4 research outputs found
Synthesis, crystal structure and spin-density-wave anomaly of the iron arsenide-fluoride SrFeAsF
The new quaternary iron arsenide-fluoride SrFeAsF with the tetragonal
ZrCuSiAs-type structure was synthesized and the crystal structure was
determined by X-ray powder diffraction (P4/nmm, a = 399.30(1), c = 895.46(1)
pm). SrFeAsF undergoes a structural and magnetic phase transition at 175 K,
accompanied by strong anomalies in the specific heat, electrical resistance and
magnetic susceptibility. In the course of this transition, the space group
symmetry changes from tetragonal (P4/nmm) to orthorhombic (Cmme). 57Fe
Moessbauer spectroscopy experiments show a single signal at room temperature at
an isomer shift of 0.30(1) mm/s and magnetic hyperfine-field splitting below
the phase transition temperature. Our results clearly show that SrFeAsF
exhibits a spin density wave (SDW) anomaly at 175 K very similar to LaFeAsO,
the parent compound of the iron arsenide-oxide superconductors and thus SrFeAsF
may serve as a further parent compound for oxygen-free iron arsenide
superconductors.Comment: 5 pages, 7 figure
Crystallographic Phase Transition and High-Tc Superconductivity in LaFeAsO:F
Undoped LaFeAsO, parent compound of the newly found high-Tc superconductor,
exhibits a sharp decrease in the temperature-dependent resistivity at ~160 K.
The anomaly can be suppressed by F doping and the superconductivity appears
correspondingly, suggesting a close associate of the anomaly with the
superconductivity. We examined the crystal structures, magnetic properties and
superconductivity of undoped (normal conductor) and 14 at.% F-doped LaFeAsO (Tc
= 20 K) by synchrotron X-ray diffraction, DC magnetic measurements, and ab
initio calculations to demonstrate that the anomaly is associated with a phase
transition from tetragonal (P4/nmm) to orthorhombic (Cmma) phases at ~160 K as
well as an antiferromagnetic transition at ~140 K. These transitions can be
explained by spin configuration-dependent potential energy surfaces derived
from the ab initio calculations. The suppression of the transitions is ascribed
to interrelated effects of geometric and electronic structural changes due to
doping by F- ions.Comment: 22 pages, 8 figures, 2 tables, Supplementary information is included
at the end of the document, accepted for publication in Supercond. Sci.
Techno
Coexistence of the spin-density-wave and superconductivity in the (Ba,K)Fe2As2
The relation between the spin-density-wave (SDW) and superconducting order is
a central topic in current research on the FeAs-based high Tc superconductors.
Conflicting results exist in the LaFeAs(O,F)-class of materials, for which
whether the SDW and superconductivity are mutually exclusive or they can
coexist has not been settled. Here we show that for the (Ba,K)Fe2As2 system,
the SDW and superconductivity can coexist in an extended range of compositions.
The availability of single crystalline samples and high value of the energy
gaps would make the materials a model system to investigate the high Tc
ferropnictide superconductivity.Comment: 4 pages, 5 figure
Feshbach resonances and mesoscopic phase separation near a quantum critical point in multiband FeAs-based superconductors
High Tc superconductivity in FeAs-based multilayers (pnictides), evading
temperature decoherence effects in a quantum condensate, is assigned to a
Feshbach resonance (called also shape resonance) in the exchange-like interband
pairing. The resonance is switched on by tuning the chemical potential at an
electronic topological transition (ETT) near a band edge, where the Fermi
surface topology of one of the subbands changes from 1D to 2D topology. We show
that the tuning is realized by changing i) the misfit strain between the
superconducting planes and the spacers ii) the charge density and iii) the
disorder. The system is at the verge of a catastrophe i.e. near a structural
and magnetic phase transition associated with the stripes (analogous to the 1/8
stripe phase in cuprates) order to disorder phase transition. Fine tuning of
both the chemical potential and the disorder pushes the critical temperature Ts
of this phase transition to zero giving a quantum critical point. Here the
quantum lattice and magnetic fluctuations promote the Feshbach resonance of the
exchange-like anisotropic pairing. This superconducting phase that resists to
the attacks of temperature is shown to be controlled by the interplay of the
hopping energy between stripes and the quantum fluctuations. The
superconducting gaps in the multiple Fermi surface spots reported by the recent
ARPES experiment of D. V. Evtushinsky et al. arXiv:0809.4455 are shown to
support the Feshbach scenario.Comment: 31 pages, 7 figure