Quasi-Static Transduction Characterization of Galfenol

The objective of the work presented is characterization of the magnetoelastic transduction properties of single crystal and textured polycrystalline Fe-Ga alloys (Galfenol) under controlled mechanical, magnetic and thermal conditions. Polycrystalline samples of interest include a directionally solidified specimen, which possesses a favorable saturation magnetostriction output, and an extruded specimen, whose magnetostriction properties were significantly reduced by annealing. A brief discussion of the thermally controlled transducer used for the magnetic testing is presented first. Thereafter, the single crystal response to major-loop cyclic magnetic fields under different temperature and stress conditions, as well as its response to minor-loop cyclic magnetic fields and major-loop cyclic stress is examined. Next, the magnetic and magnetostrictive responses to major-loop cyclic magnetic field conditions are compared for the directionally solidified, extruded and single crystal specimens. The paper concludes with a magnetic characterization summary of the different Fe-Ga alloys examined

Mechanical properties of magnetostrictive iron-gallium alloys

Single crystal specimens of Fe-17 at. % Ga were tested in tension at room temperature. Specimens with a tensile axis orientation of [110] displayed slip lines on the specimen faces corresponding to slip on the {110}with a critical resolved shear stress of 220 MPa. Yielding began at 0.3% elongation and 450 MPa. An ultimate tensile strength of 580 MPa was observed with no fracture occurring through 1.6% elongation. The Young s modulus was 160 GPa in the loading direction with a Poisson s ratio of -0.37 on the (100) major face. A specimen with a tensile axis orientation of [100] showed slip lines corresponding to slip on the {211}with critical resolved shear stress of 240 MPa. Discontinuous yielding began at 0.8% elongation, which was thought to result from twinning, kink band formation, or stress-induced transformation. The Young\u27s modulus was 65 GPa in the loading direction with a Poisson s ratio of 0.45 on the (001) major face. A maximum tensile strength of 515 MPa was observed with fracture occurring after 2% elongation. A sizeable elastic anisotropy of 19.9 was identified for Fe-27.2 at. % Ga accompanied by a Poisson\u27s ratio of -0.75 to produce a large in-plane auxetic behavior

Effects of Zn additions to highly magnetoelastic FeGa alloys

Fe1−xMx (M = Ga, Ge, Si, Al, Mo and x ∼ 0.18) alloys offer an extraordinary combination ofmagnetoelasticity and mechanical properties. They are rare-earth-free, can be processed using conventional deformation techniques, have high magnetic permeability, low hysteresis, and low magnetic saturation fields, making them attractive for device applications such as actuators and energy harvesters. Starting with Fe-Ga as a reference and using a rigid-band-filling argument, Zhang et al. predicted that lowering the Fermi level by reducing the total number of electrons could enhance magnetoelasticity. To provide a direct experimental validation for Zhang\u27s hypothesis, elemental additions with lower-than-Ga valence are needed. Of the possible candidates, only Be and Zn have sufficient solubility. Single crystals of bcc Fe-Ga-Zn have beengrown with up to 4.6 at. % Zn in a Bridgman furnace under elevated pressure (15 bars) in order to overcome the high vapor pressure of Zn and obtain homogeneous crystals. Single-crystalmeasurements of magnetostriction and elastic constants allow for the direct comparison of themagnetoelastic coupling constants of Fe-Ga-Zn with those of other magnetoelastic alloys in its class. The partial substitution of Ga with Zn yields values for the magnetoelastic coupling factor, −b 1, comparable to those of the binary Fe-Ga alloy

Rhombohedral magnetostriction in dilute iron (Co) alloys

Iron is a well-utilized material in structural and magnetic applications. This does not mean, however, that it is well understood, especially in the field of magnetostriction. In particular, the rhombohedral magnetostriction of iron, λ111 , is anomalous in two respects: it is negative in sign, in disagreement with the prediction of first principles theory, and its magnitude decreases with increasing temperature much too rapidly to be explained by a power law dependence on magnetization. These behaviors could arise from the location of the Fermi level, which leaves a small region of the majority 3d t2g states unfilled, possibly favoring small internal displacements that split these states. If this view is correct, adding small amounts of Co to Fe fills some of these states, and the value of λ111 should increase toward a positive value, as predicted for perfect bcc Fe. We have measured the magnetostriction coefficients (λ111 and λ100) of pure Fe, Fe97Co3, and Fe94Co6 single crystals from 77 K to 450 K. Resonant ultrasound spectroscopy has been used to check for anomalies in the associated elastic constants, c 44 and c′. The additional electrons provided by the cobalt atoms indeed produced positive contributions to bothmagnetostriction constants, λ111 and λ100, exhibiting an increase of 2.8 × 10−6 per at. % Co for λ111 and 3.8 × 10−6 per at. % Co for λ100

INDUCED MAGNETIC ANISOTROPY IN STRESS-ANNEALED GALFENOL LAMINATED RODS

ABSTRACT The recent discovery of Iron-Gallium alloy (Galfenol) as a "large" magnetostrictive material (as high as 400 ppm) offers a particularly promising transducer material that combines largely desirable mechanical attributes with superior magnetic propertie

Quasi-Static Transduction Characterization of Galfenol

The objective of the work presented is characterization of the magnetoelastic transduction properties of single crystal and textured polycrystalline Fe-Ga alloys (Galfenol) under controlled mechanical, magnetic and thermal conditions. Polycrystalline samples of interest include a directionally solidified specimen, which possesses a favorable saturation magnetostriction output, and an extruded specimen, whose magnetostriction properties were significantly reduced by annealing. A brief discussion of the thermally controlled transducer used for the magnetic testing is presented first. Thereafter, the single crystal response to major-loop cyclic magnetic fields under different temperature and stress conditions, as well as its response to minor-loop cyclic magnetic fields and major-loop cyclic stress is examined. Next, the magnetic and magnetostrictive responses to major-loop cyclic magnetic field conditions are compared for the directionally solidified, extruded and single crystal specimens. The paper concludes with a magnetic characterization summary of the different Fe-Ga alloys examined. This article is from ASME 2003 International Mechanical Engineering Congress and Exposition 68 (2003): pp. 273-280, doi:10.1115/IMECE2003-43140 http://dx.doi.org/10.1115/IMECE2003-43140</p

Mechanical properties of magnetostrictive iron-gallium alloys

Single crystal specimens of Fe-17 at. % Ga were tested in tension at room temperature. Specimens with a tensile axis orientation of [110] displayed slip lines on the specimen faces corresponding to slip on the {110}with a critical resolved shear stress of 220 MPa. Yielding began at 0.3% elongation and 450 MPa. An ultimate tensile strength of 580 MPa was observed with no fracture occurring through 1.6% elongation. The Young"s modulus was 160 GPa in the loading direction with a Poisson"s ratio of -0.37 on the (100) major face. A specimen with a tensile axis orientation of [100] showed slip lines corresponding to slip on the {211}with critical resolved shear stress of 240 MPa. Discontinuous yielding began at 0.8% elongation, which was thought to result from twinning, kink band formation, or stress-induced transformation. The Young's modulus was 65 GPa in the loading direction with a Poisson"s ratio of 0.45 on the (001) major face. A maximum tensile strength of 515 MPa was observed with fracture occurring after 2% elongation. A sizeable elastic anisotropy of 19.9 was identified for Fe-27.2 at. % Ga accompanied by a Poisson's ratio of -0.75 to produce a large in-plane auxetic behavior.Proc. SPIE 5053, Smart Structures and Materials 2003: Active Materials: Behavior and Mechanics, 534 (August 12, 2003); doi:10.1117/12.484347 Copyright 2003 Society of Photo Optical Instrumentation Engineers. One print or electronic copy may be made for personal use only. Systematic reproduction and distribution, duplication of any material in this paper for a fee or for commercial purposes, or modification of the content of the paper are prohibited. http://dx.doi.org/10.1117/12.484347</p

Non-Resonant Magnetoelectric Energy Harvesting Utilizing Phase Transformation in Relaxor Ferroelectric Single Crystals

Recent advances in phase transition transduction enabled the design of a non-resonant broadband mechanical energy harvester that is capable of delivering an energy density per cycle up to two orders of magnitude larger than resonant cantilever piezoelectric type generators. This was achieved in a [011] oriented and poled domain engineered relaxor ferroelectric single crystal, mechanically biased to a state just below the ferroelectric rhombohedral (FR)-ferroelectric orthorhombic (FO) phase transformation. Therefore, a small variation in an input parameter, e.g., electrical, mechanical, or thermal will generate a large output due to the significant polarization change associated with the transition. This idea was extended in the present work to design a non-resonant, multi-domain magnetoelectric composite hybrid harvester comprised of highly magnetostrictive alloy, [Fe81.4Ga18.6 (Galfenol) or TbxDy1-xFe2 (Terfenol-D)], and lead indium niobate–lead magnesium niobate–lead titanate (PIN-PMN-PT) domain engineered relaxor ferroelectric single crystal. A small magnetic field applied to the coupled device causes the magnetostrictive element to expand, and the resulting stress forces the phase change in the relaxor ferroelectric single crystal. We have demonstrated high energy conversion in this magnetoelectric device by triggering the FR-FO transition in the single crystal by a small ac magnetic field in a broad frequency range that is important for multi-domain hybrid energy harvesting devices