Catalytic ozone pretreatment of complex textile effluent using Fe2+ and zero valent iron nanoparticles

The study investigates the effect of catalytic ozone pretreatment via Fe2+ and nZVI on biodegradability enhancement of complex textile effluent. The nZVI particles were synthesized and characterized by XAD, TEM and SEM analyses. Results showed that nano catalytic ozone pretreatment led to higher biodegradability index (BOD5/COD = BI) enhancement up to 0.61 (134.6%) along with COD, color and toxicity removal up to 73.5%, 87%, and 92% respectively. The disappearance of the corresponding GC-MS & FTIR spectral peaks during catalyzed ozonation process indicated the cleavage of chromophore group and degradation of organic compounds present in the textile effluent. Subsequent aerobic biodegradation of nZVI pretreated textile effluent resulted in maximum COD and color reduction of 78% and 98.5% respectively, whereas the untreated effluent (BI = 0.26) indicated poor COD and color reduction of only 31% and 33% respectively. Bio-kinetic parameters also confirmed the increased rate of bio-oxidation at enhanced BIs. Seed germination test using seeds of Spinach (Spinacia oleracea), indicated the effectiveness of nano catalyzed ozone pretreatment in removing toxicity from contaminated textile effluent

Comparison of coagulation, ozone and ferrate treatment processes for color, COD and toxicity removal from complex textile wastewater

In this study, the comparative performance of coagulation, ozone, coagulation | ozone | coagulation and potassium ferrate processes to remove chemical oxygen demand (COD), color, and toxicity from a highly polluted textile wastewater were evaluated. Experimental results showed that ferrate alone had no effect on COD, color and toxicity removal. Whereas, in combination with FeSO4, it has shown the highest removal efficiency of 96.5%, 83% and 75% for respective parameters at the optimal dose of 40 mgL(-1) + 3 ml FeSO4 (1 M) in comparison with other processes. A seed germination test using seeds of Spinach (Spinacia oleracea) also indicated that ferrate was more effective in removing toxicity from contaminated textile wastewater. Potassium ferrate also produces less sludge with maximum contaminant removal, thereby making the process more economically feasible. Fourier transform infrared spectroscopy (FTIR) analysis also shows the cleavage of the chromophore group and degradation of textile wastewater during chemical and oxidation treatment processes

Life cycle assessment of microalgae based biodiesel production to evaluate the impact of biomass productivity and energy source

In the present study the life cycle assessment (LCA) of three scenarios for biodiesel production from Scenedesmus dimorphus, a freshwater microalgae, cultivated in open raceway ponds using primary and secondary data was investigated. The main differences in the scenarios were related to biomass productivity, mode of culture mixing and type of energy source. The process steps included algal cultivation in open raceway ponds, harvesting by chemical flocculation, dewatering by mechanical drying option (MDO)/Spray Drying (SD) followed by extraction, reaction, and purification. Supplementation of the cultivation process with electricity derived from defatted algal biomass waste was also analyzed. The scenarios were evaluated for energy demand and environmental impacts amongst the boundary conditions based on a "cradle-to-gate" inventory. The results revealed that among all the scenarios, cultivation in raceway pond was ascertained to be the most energy intensive process with the mode of culture mixing and biomass productivity being the principal determinants. The impacts were found to be directly linked to energy demand and had an inverse relationship with biomass productivity. The geographic location of the energy sources affected the environmental implications of a given process. The integration of defatted algal biomass waste derived electricity with the cultivation system showed a minor reduction in the overall energy demand. (C) 2017 Elsevier B.V. All rights reserved

Defatted algal biomass as a non-conventional low-cost adsorbent: Surface characterization and methylene blue adsorption characteristics

The present study investigates the use of defatted algal biomass (DAB) as a non-conventional low cost adsorbent. The maximum adsorption capacity of biomass (raw, defatted and sulfuric acid pretreated DAB) was determined by liquid phase adsorption studies in batch mode for the removal of methylene blue present at various concentrations (1, 2, 3, 4, and 5 mg L (1)) from aqueous solutions. The data was well fitted with Langmuir and Freundlich isotherms. The maximum adsorption capacity for raw, defatted and sulfuric acid pretreated DAB was found to be 6.0, 7.73 and 7.80 mg g (1), respectively. The specific surface area of raw, defatted and sulfuric acid pretreated DAB was estimated to be 14.70, 18.94, and 19.10 m(2) g (1), respectively. To evaluate the kinetic mechanism that controls the adsorption process, pseudo-first order, pseudo-second order, intraparticle diffusion and particle diffusion has been tested. The data fitted quite well with pseudo-second order kinetic model. (C) 2014 Elsevier Ltd. All rights reserved

Evaluation of indigenous fresh water microalga Scenedesmus obtusus for feed and fuel applications: Effect of carbon dioxide, light and nutrient sources on growth and biochemical characteristics

Scenedesmus obtusus, a freshwater microalga, was evaluated for its growth and biochemical characteristics under various culture conditions. S. obtusus was tolerant at all tested CO2 concentrations up to 20%. Among the different nitrogen sources, urea showed enhanced biomass productivities up to 2-fold compared to control, where the nitrogen source was sodium nitrate. Light intensity and photoperiod had a significant effect on growth rate and biomass productivity. The growth rate was observed maximum under continuous light exposure at the light intensities, 30 lmol m (2) sec (1) and 60 lmol m (2) sec (1) The species was able to tolerate the salinity levels up to 25 mM NaCl, where, the increase in the concentration of NaCl suppressed the growth. Ammonium acetate and glycine showed better growth rate and biomass productivity indicating mixotrophic ability of S. obtusus. Supplementation of acetate and bicarbonate significantly enhanced the biomass productivity. Biodiesel properties of S. obtusus cultivated at various culture conditions were estimated. (C) 2016 Elsevier Ltd. All rights reserved

Statistical optimization of thermal pretreatment conditions for enhanced biomethane production from defatted algal biomass

The present study analyzes the effect of thermal pretreatment for enhancing the biomethane potential of defatted algal biomass of Scenedesmus dimorphus through statistically guided experimental design. To this end, defatted microalgal biomass at various concentrations (1, 3 and 5 g L-1) was pretreated at elevated temperatures (100, 120 and 150 degrees C) for 20, 40 and 60 min. The solubilised TOC was favourably enhanced up to 71 mg L-1 after pretreatment at a temperature of 150 degrees C for reaction time of 60 min. The methane yield was substantially enhanced (up to 60%) and could be correlated with an increase in organic matter solubilisation and enhanced biodegradability via thermal pretreatment. The optimisation of the integrated thermal pretreatment-biomethanation process resulted in up to 1.6-fold increase in methane yield. (C) 2014 Elsevier Ltd. All rights reserved

Growth and biochemical characteristics of an indigenous freshwater microalga, Scenedesmus obtusus, cultivated in an airlift photobioreactor: effect of reactor hydrodynamics, light intensity, and photoperiod

The freshwater green algae, Scenedesmus obtusus, was cultivated in a 3.4 L airlift photobioreactor. The hydrodynamic parameters were estimated at different inlet gas flow rates (1, 2, 3, and 4 LPM) and their subsequent impact on the growth and biochemical characteristics of microalgae was studied. The biomass concentration and productivity increased with an increase in flow rates from 1 to 4 LPM. A maximum of 0.07 g L-1 day(-1) productivity of biomass was attained at 3 LPM. An increase of total carbohydrate content from 19.6 to 26.4% was noticed with increment in the inlet flow rate of gas from 1 to 4 LPM. Major variations in total fatty acid content were not observed. The impact of light irradiance on growth and biochemical characteristics of S. obtusus was also evaluated. A maximum biomass productivity of 0.103 g L-1 day(-1) was attained at an illumination of 150 mu mol m(-2) s(-1) under continuous light. The major fatty acids reported were palmitic acid (C16:0), alpha-linolenic acid (C18:3), linoleic acid (C18:2), and oleic acid (C18:1). Biodiesel properties of the microalgae were estimated under various culture conditions. The light profile inside the airlift reactor was experimentally measured and the predictive modelling of light profile was also attempted