Allylation of Orthoquinones Towards Annulated Polycyclic Aromatic Systems

Promising results of an efficient and convenient strategy for the annulation of polycyclic aromatic compounds (PACs), employing orthoquinones as starting material and comprising allylation, pinacol rearrangement, ring-closing metathesis (RCM), and one-pot reduction followed by Wagner-Meerwein rearrangement, are presented. The strategy involves introducing triallylborane prepared in situ in the allylation step. Moreover, a novel expedient method for the preparation of 9,10-diallylphenanthrene was introduced

Analysis and Evaluation of Methods Used in Measuring the Intensity of Bicycle Traffic

The work presents the methods of collecting and processing data with the use of devices used in individual measurement methods. Based on the collected video materials, the number of vehicles was determined, which at both measuring points actually exceeded each of the tested cross-sections of the bicycle path. More precise determination of the means of transport was divided into three categories: bicycles, electric scooters, and PT (personal transporters). The data collected with the use of each of the devices was properly processed and aggregated into a form that allows for their mutual comparison (they can be used to manage the energy of electric vehicles). Their greatest advantages and disadvantages were indicated, and external factors that had an impact on the size of the measurement error were identified. The cost of carrying out the traffic volume survey was also assessed, broken down into the measurement methods used. The purpose of this paper is to analyse and evaluate the methods used to measure bicycle traffic volume. Four different measurement methods were used to perform the practical part, which included such devices as a video recorder, microwave radar, perpendicular radar, and a meter connected to an induction loop embedded in the asphalt. The results made it possible to select a rational method for measuring the volume of bicycle traffic. The measurements carried out allow optimization of bicycle routes, especially for electric bicycles. The results indicate the method of physical counting of vehicles from video footage, thanks to which it is possible to achieve a level of measurement accuracy equal to 100%