Preparation and Characterization of Silver and Gold Nanoparticles and Study Influence on Physical Properties of PVA/PVP nanocomposites

Gold nanoparticles (Au NPs) and Silver nanoparticles (Ag NPs) ware prepared by green synthesis extraction using the Chenopodium murale leaf extract, the obtained (Ag NPs and Au NPs) were investigated by UV/Vis. absorption spectroscopy, transmission electron microscopy, Zetasizer, XRD. The plant extraction leads to produce nanoparticles of spherical shape with size range from 4 to 22 nm. Polyvinyl alcohol (PVA) and polyvinyl Pyrolidone (PVP) blend with mixed silver and gold nanoparticles were prepared by casting method. Amorphous feather of doping polymers blend was characterized by X-ray diffraction. Significant changes within the polymer matrix were monitored from infrared spectroscopy which indicates the interaction between polymer blend and mixed nanoparticles. Both indirect and direct optical energy gaps are calculated and discussed

A Study of Adiponectin in Children with Diabetes Mellitus

Objectives: Adiponectin is a hormone produced by adipose tissue. It is secreted exclusively by adipocytes and appears to play a role in the pathophysiology of obesity, diabetes mellitus (DM), and its comorbidities. The aim of this study was to assess adiponectin levels in diabetic children with type 1 DM (T1DM) and type 2 DM (T2DM), and to detect its prognostic role in them. Methods: This study was undertaken from April to July 2011 at Minia University Children’s Hospital, Egypt, and included 314 children aged 2–18 years divided into two patient groups. Group I consisted of 164 pre-diagnosed diabetic patients, further subdivided into Group Ia which included 142 patients with T1DM and Group Ib, 22 patients with T2DM; Group 2 included 150 apparently healthy children as a controls; they were age- and sex-matched to the diseased group. Patients were subjected to a thorough history taking, clinical examination, and laboratory investigations including assessment of HbA1c percentages, fasting C-peptide levels, lipid profiles and fasting serum adiponectin levels. Results: Adiponectin levels did not differ significantly between patients with T1DM and T2DM, but it was significantly higher in diabetic patients than in the controls. In T1DM, adiponectin had positive significant correlations with the duration of the disease and waist circumference, while in T2DM, it had a positive significant correlation with the dose of insulin given and negative significant associations with diastolic blood pressure, cholesterol, and C-peptide levels. Conclusion: The results of the study suggest that adiponectin can play a protective role against the metabolic complications of DM

ISTRAŽIVANJE INDEKSA ANIZOTROPIJE ČVRSTOĆE ODREĐENOGA EGIPATSKOG UKRASNOG KAMENA

The nature of ornamental stones is anisotropic. The heterogeneous characteristics of the anisotropic rocks vary with direction. The highest to lowest strength ratio is known as the anisotropy strength index (ASI). A thorough investigation of the ASI is necessary to determine the best-directed loads for these rocks. On core specimens that have been bored parallel and perpendicular to the weakness planes, this is estimated using both uniaxial compression and point load testing. For this examination, four different rock types had cores that were drilled conventionally and in line with weakness planes. The research shows that drilling cores to weakness planes at a normal or nearly normal angle (90° to 60°) yields the best, most dependable ASI. According to the current study’s findings, the ASI fluctuates depending on how uniformly the mineral content and texture of rocks are. A suggested way to calculate the ASI and the load point strength is also included. This study reveals that the employment of ornamental stone as is (for example, precipitation position is more robust and reliable than that perpendicular form) is critical in determining the resilience of this type of rock and its spatial implementation (e.g. flooring).Priroda je ukrasnoga kamena anizotropna. Heterogene karakteristike anizotropnih stijena variraju prema smjeru promatranja. Omjer najveće i najmanje čvrstoće poznat je kao indeks anizotropije čvrstoće (ASI). Kod korištenja takvih stijena potrebno je temeljito istraživanje ASI-ja kako bi se utvrdio najbolji smjer opterećenja. To se procjenjuje kod ispitivanja jednoosne tlačne čvrstoće i kod ispitivanja indeksa čvrstoće opterećenjem u točki na jezgrama koje su bušene paralelno i okomito na ravnine oslabljenja. Istraživana su četiri različita tipa stijena čije su jezgre izbušene uobičajeno paralelno s ravninama oslabljenja. Istraživanje pokazuje kako bušenje jezgri do ravnine oslabljenja pod normalnim ili gotovo normalnim kutom (90° do 60°) daje najbolji, najpouzdaniji ASI. Prema rezultatima ovoga istraživanja ASI varira ovisno o ujednačenosti sadržaja minerala i teksture stijene. Također je predložen način izračunavanja ASI-ja koji uključuje indeks čvrstoće opterećenjem u točki. Ovo istraživanje otkriva da je upotreba ukrasnoga kamena po smjeru (na primjer, paralelni je smjer robusniji i pouzdaniji od okomitoga smjera) presudna u određivanju otpornosti ove vrste stijena i u njezinoj prostornoj primjeni (npr. u popločavanju)

Comparison of the accuracy of two scoring systems in predicting the outcome of organophosphate intoxicated patients admitted to intensive care unit (ICU)

AbstractIntroductionOrganophosphates(OP) are one of the most common causes of poisoning, especially in developing countries, with high morbidity and mortality. As mortality rate of OP poisoning is still high, early diagnosis and appropriate treatment is often life saving. OP is the main cause of poisoning and death in the poison control centre (PCC), Ain Shams University (ASU) in Egypt.ObjectiveTo compare the accuracy of acute physiology and chronic health evaluation score (APACHE IV) and simplified acute physiology score (SAPS II) in the prediction of mortality of patients with organophosphate poisoning (OPP) who required admission to the Intensive Care Unit (ICU) of PCC of ASU between January 1st, 2009 and December 31st, 2009.MethodsA prospective study conducted by collecting data on consecutive patients with acute OPP admitted to the intensive care unit over 12months. Data required to calculate the patients’ predicted mortality by (APACHE) IV and (SAPS) II scoring systems were collected.ResultsNinety patients were recruited in the study with acute OP toxicity. The observed mortality following acute OP toxicity was 13.3% (12 patients). The area under the receiver operator characteristic (ROC) curves of APACHE IV score was better than SAPS II score (0.921±0.054 SE, 0.807±0.078 SE, respectively). APACHE IV and SAPS II scores were significantly higher in the non-survival than in the survival group (P<0.05).ConclusionAPACHE IV and SAPS II scores calculated within the first 24h are good prognostic indicators among patients with acute OP toxicity that required ICU admission with preference to APACHE IV score. APACHE IV and SAPS II scores above 89, 44, respectively within the first 24h are a predictor of poor outcome in patients with acute OP toxicity.RecommendationApplication of APACHE IV and SAPS II scores is a good predictor of high mortality in OP intoxicated patients which helps in proper allocation of resources

Novel Polyoxyethylene-Containing Glycolipids Are Synthesized in Corynebacterium matruchotii and Mycobacterium smegmatis Cultured in the Presence of Tween 80

The addition of polyoxyethylene sorbitan monooleate (Tween 80) to a culture of mycobacteria greatly influences cell permeability and sensitivity to antibiotics but very little is known regarding the underlying mechanism. Here we show that Corynebacterium matruchotii (surrogate of mycobacteria) converts Tween 80 to a structural series of polyoxyethylenic acids which are then used to form novel series-2A and series-2B glycolipids. Minor series-3 glycolipids were also synthesized. The polyoxyethylenic acids replaced corynomycolic acids in the cell wall. Correspondingly the trehalose dicorynomycolate content was reduced. MALDI mass spectrometry, MS-MS, 1H-NMR, and 13C-NMR were used to characterize the series-2 glycolipids. Series-2A glycolipid is trehalose 6-C36:2-corynomycolate-6′-polyoxyethylenate and series-2B glycolipid is trehalose 6-C36:2-corynomycolate-6′-furan ring-containing polyoxyethylenate. Mycobacterium smegmatis grown in the presence of Tween 80 also synthesizes series-2 type glycolipids. The synthesis of these novel glycolipids in corynebacteria and mycobacteria should result in gross changes in the cell wall permeability and drug sensitivity

On the reflection of Alfvén waves in an ideal magnetoatmosphere

A lineafized theory ofmagnetoatmospheric waves is developed where the restoring forces are those of compressibility and magnetic pressure. An equation for resonance is derived. Reflection and tunneling of upward propagating Alfvén waves in an ideal Magnetoatmosphere are considered. It is shown that the magnetic field produces a reflecting nonabsorbing critical layer. Below the critical layer, the solution of the problem can be written as a linear combination of an upward and a downward propagating wave and above it the solution decays exponentially with the altitude. The location of the critical layer and the magnitude of the reflection coefficient are determined and the conclusions are discussed in cormeetion with the heating mechanism of the solar atmospher

LINEARNO PROGRAMIRANJE KAO ALAT ZA PROJEKTIRANJE SIROVINSKE SMJESE U TVORNICI CEMENTA

This study uses linear programming to develop a methodology for selecting the best raw material mix in an ASCOM cement plant in Egypt. In cement factories, this type adheres to Egyptian chemical composition criteria for raw feed (e.g. 82.5% calcium carbonate, 14.08% silica, 2.5% alumina and 0.92% iron oxide). Furthermore, the model is bound by industry-specific characteristics (e.g. lime saturation factor, silica modulus, alumina modulus and loss of ignition). The results reveal that the model is able to accurately reproduce the mixing of high-quality feed with varying constituent percentages. It is also capable of determining the combining limitations of each ingredient. Furthermore, it demonstrates optimality for additive sourcing short-term planning and capping limestone quality to meet changeable component combinations. Additionally, improving the raw mix reduces limestone feed quality from 51 to 50.6%, resulting in the inclusion of extra limestone reserves.Studija prikazuje metodu linearnoga programiranja uporabljenu sa svrhom odabira najbolje sirovinske smjese u tvornici cementa ASCOM (Egipat). Takva smjesa poštuje egipatske standarde kemijskoga sastava sirovine (npr. 82,5 % kalcijeva karbonata, 14,08 % silikata, 2,5 % aluminijeva oksida, 0,92 % željeznoga oksida). Također, model je uvjetovan industrijskim standardima (npr. faktorom zasićenja vapnom, silikatnim i aluminatnim modulom te gubitkom (oksida) žarenjem). Modelom se mogla točno izračunati visokokvalitetna mješavina različitih (postotnih) komponenti te je dokazan kao optimalan za brz izračun raznih aditiva i postizanje najveće kvalitete vapnenačke sirovine uz doziranje ostalih komponenti. Time je udjel vapnenca bilo moguće smanjiti na 50,6 – 51 %, što je otvorilo put eksploataciji dodatnih rezervi te sirovine