72 research outputs found
Application of Graphene within Optoelectronic Devices and Transistors
Scientists are always yearning for new and exciting ways to unlock graphene's
true potential. However, recent reports suggest this two-dimensional material
may harbor some unique properties, making it a viable candidate for use in
optoelectronic and semiconducting devices. Whereas on one hand, graphene is
highly transparent due to its atomic thickness, the material does exhibit a
strong interaction with photons. This has clear advantages over existing
materials used in photonic devices such as Indium-based compounds. Moreover,
the material can be used to 'trap' light and alter the incident wavelength,
forming the basis of the plasmonic devices. We also highlight upon graphene's
nonlinear optical response to an applied electric field, and the phenomenon of
saturable absorption. Within the context of logical devices, graphene has no
discernible band-gap. Therefore, generating one will be of utmost importance.
Amongst many others, some existing methods to open this band-gap include
chemical doping, deformation of the honeycomb structure, or the use of carbon
nanotubes (CNTs). We shall also discuss various designs of transistors,
including those which incorporate CNTs, and others which exploit the idea of
quantum tunneling. A key advantage of the CNT transistor is that ballistic
transport occurs throughout the CNT channel, with short channel effects being
minimized. We shall also discuss recent developments of the graphene tunneling
transistor, with emphasis being placed upon its operational mechanism. Finally,
we provide perspective for incorporating graphene within high frequency
devices, which do not require a pre-defined band-gap.Comment: Due to be published in "Current Topics in Applied Spectroscopy and
the Science of Nanomaterials" - Springer (Fall 2014). (17 pages, 19 figures
Self-Limiting Layer Synthesis of Transition Metal Dichalcogenides
This work reports the self-limiting synthesis of an atomically thin, two dimensional transition metal dichalcogenides (2D TMDCs) in the form of MoS2. The layer controllability and large area uniformity essential for electronic and optical device applications is achieved through atomic layer deposition in what is named self-limiting layer synthesis (SLS); a process in which the number of layers is determined by temperature rather than process cycles due to the chemically inactive nature of 2D MoS2. Through spectroscopic and microscopic investigation it is demonstrated that SLS is capable of producing MoS2 with a wafer-scale (similar to 10 cm) layer-number uniformity of more than 90%, which when used as the active layer in a top-gated field-effect transistor, produces an on/off ratio as high as 10(8). This process is also shown to be applicable to WSe2, with a PN diode fabricated from a MoS2/WSe2 heterostructure exhibiting gate-tunable rectifying characteristics.ope
Topological mosaics in moiré superlattices of van der Waals heterobilayers
Van der Waals (vdW) heterostructures formed by 2D atomic crystals provide a
powerful approach towards designer condensed matter systems. Incommensurate
heterobilayers with small twisting and/or lattice mismatch lead to the
interesting concept of Moir\'e superlattice, where the atomic registry is
locally indistinguishable from commensurate bilayers but has local-to-local
variation over long range. Here we show that such Moir\'e superlattice can lead
to periodic modulation of local topological order in vdW heterobilayers formed
by two massive Dirac materials. By tuning the vdW heterojunction from normal to
the inverted type-II regime via an interlayer bias, the commensurate
heterobilayer can become a topological insulator (TI), depending on the
interlayer hybridization controlled by the atomic registry between the vdW
layers. This results in mosaic pattern of TI regions and normal insulator (NI)
regions in Moir\'e superlattices, where topologically protected helical modes
exist at the TI/NI phase boundaries. By using symmetry based k.p and
tight-binding models, we predict that this topological phenomenon can be
present in inverted transition metal dichalcogenides heterobilayers. Our work
points to a new means of realizing programmable and electrically switchable
topological superstructures from 2D arrays of TI nano-dots to 1D arrays of TI
nano-stripes.Comment: 17 pages,5 figure
Tunable quantum emission from atomic defects in hexagonal boron nitride
© 2016 Optical Society of America. We demonstrate that strain control of exfoliated hexagonal boron nitride allows spectral tuning of single photon emitters over 6 meV. We propose a material processing that sharply improves the single-photon purity with g(2)(0) = 0.077, and brightness with emission rate exceeding 107counts/sec at saturation
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