2 research outputs found
A new 1-dimensional molybdenum phosphate:Synthesis and structure of [(CH<sub>3</sub>)<sub>4</sub>N][MN<sub>2</sub>MO<sub>6</sub>O<sub>12</sub>(OH)<sub>4</sub>(PO<sub>4</sub>)(HPO<sub>4</sub>)(H<sub>2</sub>PO<sub>4</sub>)<sub>2</sub>] · 4H<sub>2</sub>O
No full textThe title compound, bis(tetramethylaramonium) dicobaltio - μ-dihydrogenphosphato -μ- bis (hydrogenphosphato)-μ 6-phosphato-tetrahydroxycyclohexamolybdate-(Mo-Mo) pentahydrate, was synthesized hydrothermally and crystallizes as a polymeric ionic complex with anionic chains, composed of [Mo6O12(OH)3(HxPO4) 4]n- clusters held together by Co2+ cations running parallel to the b axis. Neighbouring chains are linked by hydrogen bonds only via intervening [N(CH3)4]+ cations and water molecules.</p
