176 research outputs found

    Synthesis of glycopeptides as building blocks for glycoproteins

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    Sub-Weyl strength bounds for twisted GL(2)GL(2) short character sums

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    Let S(N)=nNsmoothλf(n)χ(n),S(N) = \sum_{n \sim N}^{\text{smooth}} \, \lambda_{f}(n) \, \chi(n), where λf(n)\lambda_{f}(n)'s are Fourier coefficients of Hecke-eigen form, and χ\chi is a primitive character of conductor prp^{r}. In this article we prove a sub-Weyl strength bounds for S(N)S(N). Indeed, we obtain S(N)N59 p13r45,S(N) \ll \, N^{\frac{5}{9}} \ p^{\frac{13r}{45}}, provided that p13r/20Np4r/5 p^{13r/20} \leq N \leq p^{4r/5}. Note that the above bound for S(N)S(N) is non-trivial if N(pr)23160N\geq \left(p^{r}\right)^{\frac{2}{3}-\frac{1}{60}}.Comment: First draf

    Effect of crystal structure and cationic order on phonon modes across ferroelectric phase transformation in Pb(Fe0.5-xScxNb0.5)O3 bulk ceramics

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    Pb(Fe0.5-xScxNb0.5)O3 [(PFSN) (0 ≤ x ≤ 0.5)] multiferroic relaxors were synthesized and the temperature dependence of phonon modes across ferroelectric to paraelectric transition was studied. With varying Sc content from x = 0 to 0.25 the structure remains monoclinic and with further addition (x = 0.3 - 0.5) the structure transforms into rhombohedral symmetry. Structural refinement studies showed that the change in crystal structure from monoclinic to rhombohedral symmetry involves a volume increment of 34-36%. Associated changes in the tolerance factor (1.024 ≤ t ≤ 0.976) and bond angles were observed. Structure assisted B′-B″ cation ordering was confirmed through the superlattice reflections in selected area electron diffraction (SAED) pattern of Pb(Sc0.5Nb0.5)O3 (x = 0.5). Cation ordering is also evident from the evolution of Pb-O phonon mode in Raman spectra of compositions with rhombohedral symmetry (x ≥ 0.3). The high temperature Raman scattering studies show that the B-localized mode [F1u, ∼250 cm−1] and BO6 octahedral rotational mode [F1g, ∼200 cm−1], both originating from polar nano regions (PNRs) behave like coupled phonon modes in rhombohedral symmetry. However, in monoclinic symmetry they behave independently across the transition. Softening of B localized mode across the transition followed by the hardening for all compositions confirms the diffusive nature of the ferroelectric transformation. The presence of correlation between the B localized and BO6 rotational modes introduces a weak relaxor feature for systems with rhombohedral symmetry in PFSN ceramics, which was confirmed from the macroscopic dielectric studies

    Sub-convexity bound for GL(3)×GL(2)GL(3) \times GL(2) LL-functions: GL(3)GL(3)-spectral aspect

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    Let ϕ\phi be a Hecke-Maass cusp form for SL(3,Z)SL(3, \mathbb{Z}) with Langlands parameters (ti)i=13({\bf t}_{i})_{i=1}^{3} satisfying t3t2T1ξϵ,tiT,i=1,2,3|{\bf t}_{3} - {\bf t}_{2}| \leq T^{1-\xi -\epsilon}, \quad \, {\bf t}_{i} \approx T, \quad \, \, i=1,2,3 with 1/201/2 0. Let ff be a holomorphic or Maass Hecke eigenform for SL(2,Z)SL(2,\mathbb{Z}). In this article, we prove a sub-convexity bound L(ϕ×f,12)max{T32ξ4+ϵ,T3212ξ4+ϵ}L(\phi \times f, \frac{1}{2}) \ll \max \{ T^{\frac{3}{2}-\frac{\xi}{4}+\epsilon} , T^{\frac{3}{2}-\frac{1-2 \xi}{4}+\epsilon} \} for the central values L(ϕ×f,12)L(\phi \times f, \frac{1}{2}) of the Rankin-Selberg LL-function of ϕ\phi and ff, where the implied constants may depend on ff and ϵ\epsilon. Conditionally, we also obtain a subconvexity bound for L(ϕ×f,12)L(\phi \times f, \frac{1}{2}) when the spectral parameters of ϕ\phi are in generic position, that is titjT,forij,tiT,i=1,2,3.{\bf t}_{i} - {\bf t}_{j} \approx T, \quad \, \text{for} \, i \neq j, \quad \, {\bf t}_{i} \approx T , \, \, i=1,2,3.Comment: First draf

    The second moment of derivatives of GL(2)GL(2) LL-functions over quadratic twists

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    Let ff be an Hecke eigenform for the group Γ0(q)\Gamma_{0}(q) and χd\chi_{d} be a primitive quadratic character of conductor d|d|. In this article, we prove an asymptotic for the second moment of the derivative of L(s,fχ8d)L(s, f \otimes \chi_{8d}) at the central point 1/21/2, which was previously known under GRH by Petrow \cite{petrow}.Comment: 19 Page
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