showing that the lability of the [Zn4O(RCO2)6] cluster towards solvation enables the urea linkers to adopt distorted conformations as the MOF breathes, even facilitating rotation from the trans/trans to the trans/cis conformation without compromising the overall topology. The results have significant implications in the mechanistic understanding of the hydrolytic stability of MOFs, and in preparing heterogeneous organocatalysts

    Consumer Choice and Beads in Fugitive Slave Villages in Nineteenth-Century Kenya

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    This study analyzes the consumption of European glass beads at two fugitive slave villages in nineteenth-century Kenya, Koromio and Makoroboi. The consumer choices of Koromio and Makoroboi residents reveal a strategic and symbolic material language. Specifically, the inter-household distribution of European glass beads reflects considerable variation in the performance of female identity. This distribution suggests varying norms of feminine adornment. Some of these norms likely originated in runaways’ natal communities; others may have developed during enslavement. The variability in adornment practices additionally points to women’s improvisation amid shifting gender relations in these nascent fugitive slave communities

    X-ray Emission Diagnostics from the M87 Jet

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    We use Chandra, HST and VLA observations of M87 to investigate the physics of X-ray emission from AGN jets. We find that X-ray hotspots in the M87 jet occur primarily in regions with hard optical-to-X-ray spectra and lower than average polarization. Particle injection appears to be required both continuously in the jet sheath as well as locally at X-ray hotspots.Comment: 4 pages, 2 figures, submitted to "The Physics of Relativistic Jets in the CHANDRA and XMM Era", Bologna 200

    Investigations on the scatterings of x-rays

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    A review of corneal biomechanics: Mechanisms for measurement and the implications for refractive surgery

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    Detailed clinical assessment of corneal biomechanics has the potential to revolutionize the ophthalmic industry through enabling quicker and more proficient diagnosis of corneal disease, safer and more effective surgical treatments, and the provision of customized and optimized care. Despite these wide-ranging benefits, and an outstanding clinical need, the provision of technology capable of the assessment of corneal biomechanics in the clinic is still in its infancy. While laboratory-based technologies have progressed significantly over the past decade, there remain significant gaps in our knowledge regarding corneal biomechanics and how they relate to shape and function, and how they change in disease and after surgical intervention. Here, we discuss the importance, relevance, and challenges associated with the assessment of corneal biomechanics and review the techniques currently available and underdevelopment in both the laboratory and the clinic

    X-ray Emission Processes in Extragalactic Jets, Lobes and Hot Spots

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    This paper is a brief review of the processes responsible for X-ray emission from radio jets, lobes and hot spots. Possible photons in inverse Compton scattering models include the radio synchrotron radiation itself (i.e. synchrotron self-Compton [SSC] emission), the cosmic microwave background (CMB), the galaxy starlight and radiation from the active nucleus. SSC emission has been detected from a number of hot spots. Scattering of the CMB is expected to dominate for jets (and possibly hot spots) undergoing bulk relativistic motion close to the direction towards the observer. Scattering of infrared radiation from the AGN should be observable from radio lobes, especially if they are close to the active nucleus. Synchrotron radiation is detected in some sources, most notably the jet of M87. I briefly discuss why different hot spots emit X-rays by different emission mechanisms and the nature of the synchrotron spectra.Comment: To be published in the proceedings of the Bologna conference ``The Physics of Relativistic Jets in the Chandra and XMM Era'', New Astronomy Revie
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