178 research outputs found

    Case studies examining the effects of specialist schooling on successful musicians

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    A third polymorph of N,N′-bis­(pyridin-2-yl)benzene-1,4-diamine

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    A third polymorph of the title compound, C16H14N4, has been obtained. The mol­ecule adopts a non-planar conformation with an E configuration at the two partially double exo C N bonds of the 2-pyridyl­amine units. Like in the triclinic form [Bensemann et al. (2002 ▶). New J. Chem. 26, 448–456], the recognition process between 2-pyridyl­amine units takes place through formation of a cyclic R 2 2(8) hydrogen-bond motif, leading to the creation of tapes parallel to [001]

    How Should the Health Community Respond to Violent Political Conflict?

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    Violent political conflict is on the front pages, in Iraq, Afghanistan, and Sudan. This provocative piece discusses lessons we can learn from past conflicts in dealing with future one

    Chlorido(ethyl­diphenyl­phosphine-κP)(1-pyrrolidinecarbodithio­ato-κ2 S,S′)nickel(II)

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    In the crystal structure of the title complex, [Ni(C5H8NS2)Cl(C14H15P)], the Ni atom is coordinated by an S,S′-chelating dithio­carbamate, a chloride and a diphenyl­ethyl­phosphine ligand in a distorted square-planar arrangement

    Tetra-n-butyl­ammonium iodido(pyrrolidine-1-carbodithio­ato-κ2 S,S′)(tris-tert-butoxy­silanethiol­ato-κS)cadmate(II)

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    In the anion of the title compound, (C16H36N)[Cd(C5H8NS2)(C12H27O3SSi)I], the Cd atom is four-coordinated by S,S′-chelating dithio­carbamate, S–donating silanethiol­ate and iodide ligands in a distorted tetrahedral environment . Inter­molecular C—H⋯ S and C—H⋯I inter­actions between cations and anions are present. Two C atoms of a tert-butyl group are disordered over two positions; the site occupancies are ca 0.65 and 0.35

    Redetermination of bis­(O,O′-diethyl dithio­phosphato-κ2 S,S′)nickel(II)

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    The centrosymmetric title complex, [Ni{S2P(OC2H5)2}2], has been redetermined using area-detector data. The central Ni(S2P)2 core is essentially planar and confirms the early results of McConnell & Kastalsky [Acta Cryst. (1967), 22, 853–859] based on multiple film technique data. In the title structure, the standard uncertainty values are approximately seven times lower and all H-atom positions are calculated. A pair of short symmetry-related H⋯H contacts with distances of 2.33 Å is observed in the crystal structure
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