Alkaline fuel cell performance investigation

An exploratory experimental fuel cell test program was conducted to investigate the performance characteristics of alkaline laboratory research electrodes. The objective of this work was to establish the effect of temperature, pressure, and concentration upon performance and evaluate candidate cathode configurations having the potential for improved performance. The performance characterization tests provided data to empirically establish the effect of temperature, pressure, and concentration upon performance for cell temperatures up to 300 F and reactant pressures up to 200 psia. Evaluation of five gold alloy cathode catalysts revealed that three doped gold alloys had more that two times the surface areas of reference cathodes and therefore offered the best potential for improved performance

Asymptotically exponential hitting times and metastability: a pathwise approach without reversibility

We study the hitting times of Markov processes to target set $G$, starting from a reference configuration $x_0$ or its basin of attraction. The configuration $x_0$ can correspond to the bottom of a (meta)stable well, while the target $G$ could be either a set of saddle (exit) points of the well, or a set of further (meta)stable configurations. Three types of results are reported: (1) A general theory is developed, based on the path-wise approach to metastability, which has three important attributes. First, it is general in that it does not assume reversibility of the process, does not focus only on hitting times to rare events and does not assume a particular starting measure. Second, it relies only on the natural hypothesis that the mean hitting time to $G$ is asymptotically longer than the mean recurrence time to $x_0$ or $G$. Third, despite its mathematical simplicity, the approach yields precise and explicit bounds on the corrections to exponentiality. (2) We compare and relate different metastability conditions proposed in the literature so to eliminate potential sources of confusion. This is specially relevant for evolutions of infinite-volume systems, whose treatment depends on whether and how relevant parameters (temperature, fields) are adjusted. (3) We introduce the notion of early asymptotic exponential behavior to control time scales asymptotically smaller than the mean-time scale. This control is particularly relevant for systems with unbounded state space where nucleations leading to exit from metastability can happen anywhere in the volume. We provide natural sufficient conditions on recurrence times for this early exponentiality to hold and show that it leads to estimations of probability density functions

Traffic Optimization at Junctions to Improve Vehicular Flows

The aim of this work is to improve urban traffic viability through an appropriate choice of yielding and stop signs or red and green phases for traffic lights in junctions with two entering and one exiting roads (junctions of 2×1 type). We consider a macroscopic fluid-dynamic model able to capture the traffic evolution. We analyze different functionals measuring networks performance in terms of average velocity, average traveling time, total flux, density, stop and go waves, average traveling time, weighted with the number of cars moving on roads, and kinetic energy. Right of way parameters which optimize the latter two functionals are obtained. Simulations of simple junctions of 2×1type have been used to test the correctness of the analytical results. Then, global performance of optimization procedures has been investigated on Re di Roma Square, in Italy. In particular, we discuss cases in which the functionals are optimized locally at each junction for different values of right of way parameters. We show that for the chosen initial data the only algorithm for the maximization of velocity assures globally the best performance for the network, also in terms of average traveling times and kinetic energy

Enhanced collisionless laser absorption in strongly magnetized plasmas

Strongly magnetizing a plasma adds a range of waves that do not exist in unmagnetized plasmas and enlarges the laser-plasma interaction (LPI) landscape. In this paper, we use particle-in-cell (PIC) simulations to investigate strongly magnetized LPI in one dimension under conditions relevant for magneto-inertial fusion experiments, focusing on a regime where the electron-cyclotron frequency is greater than the plasma frequency and the magnetic field is at an oblique angle with respect to the wave vectors. We show that when electron-cyclotron-like hybrid wave frequency is about half the laser frequency, the laser light resonantly decays to magnetized plasma waves via primary and secondary instabilities with large growth rates. These distinct magnetic-field-controlled instabilities, which we collectively call two-magnon decays, are analogous to two-plasmon decays in unmagnetized plasmas. Since additional phase mixing mechanisms are introduced by the oblique magnetic field, collisionless damping of large-amplitude magnetized waves substantially broadens the electron distribution function, especially along the direction of the magnetic field. During this process, energy is transferred efficiently from the laser to plasma waves and then to electrons, leading to a large overall absorptivity when strong resonances are present. The enhanced laser energy absorption may explain hotter-than-expected temperatures observed in magnetized laser implosion experiments and may also be exploited to develop more efficient laser-driven x-ray sources.Comment: 10 figure

Asymptotically exponential hitting times and metastability:A pathwise approach without reversibility

We study the hitting times of Markov processes to target set G, starting from a reference configuration x0 or its basin of attraction and we discuss its relation to metastability. Three types of results are reported: (1) A general theory is developed, based on the path-wise approach to metastability, which is general in that it does not assume reversibility of the process, does not focus only on hitting times to rare events and does not assume a particular starting measure. We consider only the natural hypothesis that the mean hitting time to G is asymptotically longer than the mean recurrence time to the refernce configuration x0 or G. Despite its mathematical simplicity, the approach yields precise and explicit bounds on the corrections to exponentiality. (2) We compare and relate different metastability conditions proposed in the literature. This is specially relevant for evolutions of infinite-volume systems. (3) We introduce the notion of early asymptotic exponential behavior to control time scales asymptotically smaller than the mean-time scale. This control is particularly relevant for systems with unbounded state space where nucleations leading to exit from metastability can happen anywhere in the volume. We provide natural sufficient conditions on recurrence times for this early exponentiality to hold and show that it leads to estimations of probability density functions.</p

Histopathology of the synovial tissue : perspectives for biomarker development in chronic inflammatory arthritides

The histopathological and molecular analysis of the synovial tissue has contributed to fundamental advances in our comprehension of arthritis pathogenesis and of the mechanisms of action of currently available treatments. On the other hand, its exploitation in clinical practice for diagnostic or prognostic purposes as well as for the prediction of treatment response to specific disease-modifying anti-rheumatic drugs is still limited. In this review, we present an overview of recent advances in the field of synovial tissue research with specific reference to the methods for synovial tissue collection, approaches to synovial tissue analysis and current perspectives for the exploitation of synovial tissue-derived biomarkers in chronic inflammatory arthritides

Defining the role of two newly identified proteins in the Vibrio vulnificus TonB2 system

Vibrio vulnificus is a human pathogenic bacteria that is closely related to Vibrio cholera, the disease causing agent of cholera. Three TonB transport systems are found in the outer membrane of V. vulnificus and are responsible for powering the uptake of iron bound siderophores into the cell. Within the Ton82 and TonB3 systems are two proteins, Orf1 and Orf6. The function and necessity of Orf1 and Orf6 to the TonB systems were investigated through the use of growth, motility, and antibiotic sensitivity assays and RNA transcriptional level analysis